Preparation of ECH-PCCB for the Pre-concentration and Determination of Cadmium (II) Ions Prior to FAAS by FIA

Yıl 2023, , 237 - 242, 30.09.2023

Vedia Nüket Tirtom , Fatma Özkafalı

https://doi.org/10.18466/cbayarfbe.1280291

Öz

In this study, ECH-PCCB structures were used for the first time as mini-column filling material in a FIA added to the AAS for the pre-concentration of cadmium ions. This method is simple, accurate and highly selective for pre-concentration of Cd(II) in water samples. Surface analysis of ECH-PCCB was performed by scanning electron microscopy. Elution of Cd(II) ions from the column was achieved with 0.1 mol L-1 EDTA. Some parameters affecting the pre-concentration of Cd(II) ions, such as sample loading time, sample flow rate, eluent type and concentration, pH, and interference ions were investigated. Under the optimized parameters, the enrichment factor was 23 and the detection limit of the method was 16 µg L-1 as a result of pre-concentration studies with ECH-PCCB.

Anahtar Kelimeler

Cd (II), Flow injection Analyses, Pumice-Chitosan Composite Beads, Online Preconcentration

Kaynakça

• [1] M. Stratford. “Welcome to Mendeley: Quick Start Guide”. 2018
• [2] Baláž, M, Bujňáková, Z, Baláž, P, Zorkovská, A, Danková, Z, Briančin. J. 2015. Adsorption of cadmium (II) on waste biomaterial. J. Colloid Interface Science; 454: 121-133.
• [3] Chen, T, Zhou, Z, Han, R, Meng, R, Wang, H, Lu, W. 2015. Adsorption of cadmium by biochar derived from municipal sewage sludge: Impact factors and adsorption mechanism. Chemosphere; 134: 286–293.
• [4] Soylak, M, Narin, I. 2005.On-Line Pre-concentration System for Cadmium Determination in Environmental Samples by Flame Atomic Absorption Spectrometry. Chem. Anal. (Warsaw); 50:705-715
• [5] Gouda, A.A, Zordok, W.A, 2018. Solid-phase extraction method for pre-concentration of cadmium and lead in environmental samples using multiwalled carbon nanotubes. Turkish Journal of Chemistry; 42(4): 1018–1031.
• [6] Marguí, E, Van Grieken, R, Fonta’S, C, Hidalgo, M, Queralt, I. 2010. Pre-concentration Methods for the Analysis of Liquid Samples by X-Ray Fluorescence Techniques. Applied Spectroscopy Reviews; 45(3): 179–205.
• [7] Mizuike, A, Pre-concentration techniques for inorganic trace analysis. 1986. Fresenius’ Zeitschrift für Analytische Chemie; 324(7): 672–677.
• [8] D. Chen, B, Hu, C, Huang, 2009. Chitosan modified ordered mesoporous silica as micro-column packing materials for on-line flow injection-inductively coupled plasma optical emission spectrometry determination of trace heavy metals in environmental water samples. Talanta; 78(2): 491–497
• [9] Wuilloud, RG, González, AH, Marchevsky, EJ, Olsina, RA, Martinez, LD. 2001. On-line complexation/pre-concentration system for the determination of lead in wine by inductively coupled plasma-atomic emission spectrometry with ultrasonic nebulization. Journal of AOAC International; 84(5): 1555–1560.
• [10] Liu, Y, Guo, Y, Meng, S, Chang, X. 2007. Online separation and pre-concentration of trace heavy metals with 2,6-dihydroxyphenyl-diazoaminoazobenzene impregnated amberlite XAD-4. Microchimica Acta; 158(3–4): 239–245
• [11] Abdelhamid, HN, Lin, YC, Wu, HF, 2017. Thymine chitosan nanomagnets for specific pre-concentration of mercury (II) prior to analysis using SELDI-MS. Microchimica Acta; 184(5): 1517–1527
• [12] Di Nezio, MS, Palomeque, ME, Fernández B, BS. 2006. A Multi‐Element Flow Injection System for Heavy Metals Determination. Analytical Letters; 39(6): 1211–1228.
• [13] Yari, M, Moghimi, A, Fakhari, S. 2016. Preparation of Modified Magnetic Nano-Fe3O4 Chitosan/Graphene Oxide for the Pre-concentration and Determination of Copper (II) ions in Biological and Environmental Water Samples. Oriental Journal of Chemistry; 32(3): 1659–1669
• [14] Shinde, RN, Pandey, AK, Acharya, R, Guin, R, Das, SK, Rajurkar, NS, 2013. Chitosan-transition metal ions complexes for selective arsenic(V) pre-concentration. Water Research; 47(10): 3497–3506.
• [15] Yadaei, H, Beyki, MH, Shemirani, F, Nouroozi, S. 2018. Ferrofluid mediated chitosan@ mesoporous carbon nanohybrid for green adsorption/pre-concentration of toxic Cd (II): modeling, kinetic and isotherm study. Reactive and Functional Polymers; 122: 85–97.
• [16] Suneetha, Y. Kumar, BN, Harinath, Y, Reddy, DHK, 2012. Seshaiah, K. Functionalization of Cross Linked Chitosanwith 2-Aminopyridine-3-carboxylic Acid for Solid Phase Extraction of Cadmium and Zinc Ions and Their Determination by Atomic Absorption Spectrometry. Microchimica Acta; 176(1–2): 169–176.
• [17] He, JC, Zhou, FQ, Mao, YF, Tang, ZN, Li, CY, 2013. Pre-concentration of Trace Cadmium (II) and Copper (II) in Environmental Water Using a Column Packed with Modified Silica Gel-Chitosan Prior to Flame Atomic Absorption Spectrometry Determination. Analytical Letters; 46(9): 1430–1441.
• [18] Al-Saidi, HM. 2016. Biosorption using chitosan thiourea polymer as an extraction and pre-concentration technique for copper prior to its determination in environmental and food samples by flame atomic absorption spectrometry: Synthesis, characterization and analytical applications. International Journal of Biological Macromolecules; 93: 390–40.
• [19] Akbal, F. 2005. Adsorption of basic dyes from aqueous solution onto pumice powder. Journal of Colloid and Interface Science; 286(2): 455–458.
• [20] Shokoohi, R, Torkshavand, Z, Bajalan, S, Zolghadnasab, H, Khodayari, Z. 2019. Cadmium removal by using pumice modified with iron nanoparticles. Global Nest Journal; 21(2): 91–97.
• [21] Martins, AO, Da Silva, EL, Carasek, E, Laranjeira, MCM, De Fávere, VT. 2004. Sulphoxine immobilized onto chitosan microspheres by spray drying: Application for metal ions pre-concentration by flow injection analysis. Talanta; 63(2): 397–403. [22] Martins, AO, Da Silva, EL, Carasek, E, Gonçalves, NS, Laranjeira, MCM, De Fávere, VT. 2004. Chelating resin from functionalization of chitosan with complexing agent 8-hydroxyquinoline: Application for metal ions online pre-concentration system. Analytica Chimica Acta; 521(2): 157–162
• [23] Sabarudin, A. Lenghor, N. Oshima, M. Hakim, L. Takayanagi, T. Gao, Y.H, Talanta. Elsevier, 2007. Sequential-injection on-line pre-concentration using chitosan resin functionalized with 2-amino-5-hydroxy benzoic acid for the determination of trace elements in environmental water samples by inductively coupled plasma-atomic emission spectrometry. Talanta; 72(5): 1609–1617.