Investigation of the Inhibition Effect of 2-ethyl-4-methyl-1,3-thiazole-5-carboxylic Acid Against Corrosion

Yıl 2022, Cilt: 9 Sayı: 2, 1110 - 1121, 31.12.2022

Mehmet Erman Mert

https://doi.org/10.35193/bseufbd.1117801

Cited By: 1

Öz

In this study, electrochemical and theoretical approaches were used to explore the inhibitory characteristics of 2-ethyl-4-methyl-1,3-thiazole-5-carboxylic acid (2E4MT5C) against the corrosion behavior of mild steel in 0.5 M HCl solution. During a 7days immersion time in HCl solutions with and without 5 mM 2E4MT5C, electrochemical impedance spectroscopy (EIS) measurements and polarization curves were obtained. The adsorption equilibrium constant and adsorption free energy were determined by drawing the adsorption isotherm using the data obtained from the EIS measurements performed for 1 hour immersion time in HCl solutions containing 2E4MT5C at different concentrations (0.5; 1; 3 and 5 mM).To demonstrate the relationship between molecular structure and electrochemical behavior, and to study the adsorption process, experimental data were compared to theoretical parameters. According to the results obtained for the 1-hour immersion time, the resistance values for MS were 39 ..cm2 in the absence of 2E4MT5C and 195,3 .cm2 in the presence. According to the results obtained for the 7-days immersion period, the resistance values for MS are 9.8 .cm2 in the absence of 2E4MT5C and 38.3 .cm2 in the presence. Theoretically calculated EHOMO and ELUMO values are -6.89 eV and -1.78 eV. The dipole moment was determined as 5.96 Debye. According to the findings, 2E4MT5C offers significant protection against mild steel corrosion.

Anahtar Kelimeler

Corrosion, 2-ethyl-4-methyl-1,3-thiazol-5-carboxylic acid, DFT, EIS

2-etil-4-metil-1,3-tiyazol-5-karboksilik Asitin Korozyona Karşı İnhibisyon Etkisinin İncelenmesi

Öz

Bu çalışmada, 2-etil-4-metil-1,3-tiyazol-5-karboksilik asitin (2E4MT5C) 0,5 M HCl çözeltisinde yumuşak çeliğin (MS) korozyon davranışına karşı inhibitör özellikleri elektrokimyasal ve teorik yöntemlerle araştırılmıştır. 7 günlük daldırma süresi boyunca 2E4MT5C içermeyen ve 5 mM 2E4MT5C içeren HCl çözeltilerinde elektrokimyasal impedans spektroskopi (EIS) ölçümleri ve polarizasyon eğrileri elde edildi. Farklı derişimlerde (0,5; 1; 3 ve 5 mM) 2E4MT5C içeren HCl çözeltilerinde 1 saatlik daldırma süresi için gerçekleştirilen EIS ölçümlerinden elde edilen veriler vasıtasıyla adsorpsiyon izotermi çizilerek, adsorpsiyon denge sabiti ve adsorpsiyon serbest enerjisi belirlendi. Moleküler yapı ile elektrokimyasal davranış arasında ilişki kurmak ve adsorpsiyon mekanizmasını araştırmak için deneysel sonuçlar teorik parametrelerle karşılaştırıldı. 1 saatlik daldırma süresi için elde edilen sonuçlara göre, MS için polarizasyon direnci değerleri 2E4MT5C yokluğunda 39 .cm2 ve mevcudiyetinde ise 195,3 .cm2 dir. 7 günlük daldırma süresi için elde edilen sonuçlara göre, MS için direnç değerleri 2E4MT5C yokluğunda 9,8 .cm2 ve mevcudiyetinde ise 38,3 .cm2 dir. Teorik olarak hesaplanan HOMO ve LUMO değerleri -6,89 eV ve -1,78 eV dir. Dipol moment 5,96 Debye olarak belirlenmiştir. Elde edilen sonuçlara göre 2E4MT5C'nin yumuşak çelik korozyonuna karşı etkin koruma sağladığı görülmüştür.

Anahtar Kelimeler

Korozyon, 2-etil-4-metil-1,3-tiyazol-5-karboksilik asit, DFT, EIS

Kaynakça

• Salcı A., Yüksel H.&Solmaz R., (2022). Experimental studies on the corrosion inhibition performance of 2-(2-aminophneyl)benzimidazole for mild steel protection in 1 M HCl solution, Journal of the Taiwan Institute of Chemical Engineers, 134 104349.
• Nayak P., Kumari P P.&Rao S. A., (2022). Electrochemical approach to interfacial adsorption and inhibitory performance of (2E)-2- [(IH-Imidazole 2yl) methylidene] Hydrazine1-carbothioamide for corrosion mitigation, Chemical Data Collections, 38.
• Alamry K. A., Aslam R., Khan A., Hussein M. A.&Tashkandi N. Y., (2022). Evaluation of corrosion inhibition performance of thiazolidine-2,4-diones and its amino derivative: Gravimetric, electrochemical, spectroscopic, and surface morphological studies, Process Safety and Environmental Protection, 159 178-197.
• Tiwari N., Mitra R. K.&Yadav M., (2021). Corrosion protection of petroleum oil well/tubing steel using thiadiazolines as efficient corrosion inhibitor: Experimental and theoretical investigation, Surfaces and Interfaces, 22 100770.
• Oubaaqa M. et al., (2021). Insight into the corrosion inhibition of new amino-acids as efficient inhibitors for mild steel in HCl solution: Experimental studies and theoretical calculations, Journal of Molecular Liquids, 334.
• Dil G., Göksenli A., Yüksel B.&Muhaffel F., (2020). Isıl İşlemin Akımsız Ni-B/Ni-B-W Dubleks Kaplamanın Korozyon Direncine Etkisinin Analiz Edilmesi, Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, 7 (2).
• Gong W., Yin X., Liu Y., Chen Y.&Yang W., (2019). 2-Amino-4-(4-methoxyphenyl)-thiazole as a novel corrosion inhibitor for mild steel in acidic medium, Progress in Organic Coatings, 126 150-161.
• Gong W., Xu B., Yin X., Liu Y., Chen Y.&Yang W., (2019). Halogen-substituted thiazole derivatives as corrosion inhibitors for mild steel in 0.5 M sulfuric acid at high temperature, Journal of the Taiwan Institute of Chemical Engineers, 97 466-479.
• Zhang J. et al., (2021). Combining experiment and theory researches to insight into anti-corrosion nature of a novel thiazole derivatives, Journal of the Taiwan Institute of Chemical Engineers, 122 190-200.
• Hou Y., Zhu L., He K., Yang Z., Ma S.&Lei J., (2022). Synthesis of three imidazole derivatives and corrosion inhibition performance for copper, Journal of Molecular Liquids, 348.
• El Ibrahimi B., Baddouh A., Oukhrib R., El Issami S., Hafidi Z.&Bazzi L., (2021). Electrochemical and in silico investigations into the corrosion inhibition of cyclic amino acids on tin metal in the saline environment, Surfaces and Interfaces, 23.
• Pal S., Ji G., Lgaz H., Chung I.-M.&Prakash R., (2020). Lemon seeds as green coating material for mitigation of mild steel corrosion in acid media: Molecular dynamics simulations, quantum chemical calculations and electrochemical studies, Journal of Molecular Liquids, 316.
• Machado Fernandes C. et al., (2020). Use of a theoretical prediction method and quantum chemical calculations for the design, synthesis and experimental evaluation of three green corrosion inhibitors for mild steel, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 599.
• Farahati R., Ghaffarinejad A., Mousavi-Khoshdel S. M., Rezania J., Behzadi H.&Shockravi A., (2019). Synthesis and potential applications of some thiazoles as corrosion inhibitor of copper in 1 M HCl: Experimental and theoretical studies, Progress in Organic Coatings, 132 417-428.
• Bhaskaran, Pancharatna P. D., Lata S.&Singh G., (2019). Imidazolium based ionic liquid as an efficient and green corrosion constraint for mild steel at acidic pH levels, Journal of Molecular Liquids, 278 467-476.
• Ongun Yüce A., Doğru Mert B., Kardaş G.&Yazıcı B., (2014). Electrochemical and quantum chemical studies of 2-amino-4-methyl-thiazole as corrosion inhibitor for mild steel in HCl solution, Corrosion Science, 83 310-316.
• Thakur A.&Kumar A., (2020). A Review On Thiazole Derivatives As Corrosion Inhibitors For Metals And Their Alloys, European Journal of Molecular & Clinical Medicine, 07 (07), 3702-3712.
• Sigma Aldrich. (2020). Safety Data Sheet. https://www.sigmaaldrich.com/TR/en/sds/aldrich/cbr00267.
• Manivel A., Ramkumar S., Wu J. J., Asiri A. M.&Anandan S., (2014). Exploration of (S)-4,5,6,7-tetrahydrobenzo[d]thiazole-2,6-diamine as feasible corrosion inhibitor for mild steel in acidic media, Journal of Environmental Chemical Engineering, 2 (1), 463-470.
• Abd El-Lateef H. M., Sayed A. R.&Shalabi K., (2022). Studying the effect of two isomer forms thiazole and thiadiazine on the inhibition of acidic chloride-induced steel corrosion: Empirical and Computer simulation explorations, Journal of Molecular Liquids, 356.
• Soltani N., Tavakkoli N., Khayat Kashani M., Mosavizadeh A., Oguzie E. E.&Jalali M. R., (2014). Silybum marianum extract as a natural source inhibitor for 304 stainless steel corrosion in 1.0 M HCl, Journal of Industrial and Engineering Chemistry, 20 (5), 3217-3227.
• Fattah-alhosseini A.&Noori M., (2016). Corrosion inhibition of SAE 1018 carbon steel in H2S and HCl solutions by lemon verbena leaves extract, Measurement, 94 787-793.
• Bagga M. K., Gadi R., Yadav O. S., Kumar R., Chopra R.&Singh G., (2016). Investigation of phytochemical components and corrosion inhibition property of Ficus racemosa stem extract on mild steel in H2SO4 medium, Journal of Environmental Chemical Engineering, 4 (4), 4699-4707.
• Fouda A. S., Al-bonayan A. M., Eissa M., Eid D. M., (2022). Electrochemical and quantum chemical studies on the corrosion inhibition of 1037 carbon steel by different types of surfactants, RSC Advances, 12, 3253-3273.
• Nazari M. H., Shihab M. S., Havens E. A., Shi X., (2020). Mechanism of corrosion protection in chloride solution by an apple-based green inhibitor: experimental and theoretical studies, Journal of Infrastructure Preservation and Resilience, 1 (7), 1-19.
• El aoufir Y. et al., (2020). Evaluation of inhibitive and adsorption behavior of thiazole-4-carboxylates on mild steel corrosion in HCl, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 606-618.
• Özkır D.&Kayakırılmaz K., (2020). The Inhibitor Effect of (E)-5-[(4-(benzyl(methyl)amino)phenyl)diazenyl]-1,4-dimethyl-1H-1,2,4-triazol-4-ium zinc(II) Chloride, an Industrial Cationic Azo Dye, onto Reducing Acidic Corrosion Rate of Mild Steel, Journal of Electrochemical Science and Technology, 11 (3), 257-272.
• Berisha A., (2020). Experimental, Monte Carlo and Molecular Dynamic Study on Corrosion Inhibition of Mild Steel by Pyridine Derivatives in Aqueous Perchloric Acid, Electrochem, 1 (2), 188-199.
• Berisha A., Podvorica F. I., Mehmeti V., Syla F.&Vataj D., (2015). Theoretical and Experimental Studies of The Corrosion Behavior of Some Thiazole Derivatives Toward Mild Steel in Sulfuric Acid Media, Macedonian Journal of Chemistry and Chemical Engineering, 34 (2), 1-8.
• Hegazy M. A., Hegazy M. M., Awad M. K.&Shawky M., (2021). Chemical, electrochemical, theoretical (DFT & MEP), thermodynamics and surface morphology studies of carbon steel during gas and oil production using three novel di-cationic amphiphiles as corrosion inhibitors in acidic medium, Journal of Molecular Liquids, 337.
• Sagdinc S. G., Zor S.&Yıldız E., (2018). Corrosion Inhibition on Stainless Steel of Benzamide and Thioacetamide and Quantum Chemical Studies on The Density Functional Theory XVth International Corrosion Symposium, 266-286.
• Tüzün B.&Bhawsar J., (2021). Quantum chemical study of thiaozole derivatives as corrosion inhibitors based on density functional theory, Arabian Journal of Chemistry, 14 (2).
• Ansari K. R., Quraishi M. A.&Singh A., (2015). Corrosion inhibition of mild steel in hydrochloric acid by some pyridine derivatives: An experimental and quantum chemical study, Journal of Industrial and Engineering Chemistry, 25 89-98.
• Doğru Mert B., (2017). Yumuşak Çeliğin Korozyon Davranışı, Çukurova Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 32 (2), 145-152.
• Kosari A. et al., (2014). Electrochemical and quantum chemical assessment of two organic compounds from pyridine derivatives as corrosion inhibitors for mild steel in HCl solution under stagnant condition and hydrodynamic flow, Corrosion Science, 78 138-150.