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The Mineralogic, Petrographic and Ion Exchange Capacity Features Of Tuffs Containing Chabazite and Phillipsite Minerals In Sandıklı (Afyon) Region and Their Usage In Agriculture (Southwest Anatolia, Turkey)

Yıl 2008, Cilt: 137 Sayı: 137, 29 - 48, 01.06.2008

Öz

The study area is located in southern part of Sandýklý town (Afyon-southwest Anatolia). The volcanics of Sandıklıý region in the investigated area are represented by lavas and pyroclastic rocks of Middle-Late Miocene age. The Lavas occur as trachyandesitic, phonolitic tephritic, basaltic andesitic, basaltic trachy-nephelinitic, andesitic and dacitic in compositions. Pyroclastic rocks are composed of lapillistone, tuffaceous conglomerate, tuffaceous sandstone, tuffaceous siltstone and tuffaceous mudstone, and also have vitric and crystal vitric tuffs in thrachyandesitic, phonolitic and tephritic compositions. In the tuffs located at the northern part of the investigated area the chabazite occurrences, and in the tuffs located at the southern part the phillipsite occurrences are found widespread. In phillipsitic tuffs, three-phillipsite forms were defined namely potassium-sodium-aluminum-silicate hydrate, sodium-aluminium-silicate hydrate and potassium-calcium-aluminum-silicate hydrate froms. In tuff samples purified with tetrabrom ethane the zeolite contents by weight mostly between 29.00 wt.% and 63.00 wt.%. After the activation of the tuff samples with 0.1N HCl and 0.1N H2SO4, their cation exchange features were investigated. In the tuffs activated with both acids, Ca+2 content with respect to other cation contents has been passed too much to the solutions depending on time. But those activated with 0.1N HCl, as depending on time, Ca+2 content has been passed as more linear to the solutions. When we consider of ion exchange capacity and selection of the radioactive cations such as 137Cs and 90Sr and 40K of chabazite and phillipsite, zeolitic tuffs may be used for the improvement of soil, stabilization of pH of acidic soils and to prevent to the passing of the radioactive elements from nature to the environment and biological systems. Because of activated natural zeolites tend to the increase of the resorption and adsorption of moisture which contributes to the plant development, activated natural zeolitic tuffs may be used as desiccants. For the adsorption of the ammonium smells arisen from urine and faecal matter, it is thought that zeolitic tuffs may be used to separate methane from other gasses. Besides, it is believed that it is possible to use them as building stone for heating and air conditioner for small houses and animal shelters.

Kaynakça

  • Afşin, M.,1991. Afyon-Sandıklı Kuruçay Ovası ve Hüdai Kaplıcasının Hidrojeolojik Incelemesi (Hydrogeological investigation of the Afyon- Sandıklı Kuruçay plain and Hüdai hot-spring). Ankara Üniversitesi, Fen Bilimleri Enstitüsü, Doktora Tezi, Ankara. 329p (unpublished).
  • Aydar, E., Bayhan, H., and Zimitoğlu, O., 1996. Investigation of volcanological and petrological evolution of Afyon stratovolcano, Hacettepe University, Bulletin of Earth Sciene Applied and Research Center 18, 87-107.
  • Aydar, E., Bayhan, H., and Gougaud, A., 2003. Lamprophyres of Afyon Stratovolcano, Western Anatolia, Turkey, desription and genesis. Comptes Rendusde I'Academie des Sciences 335, 279- 288.
  • Başarır, E., and Kun, N., 1982. Afyon Kalesi çevresindeki volkanitlerin petrografik incelemesi (Pet- rographic investigation of the volcanics around the Afyon castle). KTÜ Yerbilimleri Derg., Trabzon, 26, 27-36.
  • Besang, C., Eckahtrdt, F.J., Harre, W., Kreuzer, H., and Müller, P., 1977, Radiometricshe Al- tersbesttimmungen der Türkei, Geol. Jb. B., 25, 3-5.
  • Bulutçu, C., 1975. Afyon-Sandıklı, Hüdai kaplıcası hidrojeolojik etüdü (Hydrogeological investiga- tion of the Hudai hot-spring of Afyon-Sandıklı). Ankara, MTA Report No: 3321, (unpublished).
  • Çoban, H., and Flower M.F.J, 2007. Late Pliocene Lambroites from Bucak, Isparta (Soutwesthern Turkey): Implications for mantle "Wedge" evolution during Africa-Anatolian plate convergence, Journal of Asian Earth Sciences, 29, 160-176.
  • Epik, Ö., and Yaprak., G., 2003. Kozaklı Çam Ormanlarında 7Be, 40K ve 137Cs Aktivite Dağılımları (The distribution of the 7Be, 40K ve 137Cs activities in the pine forests of Kozaklı), VIII. Ulusal Nükleer Bilimleri ve Teknoloji Kongresi, Bildiri Metni, 15-17 Ekim, Kayseri.
  • Ercan, T., 1986. Orta Anadolu'daki Senozoyik Volkanizması (Cenozoic volcanism of the Central Anatolia). MTA Bulletin. 107,119-141.
  • Esenli, F., 2006. Piroklastik kayalarda zeolit içeriği ile amonyum değişim kapasitesi arasındaki ilişki: Türkiye'den örnekler (The relation between the zeolite contents of pyroclastic rocks and ammonium-exchange capacity: examples from Turkey), Kibited, Kil Bilimleri ve Teknoloji Dergisi, 1(2), 9-19.
  • Fisher, R.V., and Schminke, H.U.,1984. Pyroclastic Rocks, Springer Verlag, 472 p, Berlin.
  • Folk, R., 1962. Classification of carbonate rocks; Assoc. Petroleum Geologist, Mem.,1, 62-82.
  • Gür, F., and Yaprak, G., 2003. Gediz havzasında radyosezyum dağılımı (The radiocaesium dist- ribution of the Gediz basin), VIII. Ulusal Nükleer Bilimleri ve Teknoloji Kongresi, Bildiri Metni, Kayseri, 15-17 Ekim, 2003.
  • Keller, J., 1983. Potasic lavas in Orogenic Volcanisim of Mediterranean Area, J. Volcanol. Geother- mal Res. 18(36), 321-335.
  • Mikayilov, D.F., and Acar, B., 1998. Toprak ekosistemlerinde kirleticilerin tanım mekanizmasının incelenmesi ve modellenmesi (The investigation and modeling of the pollutants in the soil ecosystems), Ekoloji, 7(28), 20-23.
  • Minato, H., 1992. Methods for measurement of zeolite amount. Naturel Zeolite and its utilization, Inter- national Symposium, Japan, 401 p.
  • Öngür, T., 1973. Sandıklı (Afyon) jeotermal araştırma bölgesine ilişkin jeolojik durum ve jeotermal enerji olanakları (The geology and the geother- mal energy possibilities of the Sandıklı geothermal region), MTA Report No:5520, Ankara (unpublised).
  • Özpınar, Y., 1998. Sandıklı (Afyon) volkanitlerinin jeolojik, petrografik ve petrokimyasal inceleme- si ve tras olarak değerlendirilmesi (The investi- gation of the petrographic, petrochemical pro- perties of the Sandıklı volcanic and their evaluation as trass material), (AR-GE Proje No:97 MHF.006.Jeo.002-3, Denizli 38 p.
  • Özpınar, Y., 2001. Petrographical and petrochemical investigation of Sandıklı volcanic and usabilty of this rocks as trass, in Afyon region (Western Anatolia), Turkey, 9ThInternational Congress of The Geologıcal Society of Greece, Atina, Volume, 3, 959-967.
  • Ronner, F., 1962. Sandıklı ovası çöküntüsü, genç tektonik ve volkanik durumlar (The Sandıklı depression and, tectonics and volcanism), 59, 69-88.
  • Schmidt, R., 1981. Descriptive nomenclature and classification of pyroclastic deposits and fragments: Recommendations of the IUGS Subcomission on the Systematics of Igneous Rocks. Geology 9, 41-44.
  • Tsitsishvili, G.V., Andronikashvili, T.G., Kırov G.N., Filizova, L.G., Potashnikov I.B., and Williams P.A., 1992. Natural Zeolite, Ellis Horwood, Singapore, 293p.
  • Tolluoğlu, Ü. A., Erkan, Y., Sümer., Ö.E., Boyacı, N.M., and Yavaş (Bektaş), F., 1997. Afyon metasedi- menter grubunun Mesozoyik öncesi metamorfik evrimi (The pre-Mesozoic metamorphic evolution of the Afyon Metasedimentary Group), Türkiye Jeoloji Bülteni, 40(2), 1-17.
  • Villari, L. and Keller, J., 1972. Rhyolitic ignimbrites in region of Afyon (Central Anatolia): Bull. Volcan., 36(4), 342-358.

The Mineralogic, Petrographic and Ion Exchange Capacity Features Of Tuffs Containing Chabazite and Phillipsite Minerals In Sandıklı (Afyon) Region and Their Usage In Agriculture (Southwest Anatolia, Turkey)

Yıl 2008, Cilt: 137 Sayı: 137, 29 - 48, 01.06.2008

Öz

The study area is located in southern part of Sandýklý town (Afyon-southwest Anatolia). The volcanics of Sandıklıý region in the investigated area are represented by lavas and pyroclastic rocks of Middle-Late Miocene age. The Lavas occur as trachyandesitic, phonolitic tephritic, basaltic andesitic, basaltic trachy-nephelinitic, andesitic and dacitic in compositions. Pyroclastic rocks are composed of lapillistone, tuffaceous conglomerate, tuffaceous sandstone, tuffaceous siltstone and tuffaceous mudstone, and also have vitric and crystal vitric tuffs in thrachyandesitic, phonolitic and tephritic compositions. In the tuffs located at the northern part of the investigated area the chabazite occurrences, and in the tuffs located at the southern part the phillipsite occurrences are found widespread. In phillipsitic tuffs, three-phillipsite forms were defined namely potassium-sodium-aluminum-silicate hydrate, sodium-aluminium-silicate hydrate and potassium-calcium-aluminum-silicate hydrate froms. In tuff samples purified with tetrabrom ethane the zeolite contents by weight mostly between 29.00 wt.% and 63.00 wt.%. After the activation of the tuff samples with 0.1N HCl and 0.1N H2SO4, their cation exchange features were investigated. In the tuffs activated with both acids, Ca+2 content with respect to other cation contents has been passed too much to the solutions depending on time. But those activated with 0.1N HCl, as depending on time, Ca+2 content has been passed as more linear to the solutions. When we consider of ion exchange capacity and selection of the radioactive cations such as 137Cs and 90Sr and 40K of chabazite and phillipsite, zeolitic tuffs may be used for the improvement of soil, stabilization of pH of acidic soils and to prevent to the passing of the radioactive elements from nature to the environment and biological systems. Because of activated natural zeolites tend to the increase of the resorption and adsorption of moisture which contributes to the plant development, activated natural zeolitic tuffs may be used as desiccants. For the adsorption of the ammonium smells arisen from urine and faecal matter, it is thought that zeolitic tuffs may be used to separate methane from other gasses. Besides, it is believed that it is possible to use them as building stone for heating and air conditioner for small houses and animal shelters.

Kaynakça

  • Afşin, M.,1991. Afyon-Sandıklı Kuruçay Ovası ve Hüdai Kaplıcasının Hidrojeolojik Incelemesi (Hydrogeological investigation of the Afyon- Sandıklı Kuruçay plain and Hüdai hot-spring). Ankara Üniversitesi, Fen Bilimleri Enstitüsü, Doktora Tezi, Ankara. 329p (unpublished).
  • Aydar, E., Bayhan, H., and Zimitoğlu, O., 1996. Investigation of volcanological and petrological evolution of Afyon stratovolcano, Hacettepe University, Bulletin of Earth Sciene Applied and Research Center 18, 87-107.
  • Aydar, E., Bayhan, H., and Gougaud, A., 2003. Lamprophyres of Afyon Stratovolcano, Western Anatolia, Turkey, desription and genesis. Comptes Rendusde I'Academie des Sciences 335, 279- 288.
  • Başarır, E., and Kun, N., 1982. Afyon Kalesi çevresindeki volkanitlerin petrografik incelemesi (Pet- rographic investigation of the volcanics around the Afyon castle). KTÜ Yerbilimleri Derg., Trabzon, 26, 27-36.
  • Besang, C., Eckahtrdt, F.J., Harre, W., Kreuzer, H., and Müller, P., 1977, Radiometricshe Al- tersbesttimmungen der Türkei, Geol. Jb. B., 25, 3-5.
  • Bulutçu, C., 1975. Afyon-Sandıklı, Hüdai kaplıcası hidrojeolojik etüdü (Hydrogeological investiga- tion of the Hudai hot-spring of Afyon-Sandıklı). Ankara, MTA Report No: 3321, (unpublished).
  • Çoban, H., and Flower M.F.J, 2007. Late Pliocene Lambroites from Bucak, Isparta (Soutwesthern Turkey): Implications for mantle "Wedge" evolution during Africa-Anatolian plate convergence, Journal of Asian Earth Sciences, 29, 160-176.
  • Epik, Ö., and Yaprak., G., 2003. Kozaklı Çam Ormanlarında 7Be, 40K ve 137Cs Aktivite Dağılımları (The distribution of the 7Be, 40K ve 137Cs activities in the pine forests of Kozaklı), VIII. Ulusal Nükleer Bilimleri ve Teknoloji Kongresi, Bildiri Metni, 15-17 Ekim, Kayseri.
  • Ercan, T., 1986. Orta Anadolu'daki Senozoyik Volkanizması (Cenozoic volcanism of the Central Anatolia). MTA Bulletin. 107,119-141.
  • Esenli, F., 2006. Piroklastik kayalarda zeolit içeriği ile amonyum değişim kapasitesi arasındaki ilişki: Türkiye'den örnekler (The relation between the zeolite contents of pyroclastic rocks and ammonium-exchange capacity: examples from Turkey), Kibited, Kil Bilimleri ve Teknoloji Dergisi, 1(2), 9-19.
  • Fisher, R.V., and Schminke, H.U.,1984. Pyroclastic Rocks, Springer Verlag, 472 p, Berlin.
  • Folk, R., 1962. Classification of carbonate rocks; Assoc. Petroleum Geologist, Mem.,1, 62-82.
  • Gür, F., and Yaprak, G., 2003. Gediz havzasında radyosezyum dağılımı (The radiocaesium dist- ribution of the Gediz basin), VIII. Ulusal Nükleer Bilimleri ve Teknoloji Kongresi, Bildiri Metni, Kayseri, 15-17 Ekim, 2003.
  • Keller, J., 1983. Potasic lavas in Orogenic Volcanisim of Mediterranean Area, J. Volcanol. Geother- mal Res. 18(36), 321-335.
  • Mikayilov, D.F., and Acar, B., 1998. Toprak ekosistemlerinde kirleticilerin tanım mekanizmasının incelenmesi ve modellenmesi (The investigation and modeling of the pollutants in the soil ecosystems), Ekoloji, 7(28), 20-23.
  • Minato, H., 1992. Methods for measurement of zeolite amount. Naturel Zeolite and its utilization, Inter- national Symposium, Japan, 401 p.
  • Öngür, T., 1973. Sandıklı (Afyon) jeotermal araştırma bölgesine ilişkin jeolojik durum ve jeotermal enerji olanakları (The geology and the geother- mal energy possibilities of the Sandıklı geothermal region), MTA Report No:5520, Ankara (unpublised).
  • Özpınar, Y., 1998. Sandıklı (Afyon) volkanitlerinin jeolojik, petrografik ve petrokimyasal inceleme- si ve tras olarak değerlendirilmesi (The investi- gation of the petrographic, petrochemical pro- perties of the Sandıklı volcanic and their evaluation as trass material), (AR-GE Proje No:97 MHF.006.Jeo.002-3, Denizli 38 p.
  • Özpınar, Y., 2001. Petrographical and petrochemical investigation of Sandıklı volcanic and usabilty of this rocks as trass, in Afyon region (Western Anatolia), Turkey, 9ThInternational Congress of The Geologıcal Society of Greece, Atina, Volume, 3, 959-967.
  • Ronner, F., 1962. Sandıklı ovası çöküntüsü, genç tektonik ve volkanik durumlar (The Sandıklı depression and, tectonics and volcanism), 59, 69-88.
  • Schmidt, R., 1981. Descriptive nomenclature and classification of pyroclastic deposits and fragments: Recommendations of the IUGS Subcomission on the Systematics of Igneous Rocks. Geology 9, 41-44.
  • Tsitsishvili, G.V., Andronikashvili, T.G., Kırov G.N., Filizova, L.G., Potashnikov I.B., and Williams P.A., 1992. Natural Zeolite, Ellis Horwood, Singapore, 293p.
  • Tolluoğlu, Ü. A., Erkan, Y., Sümer., Ö.E., Boyacı, N.M., and Yavaş (Bektaş), F., 1997. Afyon metasedi- menter grubunun Mesozoyik öncesi metamorfik evrimi (The pre-Mesozoic metamorphic evolution of the Afyon Metasedimentary Group), Türkiye Jeoloji Bülteni, 40(2), 1-17.
  • Villari, L. and Keller, J., 1972. Rhyolitic ignimbrites in region of Afyon (Central Anatolia): Bull. Volcan., 36(4), 342-358.
Toplam 24 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Yahya Özpınar Bu kişi benim

Yayımlanma Tarihi 1 Haziran 2008
Yayımlandığı Sayı Yıl 2008 Cilt: 137 Sayı: 137

Kaynak Göster

APA Özpınar, Y. (2008). The Mineralogic, Petrographic and Ion Exchange Capacity Features Of Tuffs Containing Chabazite and Phillipsite Minerals In Sandıklı (Afyon) Region and Their Usage In Agriculture (Southwest Anatolia, Turkey). Bulletin of the Mineral Research and Exploration, 137(137), 29-48.
AMA Özpınar Y. The Mineralogic, Petrographic and Ion Exchange Capacity Features Of Tuffs Containing Chabazite and Phillipsite Minerals In Sandıklı (Afyon) Region and Their Usage In Agriculture (Southwest Anatolia, Turkey). Bull.Min.Res.Exp. Haziran 2008;137(137):29-48.
Chicago Özpınar, Yahya. “The Mineralogic, Petrographic and Ion Exchange Capacity Features Of Tuffs Containing Chabazite and Phillipsite Minerals In Sandıklı (Afyon) Region and Their Usage In Agriculture (Southwest Anatolia, Turkey)”. Bulletin of the Mineral Research and Exploration 137, sy. 137 (Haziran 2008): 29-48.
EndNote Özpınar Y (01 Haziran 2008) The Mineralogic, Petrographic and Ion Exchange Capacity Features Of Tuffs Containing Chabazite and Phillipsite Minerals In Sandıklı (Afyon) Region and Their Usage In Agriculture (Southwest Anatolia, Turkey). Bulletin of the Mineral Research and Exploration 137 137 29–48.
IEEE Y. Özpınar, “The Mineralogic, Petrographic and Ion Exchange Capacity Features Of Tuffs Containing Chabazite and Phillipsite Minerals In Sandıklı (Afyon) Region and Their Usage In Agriculture (Southwest Anatolia, Turkey)”, Bull.Min.Res.Exp., c. 137, sy. 137, ss. 29–48, 2008.
ISNAD Özpınar, Yahya. “The Mineralogic, Petrographic and Ion Exchange Capacity Features Of Tuffs Containing Chabazite and Phillipsite Minerals In Sandıklı (Afyon) Region and Their Usage In Agriculture (Southwest Anatolia, Turkey)”. Bulletin of the Mineral Research and Exploration 137/137 (Haziran 2008), 29-48.
JAMA Özpınar Y. The Mineralogic, Petrographic and Ion Exchange Capacity Features Of Tuffs Containing Chabazite and Phillipsite Minerals In Sandıklı (Afyon) Region and Their Usage In Agriculture (Southwest Anatolia, Turkey). Bull.Min.Res.Exp. 2008;137:29–48.
MLA Özpınar, Yahya. “The Mineralogic, Petrographic and Ion Exchange Capacity Features Of Tuffs Containing Chabazite and Phillipsite Minerals In Sandıklı (Afyon) Region and Their Usage In Agriculture (Southwest Anatolia, Turkey)”. Bulletin of the Mineral Research and Exploration, c. 137, sy. 137, 2008, ss. 29-48.
Vancouver Özpınar Y. The Mineralogic, Petrographic and Ion Exchange Capacity Features Of Tuffs Containing Chabazite and Phillipsite Minerals In Sandıklı (Afyon) Region and Their Usage In Agriculture (Southwest Anatolia, Turkey). Bull.Min.Res.Exp. 2008;137(137):29-48.

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