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Investigation of dissolution behavior of scandium and lithium from red mud

Yıl 2022, Cilt: 167 Sayı: 167, 179 - 188, 20.04.2022
https://doi.org/10.19111/bulletinofmre.941073

Öz


In this study, scandium and lithium extractions were investigated using the atmospheric pressure agitation leaching method at acidic medium. The leaching tests were carried out at two stages. To remove the ionic impurities such as Na and Al first stage leaching was performed at relatively higher pH. Following solid-liquid separation of leach cake of the first stage leaching, it was subjected to the second stage leaching. The second stage leaching resulted in 95.1% Sc and 94.7% Li extractions. The overall Sc and Li recoveries were determined as 82.4% and 86.5%, respectively. Regarding the kinetic studies, it was understood that scandium and lithium leaching processes were controlled by a combination of chemical reaction and ash diffusion models. In this case, the activation energies were determined as 29.52 and 30.22 kJmol-1, respectively for scandium and lithium. As a result, while direct H2SO4 leaching of red mud is a challenge due to physical and chemical problems, an alternative solution was suggested using H2SO4

Kaynakça

  • Abdulvaliyev, R. A., Akcil, A., Gladyshev, S. V., Tastanov,E. A., Beisembekova, K. O., Akhmadiyeva, N. K., Deveci, H. 2015. Gallium and vanadium extraction from red mud of Turkish alumina refinery plant: hydrogarnet process. Hydrometallurgy 157, 72- 77.
  • Baral, S. S., Shekar, R. K., Viswanathan, V., Surendran, G. 2016. Dissolution kinetics of cerium from red mud, Separation Science and Technology 52(5), 883-891.
  • Baştürkcü, H. 2020. Extraction of lanthanum and yttrium from red mud following elimination of ionic impurities. Separation Science and Technology 56(13), 2243-2252.
  • Borra, C. R., Pontikes, Y., Binnemans, K., Gerven, V. T. 2015. Leaching of rare earths from bauxite residue (red mud). Minerals Engineering 76, 20-27.
  • Borra, C. R., Mermans, J., Blanpain, B., Pontikes, Y., Binnemans, K., Gerven, V. T. 2016. Selective recovery of rare earths from bauxite residue by combination of sulfation, roasting and leaching. Minerals Engineering 92, 151-159.
  • Chen, X., Lun, A., Qu, G. 2013. Preparation and characterization of foam ceramics from red mud and fly ash using sodium silicate as foaming agent. Ceramics International 39, 1923-1929.
  • Christmann, P., Gloaguen, E., Labbe, J. F., Melleton, J., Piantone, P. 2015. Global lithium resources and sustainability issues. Lithium Process Chemistry Resources, Extraction, Chapter 1. Batteries, and Recycling edited by Alexandre Chagnes and Jolanta Swiatowska, Elsevier.
  • Deng, B., Li, G., Luo, J., Ye, Q., Liu, M., Peng, Z., Jiang, T. 2017. Enrichment of Sc2O3 and TiO2 from bauxite ore residues. Journal of Hazardous Materials 331, 71-80.
  • Erçağ, E., Apak, R. 1997. Furnace smelting and extractive metallurgy of red mud: recovery of TiO2, Al2O3 and pig iron. Journal of Chemical Technology and Biotechnology 70, 241-246.
  • Evans, K. 2015. Successes and challenges in the management and use of bauxite residue. Bauxite Residue Valoris. Best Practice Conference, 113-127.
  • Fulford, G. D., Lever, G., Sato, T. 1991. Recovery of rare earth elements from Bayer process red mud. US5030424.
  • Gladyshev, S. V., Akcil, A., Abdulvaliyev, R. A., Tastanov, E. A., Beisembekova, K. O., Temirova, S. S., Deveci, H. 2015. Recovery of vanadium and gallium from solid waste by-products of Bayer process, Minerals Engineering 74, 91-98.
  • Hammond, K., Apelian, B. M. D., Blanpain, B. 2013. CR3 communication: red mud-a resource or a waste?. Journal of the Minerals Metals and Materials Society 65, 340-341.
  • Kumar, S., Kumar, R., Bandopadhyay, A. 2006. Innovative methodologies for the utilisation of wastes from metallurgical and allied industries. Resources, Conservation and Recycling 48, 301-314.
  • Liu, W., Sun, S., Zhang, L., Jahanshahi, S., Yang, J. 2012. Experimental and simulative study on phase transformation in Bayer red mud soda-lime roasting system and recovery of Al, Na and Fe. Minerals Engineering 39, 213-218.
  • Liu, Y., Lin, C., Wu, Y. 2007. Characterization of red mud derived from a combined Bayer process and bauxite calcination method. Journal of Hazardous Materials 146, 255-261.
  • Okudan, M. D., Akcil, A., Tuncuk, A., Deveci, H. 2015a. Effect of parameters on vanadium recovery from by-products of the Bayer process, Hydrometallurgy 152, 76-83.
  • Okudan, M. D., Akcil, A., Tuncuk, A., Deveci, H. 2015b. Recovery of gallium and aluminum from electrofilter dust of alumina calcination plant in Bayer process, Separation Science and Technology 50, 2596-2605.
  • Ochsenkuhn-Petropulu, M., Lyberopulu, T., Parissakis, G. 1995. Selective separation and determination of scandium from yttrium and lanthanides in red mud by a combined ion exchange/solvent extraction method. Analytic Chimica Acta 315, 231-237.
  • Ochsenkuhn-Petropulu, M., Lyberopulu, T., Ochsenkuhn, K. M., Parissakis, G. 1996. Recovery of lanthanides and yttrium from red mud by selective leaching. Analytic Chimica Acta 319, 249-254.
  • Smirnov, D. I., Molchanova, T. V. 1997. The investigation of sulphuric acid sorption recovery of scandium and uranium from the red mud of alumina production. Hydrometallurgy 45, 249-259.
  • Teixeira, I. F., Medeiros, T. P. V., Freitas, P. E., Rosmaninho, M. G., Ardisson, J. D., Lago, R. M. 2014. Carbon deposition and oxidation using the waste red mud: a route to store, transport and use offshore gas lost in petroleum exploration. Fuel 124, 7-13. Uzun, D., Gülfen, M. 2007. Dissolution kinetics of iron and aluminum from red mud in sulfuric acid solution. Indian Journal of Chemical Technology 14, 263- 268.
  • Verlaguet, A., Goff, B., Brunet, F., Poinssot, C., Vidal, O., Findling, N. 2011. Metamorphic veining and mass transfer in a chemically closed system: a case study in Alpine metabauxites (western Vanoise). Journal of Metamorphic Geology 29, 275-300.
  • Wang, D. H, Li, P. G, Qu, W. J, Yin, L. J., Zhao, Z., Lei,Z. Y. 2013a. Discovery and preliminary study of the high tungsten and lithium contents in the Dazhuyuan bauxite deposit, Guizhou, China. Science China Earth Sciences 56(1), 145-152.
  • Wang, W., Pranolo, Y., Cheng, C. Y. 2013b. Recovery of scandium from synthetic red mud leach solutions by solvent extraction with D2EHPA. Separation and Purification Technology 108, 96-102.
  • Wang, H. H., Li, G. Q., Zhao, D., Ma, J. H., Yang, J. 2017. Dephosphorization of high phosphorus oolitic hematite by acid leaching and the leaching kinetics. Hydrometallurgy 171, 61-68.
  • Xu, Y., Jiang, T., Wen, J., Gao, H., Wang, J., Xue, X. 2018. Leaching kinetics of mechanically activated boron concentrate in a NaOH solution. Hydrometallurgy 179, 60-72.
  • Zhang, R., Zheng, S., Ma, S., Zhang, Y. 2011. Recovery of alumina and alkali in Bayer red mud by the formation of andradite-grossular hydrogarnet in hydrothermal process. Journal of Hazardous Materials 189, 827-835.
  • Zhou, H., Li, D., Tian, Y., Chen, Y. 2008. Extraction of scandium from red mud by modified activated carbon and kinetics study. Rare Metals 27, 223-227.
Yıl 2022, Cilt: 167 Sayı: 167, 179 - 188, 20.04.2022
https://doi.org/10.19111/bulletinofmre.941073

Öz

Kaynakça

  • Abdulvaliyev, R. A., Akcil, A., Gladyshev, S. V., Tastanov,E. A., Beisembekova, K. O., Akhmadiyeva, N. K., Deveci, H. 2015. Gallium and vanadium extraction from red mud of Turkish alumina refinery plant: hydrogarnet process. Hydrometallurgy 157, 72- 77.
  • Baral, S. S., Shekar, R. K., Viswanathan, V., Surendran, G. 2016. Dissolution kinetics of cerium from red mud, Separation Science and Technology 52(5), 883-891.
  • Baştürkcü, H. 2020. Extraction of lanthanum and yttrium from red mud following elimination of ionic impurities. Separation Science and Technology 56(13), 2243-2252.
  • Borra, C. R., Pontikes, Y., Binnemans, K., Gerven, V. T. 2015. Leaching of rare earths from bauxite residue (red mud). Minerals Engineering 76, 20-27.
  • Borra, C. R., Mermans, J., Blanpain, B., Pontikes, Y., Binnemans, K., Gerven, V. T. 2016. Selective recovery of rare earths from bauxite residue by combination of sulfation, roasting and leaching. Minerals Engineering 92, 151-159.
  • Chen, X., Lun, A., Qu, G. 2013. Preparation and characterization of foam ceramics from red mud and fly ash using sodium silicate as foaming agent. Ceramics International 39, 1923-1929.
  • Christmann, P., Gloaguen, E., Labbe, J. F., Melleton, J., Piantone, P. 2015. Global lithium resources and sustainability issues. Lithium Process Chemistry Resources, Extraction, Chapter 1. Batteries, and Recycling edited by Alexandre Chagnes and Jolanta Swiatowska, Elsevier.
  • Deng, B., Li, G., Luo, J., Ye, Q., Liu, M., Peng, Z., Jiang, T. 2017. Enrichment of Sc2O3 and TiO2 from bauxite ore residues. Journal of Hazardous Materials 331, 71-80.
  • Erçağ, E., Apak, R. 1997. Furnace smelting and extractive metallurgy of red mud: recovery of TiO2, Al2O3 and pig iron. Journal of Chemical Technology and Biotechnology 70, 241-246.
  • Evans, K. 2015. Successes and challenges in the management and use of bauxite residue. Bauxite Residue Valoris. Best Practice Conference, 113-127.
  • Fulford, G. D., Lever, G., Sato, T. 1991. Recovery of rare earth elements from Bayer process red mud. US5030424.
  • Gladyshev, S. V., Akcil, A., Abdulvaliyev, R. A., Tastanov, E. A., Beisembekova, K. O., Temirova, S. S., Deveci, H. 2015. Recovery of vanadium and gallium from solid waste by-products of Bayer process, Minerals Engineering 74, 91-98.
  • Hammond, K., Apelian, B. M. D., Blanpain, B. 2013. CR3 communication: red mud-a resource or a waste?. Journal of the Minerals Metals and Materials Society 65, 340-341.
  • Kumar, S., Kumar, R., Bandopadhyay, A. 2006. Innovative methodologies for the utilisation of wastes from metallurgical and allied industries. Resources, Conservation and Recycling 48, 301-314.
  • Liu, W., Sun, S., Zhang, L., Jahanshahi, S., Yang, J. 2012. Experimental and simulative study on phase transformation in Bayer red mud soda-lime roasting system and recovery of Al, Na and Fe. Minerals Engineering 39, 213-218.
  • Liu, Y., Lin, C., Wu, Y. 2007. Characterization of red mud derived from a combined Bayer process and bauxite calcination method. Journal of Hazardous Materials 146, 255-261.
  • Okudan, M. D., Akcil, A., Tuncuk, A., Deveci, H. 2015a. Effect of parameters on vanadium recovery from by-products of the Bayer process, Hydrometallurgy 152, 76-83.
  • Okudan, M. D., Akcil, A., Tuncuk, A., Deveci, H. 2015b. Recovery of gallium and aluminum from electrofilter dust of alumina calcination plant in Bayer process, Separation Science and Technology 50, 2596-2605.
  • Ochsenkuhn-Petropulu, M., Lyberopulu, T., Parissakis, G. 1995. Selective separation and determination of scandium from yttrium and lanthanides in red mud by a combined ion exchange/solvent extraction method. Analytic Chimica Acta 315, 231-237.
  • Ochsenkuhn-Petropulu, M., Lyberopulu, T., Ochsenkuhn, K. M., Parissakis, G. 1996. Recovery of lanthanides and yttrium from red mud by selective leaching. Analytic Chimica Acta 319, 249-254.
  • Smirnov, D. I., Molchanova, T. V. 1997. The investigation of sulphuric acid sorption recovery of scandium and uranium from the red mud of alumina production. Hydrometallurgy 45, 249-259.
  • Teixeira, I. F., Medeiros, T. P. V., Freitas, P. E., Rosmaninho, M. G., Ardisson, J. D., Lago, R. M. 2014. Carbon deposition and oxidation using the waste red mud: a route to store, transport and use offshore gas lost in petroleum exploration. Fuel 124, 7-13. Uzun, D., Gülfen, M. 2007. Dissolution kinetics of iron and aluminum from red mud in sulfuric acid solution. Indian Journal of Chemical Technology 14, 263- 268.
  • Verlaguet, A., Goff, B., Brunet, F., Poinssot, C., Vidal, O., Findling, N. 2011. Metamorphic veining and mass transfer in a chemically closed system: a case study in Alpine metabauxites (western Vanoise). Journal of Metamorphic Geology 29, 275-300.
  • Wang, D. H, Li, P. G, Qu, W. J, Yin, L. J., Zhao, Z., Lei,Z. Y. 2013a. Discovery and preliminary study of the high tungsten and lithium contents in the Dazhuyuan bauxite deposit, Guizhou, China. Science China Earth Sciences 56(1), 145-152.
  • Wang, W., Pranolo, Y., Cheng, C. Y. 2013b. Recovery of scandium from synthetic red mud leach solutions by solvent extraction with D2EHPA. Separation and Purification Technology 108, 96-102.
  • Wang, H. H., Li, G. Q., Zhao, D., Ma, J. H., Yang, J. 2017. Dephosphorization of high phosphorus oolitic hematite by acid leaching and the leaching kinetics. Hydrometallurgy 171, 61-68.
  • Xu, Y., Jiang, T., Wen, J., Gao, H., Wang, J., Xue, X. 2018. Leaching kinetics of mechanically activated boron concentrate in a NaOH solution. Hydrometallurgy 179, 60-72.
  • Zhang, R., Zheng, S., Ma, S., Zhang, Y. 2011. Recovery of alumina and alkali in Bayer red mud by the formation of andradite-grossular hydrogarnet in hydrothermal process. Journal of Hazardous Materials 189, 827-835.
  • Zhou, H., Li, D., Tian, Y., Chen, Y. 2008. Extraction of scandium from red mud by modified activated carbon and kinetics study. Rare Metals 27, 223-227.
Toplam 29 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Hüseyin Baştürkcü Bu kişi benim 0000-0001-7301-9317

Yayımlanma Tarihi 20 Nisan 2022
Yayımlandığı Sayı Yıl 2022 Cilt: 167 Sayı: 167

Kaynak Göster

APA Baştürkcü, H. (2022). Investigation of dissolution behavior of scandium and lithium from red mud. Bulletin of the Mineral Research and Exploration, 167(167), 179-188. https://doi.org/10.19111/bulletinofmre.941073
AMA Baştürkcü H. Investigation of dissolution behavior of scandium and lithium from red mud. Bull.Min.Res.Exp. Nisan 2022;167(167):179-188. doi:10.19111/bulletinofmre.941073
Chicago Baştürkcü, Hüseyin. “Investigation of Dissolution Behavior of Scandium and Lithium from Red Mud”. Bulletin of the Mineral Research and Exploration 167, sy. 167 (Nisan 2022): 179-88. https://doi.org/10.19111/bulletinofmre.941073.
EndNote Baştürkcü H (01 Nisan 2022) Investigation of dissolution behavior of scandium and lithium from red mud. Bulletin of the Mineral Research and Exploration 167 167 179–188.
IEEE H. Baştürkcü, “Investigation of dissolution behavior of scandium and lithium from red mud”, Bull.Min.Res.Exp., c. 167, sy. 167, ss. 179–188, 2022, doi: 10.19111/bulletinofmre.941073.
ISNAD Baştürkcü, Hüseyin. “Investigation of Dissolution Behavior of Scandium and Lithium from Red Mud”. Bulletin of the Mineral Research and Exploration 167/167 (Nisan 2022), 179-188. https://doi.org/10.19111/bulletinofmre.941073.
JAMA Baştürkcü H. Investigation of dissolution behavior of scandium and lithium from red mud. Bull.Min.Res.Exp. 2022;167:179–188.
MLA Baştürkcü, Hüseyin. “Investigation of Dissolution Behavior of Scandium and Lithium from Red Mud”. Bulletin of the Mineral Research and Exploration, c. 167, sy. 167, 2022, ss. 179-88, doi:10.19111/bulletinofmre.941073.
Vancouver Baştürkcü H. Investigation of dissolution behavior of scandium and lithium from red mud. Bull.Min.Res.Exp. 2022;167(167):179-88.

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