Araştırma Makalesi
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Anderson Type Polyoxometalates Containing Vitamin B1

Yıl 2025, Cilt: 21 Sayı: 2, 95 - 99, 27.06.2025
https://doi.org/10.18466/cbayarfbe.1570842

Öz

The novel vitamin B1-substituted polyoxomolybdates (C12H17N4OS)3[Co(III)Mo6O24H6]·7H2O (1) and (C12H17N4OS)4[Ni(II)Mo6O24H6]·7H2O (2) have been synthesized using (NH4)3[Co(III)Mo6O24H6]·7H2O and (NH4)4[Ni(II)Mo6O24H6]·7H2O respectively as a precursor for the in situ formation of the counter ion vitamin B1 (C12H17N4OS)+. These compounds have been thoroughly characterized in the solid state FT-IR spectroscopy, powder X-ray diffraction (PXRD), TGA and elemental analysis.

Kaynakça

  • [1]. Wang, SS, Yang, GY. 2015. Recent advances in polyoxometalate-catalyzed reactions. Chemical Reviews; 115: 4893-4962.
  • [2]. Kastner, K, Kibler, AJ, Karjalainen, E, Fernandes, JA, Sans, V, Newton, GN. 2017. Redox-active organic–inorganic hybrid polyoxometalate micelles. Journal of Materials Chemistry A; 5:11577-11581.
  • [3]. Bijelic, A, Aureliano, M, Rompel, A. 2018. The antibacterial activity of polyoxometalates: structures, antibiotic effects and future perspectives. Chemical Communications; 54:1153-1169.
  • [4]. Bijelic, A, Aureliano, M, Rompel, A. 2019. Polyoxometalates as potential next-generation metallodrugs in the combat against cancer. Angewandte Chemie International Edition; 58:2980-2999
  • [5]. Avcı Özbek, H, Kopar, E, Demirhan, F. 2021. Synthesis, structure, and antimicrobial properties of mixed-metal organometallic polyoxometalates. [Cp*2M5VO17]- (M=Mo, W). Journal of Coordination Chemistry; 74:1794-1809.
  • [6]. Avcı Özbek, H. 2023. V-subtituted lindqvist-type polyoxometalates: preparation, structural characterization and antibacterial activity. Chemical Papers; 77:5663-5669.
  • [7]. Avcı Özbek, H. 2023. Synthesis and characterization of Anderson-Evans type polyoxometalates, antibacterial properties. Turkish Journal of Chemşitry; 47(4): 742-748.
  • [8]. Avcı Özbek, H. 2024. Molybdenum–Vanadium Oxide Clusters: Syntheses, Structures and Antibacterial Properties. Journal of the Institute of Science and Technology; 14 (1):356-362.
  • [9]. Wang, YJ, Chen, WL, Chen, L, Zheng, XT, Xu, SS, Wang, EB. 2017. Sandwich-type silicotungstate modified TiO2 microspheres for enhancing light harvesting and reducing electron recombination in dye-sensitized solar cells. Inorganic. Chemistry Frontiers; 4:559–565.
  • [10]. Yang, HK, Cheng, YX, Su, MM, Xiao, Y, Hu, MB, Wang, W, Wang, Q. 2013. Polyoxometalate–biomolecule conjugates: a new approach to create hybrid drugs for cancer therapeutics, Bioorganic & Medicinal Chemistry Letters; 23:1462–1466.
  • [11]. Song, F, Wang, T. 2022. Application of Polyoxometalates in Chemiresistive Gas Sensors: A Review. ACS Sensors; 7(12) 3634–3643.
  • [12]. Xing, C, Ma, M, Chang, J, Ji, Z, Wang, P, Sun, L, Li, S, Li, M. 2023. Polyoxometalate anchored zinc oxide nanocomposite as a highly effective photocatalyst and bactericide for wastewater decontamination. Chemical Engineering Journal; 464:142632.
  • [13]. Zhao, M., Fang, Y, Ma, L, Zhu, X, Jiang, L, Li, M., Han, Q. 2020. Synthesis, characterization and in vitro antibacterial mechanism study of two Keggin-type polyoxometalates. Journal of Inorganic Biochemistry; 210:111131.
  • [14]. Çetindere, S. 2023. Polyoxometalate‑based boron dipyrromethene (BODIPY) conjugates: syntheses, characterization and photophysical properties. Journal of the Iranian Chemical Society; 20:3069-3077.
  • [15]. Çetindere, S, Ardıç Alidağı, H, Anjass, M. 2023. Two novel Anderson-type polyoxometalate based MnIII complexes constructed from pyrene derivatives: Synthesis, photophysical, and electrochemical properties. Inorganica Chimica Acta; 545: 121280.
  • [16]. Golubeva, OY, Pavlova, SV. 2014. Adsorption of Thiamine Hydrochloride (Vitamin B1) by Synthetic Layered Silicates with a Montmorillonite Structure. Glass Physics and Chemistry; 40(3):375–379.
  • [17]. Ostroushko, A, Gagarin, I, Tonkushina, M, Grzhegorzhevskii, K, Russkikh, O. 2018. Association of Spherical Porous Nanocluster Keplerate-Type Polyoxometalate Mo72Fe30 with Biologically Active Substances. Journal of Cluster Science; 29:111–120.
  • [18]. Mahvash, S, Zavareh, VA, Taymouri, S, Mirian, M, Ramezani-Aliakbari, M, Dousti, F, Rostami, M. 2023. Anderson-type manganese polyoxomolybdate hybrid nanocomposite for boosting drug delivery against breast cancer. Journal of Drug Delivery Science and Technology; 87:104778.
  • [19]. Ramezani-Aliakbari, M, Varshosaz, J, Sadeghi-aliabadi, H, Hassanzadeh, F, Rostami, M. 2021. Biotin-Targeted Nanomicellar Formulation of an Anderson-Type Polyoxomolybdate: Synthesis and In Vitro Cytotoxicity Evaluations. Langmuir; 37:6475−6489.
  • [20]. Ramezani-Aliakbari, M, Varshosaz, J, Mirian, M, Khodarahmi, G, Rostami, M. 2022. pH-responsive glucosamine anchored polydopamine coated mesoporous silica nanoparticles for delivery of Anderson-type polyoxomolybdate in breast cancer. Journal of Microencapsulation; 39(5): 433-451.
  • [21]. Nomiya, K, Takahashi, T, Shirai, T, Miwa, M. 1987. Anderson-type heteropolyanions of molybdenum(VI) and tungsten(VI). Polyhedron; 6(2):213-218.
  • [22]. Tewari, S, Adnan, M, Balendra, Kumar, V, Jangra, G, Prakash GV, Ramanan, A. 2019. Photoluminescence properties of two closely related isostructural series based on Anderson-Evans cluster coordinated with lanthanides [Ln(H2O)7{X(OH)6Mo6O18}]·yH2O, X = Al, Cr. Frontiers in Chemistry ;6 (631):1-19.
  • [23]. Thabet, S, Ayed, D, Haddad, A. 2013. Novel organic-inorganic hybrid with Anderson type polyanions as building blocks: (C6H10N3O2)2Na(H2O)2[Al(OH)6Mo6O18]·6H2O. Materials Research Bulletin. 47:3791–3796.
  • [24]. Avcı Özbek, H. 2023. Synthesis and Characterization of New Anderson-Type Polyoxometalates: [M ((1,10-phen)(OH)x]3[Cr (OH)6Mo6O18]·16H2O (M= Cr, Mn, Co, Ni, Cu; x= 1, 2). Journal of the Turkish Chemical Society Section A: Chemistry; 1 (2): 315-324.

Yıl 2025, Cilt: 21 Sayı: 2, 95 - 99, 27.06.2025
https://doi.org/10.18466/cbayarfbe.1570842

Öz

Kaynakça

  • [1]. Wang, SS, Yang, GY. 2015. Recent advances in polyoxometalate-catalyzed reactions. Chemical Reviews; 115: 4893-4962.
  • [2]. Kastner, K, Kibler, AJ, Karjalainen, E, Fernandes, JA, Sans, V, Newton, GN. 2017. Redox-active organic–inorganic hybrid polyoxometalate micelles. Journal of Materials Chemistry A; 5:11577-11581.
  • [3]. Bijelic, A, Aureliano, M, Rompel, A. 2018. The antibacterial activity of polyoxometalates: structures, antibiotic effects and future perspectives. Chemical Communications; 54:1153-1169.
  • [4]. Bijelic, A, Aureliano, M, Rompel, A. 2019. Polyoxometalates as potential next-generation metallodrugs in the combat against cancer. Angewandte Chemie International Edition; 58:2980-2999
  • [5]. Avcı Özbek, H, Kopar, E, Demirhan, F. 2021. Synthesis, structure, and antimicrobial properties of mixed-metal organometallic polyoxometalates. [Cp*2M5VO17]- (M=Mo, W). Journal of Coordination Chemistry; 74:1794-1809.
  • [6]. Avcı Özbek, H. 2023. V-subtituted lindqvist-type polyoxometalates: preparation, structural characterization and antibacterial activity. Chemical Papers; 77:5663-5669.
  • [7]. Avcı Özbek, H. 2023. Synthesis and characterization of Anderson-Evans type polyoxometalates, antibacterial properties. Turkish Journal of Chemşitry; 47(4): 742-748.
  • [8]. Avcı Özbek, H. 2024. Molybdenum–Vanadium Oxide Clusters: Syntheses, Structures and Antibacterial Properties. Journal of the Institute of Science and Technology; 14 (1):356-362.
  • [9]. Wang, YJ, Chen, WL, Chen, L, Zheng, XT, Xu, SS, Wang, EB. 2017. Sandwich-type silicotungstate modified TiO2 microspheres for enhancing light harvesting and reducing electron recombination in dye-sensitized solar cells. Inorganic. Chemistry Frontiers; 4:559–565.
  • [10]. Yang, HK, Cheng, YX, Su, MM, Xiao, Y, Hu, MB, Wang, W, Wang, Q. 2013. Polyoxometalate–biomolecule conjugates: a new approach to create hybrid drugs for cancer therapeutics, Bioorganic & Medicinal Chemistry Letters; 23:1462–1466.
  • [11]. Song, F, Wang, T. 2022. Application of Polyoxometalates in Chemiresistive Gas Sensors: A Review. ACS Sensors; 7(12) 3634–3643.
  • [12]. Xing, C, Ma, M, Chang, J, Ji, Z, Wang, P, Sun, L, Li, S, Li, M. 2023. Polyoxometalate anchored zinc oxide nanocomposite as a highly effective photocatalyst and bactericide for wastewater decontamination. Chemical Engineering Journal; 464:142632.
  • [13]. Zhao, M., Fang, Y, Ma, L, Zhu, X, Jiang, L, Li, M., Han, Q. 2020. Synthesis, characterization and in vitro antibacterial mechanism study of two Keggin-type polyoxometalates. Journal of Inorganic Biochemistry; 210:111131.
  • [14]. Çetindere, S. 2023. Polyoxometalate‑based boron dipyrromethene (BODIPY) conjugates: syntheses, characterization and photophysical properties. Journal of the Iranian Chemical Society; 20:3069-3077.
  • [15]. Çetindere, S, Ardıç Alidağı, H, Anjass, M. 2023. Two novel Anderson-type polyoxometalate based MnIII complexes constructed from pyrene derivatives: Synthesis, photophysical, and electrochemical properties. Inorganica Chimica Acta; 545: 121280.
  • [16]. Golubeva, OY, Pavlova, SV. 2014. Adsorption of Thiamine Hydrochloride (Vitamin B1) by Synthetic Layered Silicates with a Montmorillonite Structure. Glass Physics and Chemistry; 40(3):375–379.
  • [17]. Ostroushko, A, Gagarin, I, Tonkushina, M, Grzhegorzhevskii, K, Russkikh, O. 2018. Association of Spherical Porous Nanocluster Keplerate-Type Polyoxometalate Mo72Fe30 with Biologically Active Substances. Journal of Cluster Science; 29:111–120.
  • [18]. Mahvash, S, Zavareh, VA, Taymouri, S, Mirian, M, Ramezani-Aliakbari, M, Dousti, F, Rostami, M. 2023. Anderson-type manganese polyoxomolybdate hybrid nanocomposite for boosting drug delivery against breast cancer. Journal of Drug Delivery Science and Technology; 87:104778.
  • [19]. Ramezani-Aliakbari, M, Varshosaz, J, Sadeghi-aliabadi, H, Hassanzadeh, F, Rostami, M. 2021. Biotin-Targeted Nanomicellar Formulation of an Anderson-Type Polyoxomolybdate: Synthesis and In Vitro Cytotoxicity Evaluations. Langmuir; 37:6475−6489.
  • [20]. Ramezani-Aliakbari, M, Varshosaz, J, Mirian, M, Khodarahmi, G, Rostami, M. 2022. pH-responsive glucosamine anchored polydopamine coated mesoporous silica nanoparticles for delivery of Anderson-type polyoxomolybdate in breast cancer. Journal of Microencapsulation; 39(5): 433-451.
  • [21]. Nomiya, K, Takahashi, T, Shirai, T, Miwa, M. 1987. Anderson-type heteropolyanions of molybdenum(VI) and tungsten(VI). Polyhedron; 6(2):213-218.
  • [22]. Tewari, S, Adnan, M, Balendra, Kumar, V, Jangra, G, Prakash GV, Ramanan, A. 2019. Photoluminescence properties of two closely related isostructural series based on Anderson-Evans cluster coordinated with lanthanides [Ln(H2O)7{X(OH)6Mo6O18}]·yH2O, X = Al, Cr. Frontiers in Chemistry ;6 (631):1-19.
  • [23]. Thabet, S, Ayed, D, Haddad, A. 2013. Novel organic-inorganic hybrid with Anderson type polyanions as building blocks: (C6H10N3O2)2Na(H2O)2[Al(OH)6Mo6O18]·6H2O. Materials Research Bulletin. 47:3791–3796.
  • [24]. Avcı Özbek, H. 2023. Synthesis and Characterization of New Anderson-Type Polyoxometalates: [M ((1,10-phen)(OH)x]3[Cr (OH)6Mo6O18]·16H2O (M= Cr, Mn, Co, Ni, Cu; x= 1, 2). Journal of the Turkish Chemical Society Section A: Chemistry; 1 (2): 315-324.
Toplam 24 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular İnorganik Malzemeler
Bölüm Araştırma Makalesi
Yazarlar

Hülya Avcı Özbek 0000-0003-1508-2558

Gönderilme Tarihi 22 Ekim 2024
Kabul Tarihi 12 Mayıs 2025
Yayımlanma Tarihi 27 Haziran 2025
Yayımlandığı Sayı Yıl 2025 Cilt: 21 Sayı: 2

Kaynak Göster

APA Avcı Özbek, H. (2025). Anderson Type Polyoxometalates Containing Vitamin B1. Celal Bayar University Journal of Science, 21(2), 95-99. https://doi.org/10.18466/cbayarfbe.1570842
AMA Avcı Özbek H. Anderson Type Polyoxometalates Containing Vitamin B1. Celal Bayar University Journal of Science. Haziran 2025;21(2):95-99. doi:10.18466/cbayarfbe.1570842
Chicago Avcı Özbek, Hülya. “Anderson Type Polyoxometalates Containing Vitamin B1”. Celal Bayar University Journal of Science 21, sy. 2 (Haziran 2025): 95-99. https://doi.org/10.18466/cbayarfbe.1570842.
EndNote Avcı Özbek H (01 Haziran 2025) Anderson Type Polyoxometalates Containing Vitamin B1. Celal Bayar University Journal of Science 21 2 95–99.
IEEE H. Avcı Özbek, “Anderson Type Polyoxometalates Containing Vitamin B1”, Celal Bayar University Journal of Science, c. 21, sy. 2, ss. 95–99, 2025, doi: 10.18466/cbayarfbe.1570842.
ISNAD Avcı Özbek, Hülya. “Anderson Type Polyoxometalates Containing Vitamin B1”. Celal Bayar University Journal of Science 21/2 (Haziran2025), 95-99. https://doi.org/10.18466/cbayarfbe.1570842.
JAMA Avcı Özbek H. Anderson Type Polyoxometalates Containing Vitamin B1. Celal Bayar University Journal of Science. 2025;21:95–99.
MLA Avcı Özbek, Hülya. “Anderson Type Polyoxometalates Containing Vitamin B1”. Celal Bayar University Journal of Science, c. 21, sy. 2, 2025, ss. 95-99, doi:10.18466/cbayarfbe.1570842.
Vancouver Avcı Özbek H. Anderson Type Polyoxometalates Containing Vitamin B1. Celal Bayar University Journal of Science. 2025;21(2):95-9.