Synthesis and crystal structure of new [Pyridine-4-boronic acid methyl ester and Nickel(II) dithiooxalate] compound

Yıl 2022, Cilt: 24 Sayı: 2, 750 - 756, 08.07.2022

Hülya Kara Subasat Elif Güngör

https://doi.org/10.25092/baunfbed.1070259

Öz

In this study, a new compound [HNC5H4B(OH)(OCH3)-4]2[Ni(S2C2O2)2], [Pyridine-4-boronic acid methyl ester and Nickel(II) dithiooxalate] was synthesized and its crystal structure was determined by the single-crystal X-ray diffraction method. The compound crystallized in the monoclinic crystal system in the P21/n space group. The NiII ion is four-coordinated and has a slightly distorted square-plane geometry. There is NH⋯O, OH⋯O and CH⋯O hydrogen bond interactions in the crystal structure. These interactions form a 3-dimension network stacked along the c axis in the ab plane.

Anahtar Kelimeler

Crystal structure, 4-pyridine boronic acid, hydrogen bond interactions

Yeni [Piridin-4-boronik asit metil ester ve Nikel(II) ditiooksalat] bileşiğinin sentezi ve kristal yapısı

Öz

Bu çalışmada yeni bir bileşik [HNC5H4B(OH)(OCH3)-4]2[Ni(S2C2O2)2], [Piridin-4-boronik asit metil ester ve Nikel(II) ditiooksalat] sentezlendi ve onun kristal yapısı tek kristal X-ışını difraktometresi metodu ile belirlendi. Bileşik P21/n uzay grubunda monoklinik kristal sisteminde kristallendi. NiII iyonu dört koordinasyonlu ve hafifçe bozulmuş kare düzlem geometriye sahiptir. Kristal yapıda, NH⋯O, OH⋯O ve CH⋯O hidrojen bağ etkileşimleri vardır. Bu etkileşimler ab düzleminde c ekseni boyunca paketlenir ve 3 boyutlu bir ağ oluşturur.

Anahtar Kelimeler

Kristal yapı, 4-pridin boronik asit, hidrojen bağ etkileşimleri.

Kaynakça

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