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Recovery Cu ad Ce from copper slag by using flotation and chemical methods

Yıl 2022, , 17 - 26, 05.12.2022
https://doi.org/10.19111/bulletinofmre.1139294

Öz

Slag, which is now considered as a secondary source, attracts attention due to the metallic values they contain. Copper slags having economical operating grades in terms of Zn, Cu, Ce, Ni, Co, Mo, and V show complex mineralogy due to its thermal processing history. Various methods for the recovery of copper and other precious metals from this byproduct have been studied, and there are many operating flotation plants in industrial scale. However, in cases where physical or physo-chemical mineral processing methods are not sufficient, hydrometallurgical methods are applied. In this study, flotation was applied to copper slag with 0.9% Cu grade. Copper recovery and concentrate grade were found as around 40 and 22.7% Cu, respectively. Further, metal extractions were examined by conducting direct leaching tests. Gel formation was observed, when H2SO4was used in the leach process, therefore, the leach parameters were investigated using HCl. Cu and Ce extractions of around 70-80% were reached as a result of a test performed for 2 hours with the addition of 25 g/L H2O2 at a rate of 20-25% solids and 300 g/L HCl concentration. When the relationship of dissolved metals with each other wasexamined, dissolution behavior of Cu and Ce was quite similar to Al dissolution (R2=0.9).

Kaynakça

  • Altundoğan, H. S, Tümen, F. 1997. Metal recovery from copper converter slag by roasting with ferric sulphate. Hydrometallurgy 44, 261-267.
  • Altundogan, H. S, Boyrazlı, M., Tumen, F. 2004. A study on the sulphuric acid leaching of copper converter slag in the presence of dichromate. Minerals Engineering 17, 465-467.
  • Altundoğan, H. S, Turan, D. 2012. Bakır converter cürufundan değerli metallerin kükürt kavurması - su liçi yöntemiyle geri kazanılması. Fırat Üniversitesi Mühendislik Bilimleri Dergisi 24(1), 37-44.
  • Arslan, C., Arslan, F. 2002. Recovery of copper, cobalt, and zinc from copper smelter and converter slag, Hydrometallurgy 67, 1-7.
  • Banza, A. N., Gock, E., Kongolo, K. 2002. Base metals recovery from copper smelter slag by oxidising leaching and solvent extraction, Hydrometallurgy 63(1-3).
  • Basir, Abdel, Rabah, S. M., Mahmoud, A. 1999. Hydrometallurgical recovery of metal values from brass melting slag, Hydrometallurgy 53, 31–44.
  • Beşe, A. 2017. Bakır cüruflarından metallerin kazanılması. Sinop University 2, 140-149.
  • Beşe, A. V. 2007. Effect of ultrasound on the dissolution of copper from copper converter slag by acid leaching, Ultrasonics Sonochemistry 14, 290-296.
  • Chen, M. S., Han, Z. R., Wang, L. Z. 2011. Recovery of valuable metals from copper slag by hydrometallurgy. Advanced Materials Research 402, 35–40.
  • Çakır, M., Kartal, M., Gül, H., Taşkın, E., Uysal, M., Aydın, A. O., Alp, A. 2016. Bakır rafinasyon curufu flotasyon atıklarındaki bakırın geri kazanımı. Akademik Platform, 200-207.
  • Dimitrijevic, M., Urosevic, D., Milic, S., Sokic, M., Markovic, R. 2017. Journal of Mining and Metallurgy. Metallurgy 53(3), 407-7.
  • Herreros, O., Quiroz, R, Manzano, E., Bou, C., Viňals, J. 1998. Copper extraction from reverberatory and flash furnace slags by chlorine leaching. Hydrometallurgy 49, 87-101.
  • Najimi, M., Sobhani, J., Pourkhorshidi, A. R. 2011. Durability of copper slag contained concrete exposed to sulfate attack. Construction and Building Materials 25(4), 1895-1905.
  • Sanchez, M. Sudbury, M. 2013. Physicochemical characterization of copper slag and alternatives of friendly environmental management. Journal of Mining and Metallurgy, Section B: Metallurgy 49(2), 161-168.
  • Schlesinger, M. E., King, M. J., Sole, K. C., Davenport, W. G. 2011. Extractive Metallurgy of Copper. Elsevier Ltd., UK, 13.
  • Uzkut, İ., Tunçer, F. 1981. KBİ Samsun izebe cüruf ve flotasyon artıklarının metal içeriği ve değerlendirilmesi. Türkiye Bilimsel Madencilik ve Teknik 7, 295-318.
  • Yao, Y., Zhu, M., Zhao, Z., Tong, B., Fan, Y., Hua, Z. 2018. Hydrometallurgical processes for recycling spent lithium- ion batteries: a critical review, ACS Sustainable Chemistry and Engineering 6(11), 13611–13627.
  • Yılmaz, K. C. 2018. Bakır cürufu flotasyonunda iki farklı toplayıcı kullanımının üç tane boyları verimlerine etkisinin incelenmesi. Yüksek Lisans Tezi, Hacettepe Üniversitesi, Maden Mühendisliği Bölümü.
Yıl 2022, , 17 - 26, 05.12.2022
https://doi.org/10.19111/bulletinofmre.1139294

Öz

Kaynakça

  • Altundoğan, H. S, Tümen, F. 1997. Metal recovery from copper converter slag by roasting with ferric sulphate. Hydrometallurgy 44, 261-267.
  • Altundogan, H. S, Boyrazlı, M., Tumen, F. 2004. A study on the sulphuric acid leaching of copper converter slag in the presence of dichromate. Minerals Engineering 17, 465-467.
  • Altundoğan, H. S, Turan, D. 2012. Bakır converter cürufundan değerli metallerin kükürt kavurması - su liçi yöntemiyle geri kazanılması. Fırat Üniversitesi Mühendislik Bilimleri Dergisi 24(1), 37-44.
  • Arslan, C., Arslan, F. 2002. Recovery of copper, cobalt, and zinc from copper smelter and converter slag, Hydrometallurgy 67, 1-7.
  • Banza, A. N., Gock, E., Kongolo, K. 2002. Base metals recovery from copper smelter slag by oxidising leaching and solvent extraction, Hydrometallurgy 63(1-3).
  • Basir, Abdel, Rabah, S. M., Mahmoud, A. 1999. Hydrometallurgical recovery of metal values from brass melting slag, Hydrometallurgy 53, 31–44.
  • Beşe, A. 2017. Bakır cüruflarından metallerin kazanılması. Sinop University 2, 140-149.
  • Beşe, A. V. 2007. Effect of ultrasound on the dissolution of copper from copper converter slag by acid leaching, Ultrasonics Sonochemistry 14, 290-296.
  • Chen, M. S., Han, Z. R., Wang, L. Z. 2011. Recovery of valuable metals from copper slag by hydrometallurgy. Advanced Materials Research 402, 35–40.
  • Çakır, M., Kartal, M., Gül, H., Taşkın, E., Uysal, M., Aydın, A. O., Alp, A. 2016. Bakır rafinasyon curufu flotasyon atıklarındaki bakırın geri kazanımı. Akademik Platform, 200-207.
  • Dimitrijevic, M., Urosevic, D., Milic, S., Sokic, M., Markovic, R. 2017. Journal of Mining and Metallurgy. Metallurgy 53(3), 407-7.
  • Herreros, O., Quiroz, R, Manzano, E., Bou, C., Viňals, J. 1998. Copper extraction from reverberatory and flash furnace slags by chlorine leaching. Hydrometallurgy 49, 87-101.
  • Najimi, M., Sobhani, J., Pourkhorshidi, A. R. 2011. Durability of copper slag contained concrete exposed to sulfate attack. Construction and Building Materials 25(4), 1895-1905.
  • Sanchez, M. Sudbury, M. 2013. Physicochemical characterization of copper slag and alternatives of friendly environmental management. Journal of Mining and Metallurgy, Section B: Metallurgy 49(2), 161-168.
  • Schlesinger, M. E., King, M. J., Sole, K. C., Davenport, W. G. 2011. Extractive Metallurgy of Copper. Elsevier Ltd., UK, 13.
  • Uzkut, İ., Tunçer, F. 1981. KBİ Samsun izebe cüruf ve flotasyon artıklarının metal içeriği ve değerlendirilmesi. Türkiye Bilimsel Madencilik ve Teknik 7, 295-318.
  • Yao, Y., Zhu, M., Zhao, Z., Tong, B., Fan, Y., Hua, Z. 2018. Hydrometallurgical processes for recycling spent lithium- ion batteries: a critical review, ACS Sustainable Chemistry and Engineering 6(11), 13611–13627.
  • Yılmaz, K. C. 2018. Bakır cürufu flotasyonunda iki farklı toplayıcı kullanımının üç tane boyları verimlerine etkisinin incelenmesi. Yüksek Lisans Tezi, Hacettepe Üniversitesi, Maden Mühendisliği Bölümü.
Toplam 18 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Bekir Başkurt Bu kişi benim 0000-0003-1715-8667

Mete Tayhan Serdengeçti Bu kişi benim 0000-0001-9651-2980

Kaan Özçelik Bu kişi benim 0000-0001-6476-5895

Hüseyin Baştürkçü Bu kişi benim 0000-0001-7301-9317

Yayımlanma Tarihi 5 Aralık 2022
Yayımlandığı Sayı Yıl 2022

Kaynak Göster

APA Başkurt, B., Serdengeçti, M. T., Özçelik, K., Baştürkçü, H. (2022). Recovery Cu ad Ce from copper slag by using flotation and chemical methods. Bulletin of the Mineral Research and Exploration, 169(169), 17-26. https://doi.org/10.19111/bulletinofmre.1139294
AMA Başkurt B, Serdengeçti MT, Özçelik K, Baştürkçü H. Recovery Cu ad Ce from copper slag by using flotation and chemical methods. Bull.Min.Res.Exp. Aralık 2022;169(169):17-26. doi:10.19111/bulletinofmre.1139294
Chicago Başkurt, Bekir, Mete Tayhan Serdengeçti, Kaan Özçelik, ve Hüseyin Baştürkçü. “Recovery Cu Ad Ce from Copper Slag by Using Flotation and Chemical Methods”. Bulletin of the Mineral Research and Exploration 169, sy. 169 (Aralık 2022): 17-26. https://doi.org/10.19111/bulletinofmre.1139294.
EndNote Başkurt B, Serdengeçti MT, Özçelik K, Baştürkçü H (01 Aralık 2022) Recovery Cu ad Ce from copper slag by using flotation and chemical methods. Bulletin of the Mineral Research and Exploration 169 169 17–26.
IEEE B. Başkurt, M. T. Serdengeçti, K. Özçelik, ve H. Baştürkçü, “Recovery Cu ad Ce from copper slag by using flotation and chemical methods”, Bull.Min.Res.Exp., c. 169, sy. 169, ss. 17–26, 2022, doi: 10.19111/bulletinofmre.1139294.
ISNAD Başkurt, Bekir vd. “Recovery Cu Ad Ce from Copper Slag by Using Flotation and Chemical Methods”. Bulletin of the Mineral Research and Exploration 169/169 (Aralık 2022), 17-26. https://doi.org/10.19111/bulletinofmre.1139294.
JAMA Başkurt B, Serdengeçti MT, Özçelik K, Baştürkçü H. Recovery Cu ad Ce from copper slag by using flotation and chemical methods. Bull.Min.Res.Exp. 2022;169:17–26.
MLA Başkurt, Bekir vd. “Recovery Cu Ad Ce from Copper Slag by Using Flotation and Chemical Methods”. Bulletin of the Mineral Research and Exploration, c. 169, sy. 169, 2022, ss. 17-26, doi:10.19111/bulletinofmre.1139294.
Vancouver Başkurt B, Serdengeçti MT, Özçelik K, Baştürkçü H. Recovery Cu ad Ce from copper slag by using flotation and chemical methods. Bull.Min.Res.Exp. 2022;169(169):17-26.

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