Adsorption behavior of methylene blue onto four different coffee residues

Öz

In this study, four coffee residues were investigated for the adsorption of methylene blue from aqueous solution. The four coffee residues were Jacobs Monarch Coffee, Tchibo Professional Special Filter Coffee, Turkish Coffee (Mehmet Efendi), and Anisah Guatemala Coffee. These coffees were washed with distilled water, and dried up to 60 °C. Adsorption mechanisms, such as pH, contact time, concentration of methylene blue, and temperature, were investigated. The characterization of the samples (before and after adsorption with methylene blue) was performed using FTIR and SEM analyses. Langmuir and Freundlich isotherms were used to determine the adsorption mechanisms. The FTIR findings indicated that methylene blue bonded with the hydrogen bonds. The results showed that the maximum adsorption capacity was 67,14 mg/g at 298 K for Turkish coffee. It can be understood that, coffee residue (especially Turkish coffee) was a cost-effective and eco-friendly material for removing methylene blue from aqueous solution.

Anahtar Kelimeler

• adsorption
• coffee residue
• methylene blue.

Kaynakça

1. [1]. Dinçer A, Aydemir T. 2021. Adsorptive Removal of Tartrazine Dye by Poly(N-vinylimidazoleethylene glycol dimethacrylate) And Poly(2-hydroxyethyl methacrylateethylene glycol dimethacrylate) Polymers. Celal Bayar University Journal of Science; 17 (4): 397-404.
2. [2]. Kausar A, Iqbal M, Javed A, Aftab K, Nazli ZH, Bhatti HN, Nouren S. 2018. Dyes adsorption using clay and modified clay: A review. Journal of Molecular Liquids; 256: 395-407.
3. [3]. Yagub MT, Sen TK, Afroze S, Ang HM. 2014. Dye and its removal from aqueous solution by adsorption: A review. Advances in Colloid and Interface Science; 209: 172-184.
4. [4]. Saxena M, Sharma N, Saxena R. 2020. Highly efficient and rapid removal of a toxic dye: Adsorption kinetics, isotherm, and mechanism studies on functionalized multiwalled carbon nanotubes. Surfaces and Interfaces; 21: 100639:1-10.
5. [5]. Ghoreishi SM, Haghighi R. 2003. Chemical catalytic reaction and biological oxidation for treatment of non-biodegradable textile effluent. Chemical Engineering Journal; 95(1):163–169.
6. [6]. Adeyemo AA, Adeoye IO, Bello OS. 2017. Adsorption of dyes using different types of clay: a review. Applied Water Science; 7: 543–568.
7. [7]. Dabrowski A. 2001. Adsorption - from theory to practice. Advances in Colloid and Interface Science; 93 (1-3) 135-224.
8. [8]. Qui H, Lv L, PAN B, Zhang Q, Zhang W, Zhang Q. 2009. Critical review in adsorption kinetic models. Journal of Zhejiang University-Science A; 10(5):716-724.

9. [9]. Annadurai G, Juang RS, Lee DJ. 2002. Use of cellulose-based wastes for adsorption of dyes from aqueous solutions. Journal of Hazardous Materials; B92: 263–274.
10. [10]. Hevira L, Ighalo JO, Zein R. 2020. Biosorption of indigo carmine from aqueous solution by Terminalia catappa Shell. Journal of Environmental Chemical Engineering; 8(5), 104290, 2020.
11. [11]. Berber-Villamar NK, Netzahuatl-Muñoz AR, Morales-Barrera L, Chávez-Camarillo GM, Flores-Ortiz CM, Cristiani-Urbina E. 2018. Corncob as an effective, eco-friendly, and economic biosorbent for removing the azo dye Direct Yellow 27 from aqueous solutions. Plos One; 13(4): 1-30.
12. [12]. El-Naggar NEA, Rabei NH, El-Malkey SE. 2020. Eco-friendly approach for biosorption of Pb 2+ and carcinogenic Congo red dye from binary solution onto sustainable Ulva lactuca biomass. Scientific Reports; 10(1): 1-22.
13. [13]. Ozudogru Y, Merdivan M. 2017. Metilen mavisinin modifiye edilmiş Cystoseira barbata (stackhouse) C. Agardh kullanılarak biyosorpsiyonu. Trakya University Journal of Natural Sciences; 18 (2): 81-87.
14. [14]. Meili L, Lins PVS, Costa MT, Almeida RL, Abud AKS, Soletti JL, Dotto GL, Tanabe EH, Sellaoui L, Carvalho SHV, Erto A. 2019. Adsorption of methylene blue on agroindustrial wastes: Experimental investigation and phenomenological modelling. Progress in Biophysics and Molecular Biology; 141: 60-71.
15. [15]. Ghosh D, Bhattacharyya KG. 2002. Adsorption of methylene blue on kaolinite. Applied Clay Science; 20 (6): 295-300.
16. [16]. Ahmad MA, Rahman NK. 2011. Equilibrium, kinetics and thermodynamic of Remazol Brilliant Orange 3R dye adsorption on coffee husk-based activated carbon. Chemical Engineering Journal; 170(1): 154-161.
17. [17]. Cheruiyot GK, Wanyonyi WC, Kiplimo JJ, Maina EN. 2019. Adsorption of toxic crystal violet dye using coffee husks: equilibrium, kinetics and thermodynamics study. Scientific African; 5 (e00116): 1-11.
18. [18]. Shen K, Gondal MA. 2017. Removal of hazardous Rhodamine dye from water by adsorption onto exhausted coffee ground. Journal of Saudi Chemical Society; 21 (1): 120-127.
19. [19]. Ayalew AA, Aragaw TA. 2020. Utilization of treated coffee husk as low-cost bio-sorbent for adsorption of methylene blue. Adsorption Science & Technology; 38(5–6): 205-222.
20. [20]. Vairavel P, Rampal N, Jeppu G. 2021. Adsorption of toxic Congo red dye from aqueous solution using untreated coffee husks: kinetics, equilibrium, thermodynamics and desorption study. International Journal of Environmental Analytical Chemistry; 1-19.
21. [21]. Manzar MS, Zubair M, Khan NA, Khan AH, Baig U, Aziz MA, Blaisi NI, Abdel-Magid HIM. 2020. Adsorption behaviour of green coffee residues for decolourization of hazardous congo red and eriochrome black T dyes from aqueous solutions. International Journal of Environmental Analytical Chemistry; 1-17.
22. [22]. Franca, AS, Oliveira LS, Ferreira ME. 2009. Kinetics and equilibrium studies of methylene blue adsorption by spent coffee grounds. Desalination; 249: 262-272.
23. [23]. Bulut Y, Aydın H. 2006. A kinetics and thermodynamics study of methylene blue adsorption on wheat shells. Desalination; 194–267.
24. [24]. Ronix A, Pezoti O, Souza LS, Souza IPAF, Bedin KC, Souza PSC, Silva TL, Melo SAR, Cazetta AL, Almeida VC. 2017. Hydrothermal carbonization of coffee husk: Optimization of experimental parameters and adsorption of methylene blue dye. Journal of Environmental Engineering; 5: 4841-4849.
25. [25]. Mathivanan M, Syed Abdul Rahman S, Vedachalam R, Karuppiah S. 2021. Ipomoea carnea: a novel biosorbent for the removal of methylene blue (MB) from aqueous dye solution: kinetic, equilibrium and statistical approach. International Journal of Phytoremediation; 1-19.
26. [26]. Mbarki F, Kesraoui A, Seffen M, Ayrault P. 2018. Kinetic, thermodynamic, and adsorption behavior of cationic and anionic dyes onto corn stigmata: nonlinear and stochastic analyses. Water, Air, & Soil Pollution; 229(3): 1-17.
27. [27]. Fawzy MA, Gomaa M. 2021. Low-cost biosorption of Methylene Blue and Congo Red from single and binary systems using Sargassum latifolium biorefinery waste/wastepaper xerogel: an optimization and modeling study. Journal of Applied Phycology; 33: 675-691.
28. [28]. Saxene M, Sharma N, Saxene R. 2020. Highly efficienr and rapid removal of toxic dye: Adsorption kinetics, isotherm, and mechanism studies on functionalized multiwalled carbon nanotubes. Surface and Interfaces; 21 (100639):1-10.
29. [29]. Kusmono IA. 2019. Water sorption, antimicrobial activity, and thermal and mechanical properties of chitosan/clay/glycerol nanocomposite films. Heliyon; 5(e02342): 1-7.