CONGO RED REMOVAL FROM AQUEOUS SOLUTIONS BY ADSORPTION ON PEANUT HULL

Yıl 2020, Cilt: 2 Sayı: 1, 28 - 35, 29.04.2020

Serap Fındık

https://doi.org/10.46387/bjesr.657609

Cited By: 1

Öz

Congo red is one of the anionic diazo dyes and is widely used in the dying process for many industries. Industries such as textile, leather, paper, rubber, plastics and cosmetics are used the congo red dye. In this study, removal of congo red from aqueous solutions by adsorption on peanut hull was explored. The effects of several parameters like contact time, initial concentration, adsorbent amount, particle size and temperature were researched. A kinetic study was also performed. Adsorption rate increases up to 60mg/L initial concentration and then decreases. 60mg/L may be considered as an optimum initial concentration in the initial concentration range studied. The removal of congo red increases with increasing absorbent amount. The removal of congo red decreases with increasing adsorbent particle size and temperature as well. The adsorption equilibriums were reached at about 60min. Adsorption kinetics of congo red on the peanut hull followed by pseudo second - order kinetic model.

Anahtar Kelimeler

adsorpsiyon, congo red, kinetic, Peanut hull

Fıstık Kabuğu Üzerinde Sulu Çözeltilerden Adsorpsiyon İle Kongo Kırmızının Uzaklaştırılması

Öz

Congo red is one of the anionic diazo dyes and is widely used in the dying process for many industries. Industries such as textile, leather, paper, rubber, plastics and cosmetics are used the congo red dye. In this study, removal of congo red from aqueous solutions by adsorption on peanut hull was explored. The effects of several parameters like contact time, initial concentration, adsorbent amount, particle size and temperature were researched. A kinetic study was also performed. Adsorption rate increases up to 60mg/L initial concentration and then decreases. 60mg/L may be considered as an optimum initial concentration in the initial concentration range studied. The removal of congo red increases with increasing absorbent amount. The removal of congo red decreases with increasing adsorbent particle size and temperature as well. The adsorption equilibriums were reached at about 60min. Adsorption kinetics of congo red on the peanut hull followed by pseudo second - order kinetic model.

Anahtar Kelimeler

Adsorpsiyon, Kinetik, Kongo kırmızı, Fıstık kabuğu

Kaynakça

• [1] N. H. Hairom, A. W. Mohammad, A. A. Kadhum, “Influence of zinc oxide nanoparticles in the nanofiltration of hazardous Congo red dyes”, Chemical Engineering Journal, vol. 260, pp. 907–915, 2015.
• [2] N. Kataria, V. K. Garg, “Removal of Congo red and Brilliant green dyes from aqueous solution using flower shaped ZnO nanoparticles”, Journal of Environmental Chemical Engineering, vol.5, no. 6, pp. 5420–5428, 2017.
• [3] R. S. Aliabadi, N. O. Mahmoodi, “Synthesis and characterization of polypyrrole, polyaniline nanoparticles and their nanocomposite for removal of azo dyes; sunset yellow and Congo red”, Journal of Cleaner Production, vol. 179, pp. 235-245, 2018.
• [4] K. Naseem, Z. H. Farooqi, R. Begum, A. Irfan, “ Removal of Congo red dye from aqueous medium by its catalytic reduction using sodium borohydride in the presence of various inorganic nano-catalysts: A review”, Journal of Cleaner Production, vol.187, pp. 296-307, 2018.
• [5] H. Patel, R. T. Vashi, “Removal of Congo Red dye from its aqueous solution using natural coagulants”, Journal of Saudi Chemical Society, vol. 16, no. 2, pp. 131-136, 2012.
• [6] N. Güy, S. Çakar, M. Özacar, “Comparison of palladium/zinc oxide photocatalysts prepared by different palladium doping methods for congo red degradation”, Journal of Colloid and Interface Science, vol. 466, pp. 128–137, 2016.
• [7] M. Khadhraoui, H. Trabelsi, M. Ksibi, S. Bouguerra, B. Elleuch, “Discoloration and detoxicification of a Congo red dye solution by means of ozone treatment for a possible water reuse”, Journal of Hazardous Materials, vol. 161, no. 2-3, pp. 974–981, 2009.
• [8] J. Wang, Y. Jiang, Z. Zhang, G. Zhao, G. Zhang, T. Ma, W. Sun, “Investigation on the sonocatalytic degradation of congo red catalyzed by nanometer rutile TiO2 powder and various influencing factors”, Desalination, vol. 216, no.1-3, pp. 196–208, 2007.
• [9] M. T. Yagub, T. K. Sen, S. Afroze, H. M. Ang, “Dye and its removal from aqueous solution by adsorption: A review”, Advances in Colloid and Interface Science, vol. 209, pp. 172–184, 2014.
• [10] M. Hu, X. Yan, X. Hu, J. Zhang, R. Feng, M. Zhou, “Ultra-high adsorption capacity of MgO/SiO2 composites with rough surfaces for Congo red removal from water”, Journal of Colloid and Interface Science, vol.510, pp. 111–117, 2018.
• [11] I. A. Lawal, D. Chetty, S. O. Akpotu, B. Moodley, “Sorption of Congo red and reactive blue on biomass and activated carbon derived from biomass modified by ionic liquid, Environmental Nanotechnology”, Monitoring & Management, vol. 8, pp. 83–91, 2017.
• [12] S. K. Low, M. C. Tan, N. L. Chin, “Effect of ultrasound pre-treatment on adsorbent in dye adsorption compared with ultrasound simultaneous adsorption”, Ultrasonics Sonochemistry, vol. 48, pp. 64–70, 2018.
• [13] R. Gong, Y. Ding, M. Li, C. Yang, H. Liu, Y. Sun, “Utilization of powdered peanut hull as biosorbent for removal of anionic dyes from aqueous solution”, Dyes and Pigments, vol. 64, no.3, pp. 187-192, 2015.
• [14] R. Gong, M. Li, C. Yang, Y. Sun, J. Chen, “Removal of cationic dyes from aqueous solution by adsorption on peanut hull”, Journal of Hazardous Materials, vol. 121, no. 1-3, pp. 247–250, 2005.
• [15] S. Sadaf, H. N. Bhatti, “ Evaluation of peanut husk as a novel, low cost biosorbent for the removal of Indosol Orange RSN dye from aqueous solutions: batch and fixed bed studies”, Clean Techn Environ Policy, vol. 16, pp. 527–544, 2014.
• [16] S. Sadaf, H. N. Bhatti, “Batch and fixed bed column studies for the removal of Indosol Yellow BG dye by peanut husk”, Journal of the Taiwan Institute of Chemical Engineers, vol. 45, no. 2, pp. 541–553, 2014.
• [17] M. Ş. Tanyıldızı, “Modeling of adsorption isotherms and kinetics of reactive dye from aqueous solution by peanut hull”, Chemical Engineering Journal, vol. 168, no. 3, pp. 1234–1240, 2011.
• [18] B. Zhao, W. Xiao, Y. Shang, H. Zhu, R. Han, “Adsorption of light green anionic dye using cationic surfactant-modified peanut husk in batch mode”, Arabian Journal of Chemistry, vol. 10, no.2, pp. S3595–S3602, 2017.
• [19] E. H. Gürkan, S. Çoruh, Yeni Potansiyel Biosorbentlerle Kongo Kırmızısının Biosorpsiyon Çalışmaları, Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 10 no. 2, pp. 203-212, 2017.
• [20] Z. Zhang, Y. Li, Q. Du, Q. Li, “Adsorption of congo red from aqueous solutions by porous soybean curd Xerogels”, Polish Journal of Chemical Technology, vol. 20, no. 3, pp. 95-102, 2018.
• [21] H. Nadi, M. Alizadeh, M. Ahmadabadi, A. R. Yari, S. Hashemi, “Removal of Reactive Dyes (Green, Orange, and Yellow) from Aqueous Solutions by Peanut Shell Powder as a Natural Adsorbent”, Arch Hyg Sci.,vol. 1, no.2, pp. 41-47. 2012.
• [22] N. Tahir, H. N. Bhatti, M. Iqbal, S. Noreen, “Biopolymers composites with peanut hull waste biomass and application for Crystal Violet adsorption”, International Journal of Biological Macromolecules, vol. 94, pp. 210–220, 2017.
• [23] A. Samil, B. Acemioğlu, G. Gültekin, M. H. Alma, “Removal of Remazol Orange RGB from Aqueous Solution by Peanut Shell”, Asian Journal of Chemistry, vol. 23, no.7, pp. 3224-3230, 2011.
• [24] V. S. Munagapati, D. S. Kim, “Adsorption of anionic azo dye Congo Red from aqueous solution by Cationic Modified Orange Peel Powder”, Journal of Molecular Liquids, vol. 220, pp.540–548, 2016.