-

Öz

The design and synthesis of coordination polymers with unusual structures and properties have growing interest due to their diverse topologies and numerous potential applications in catalysis, molecular recognition, separation, gas storage, ion exchange, chemical sensing, magnetism, nonlinear optics and luminescence. In recent years, metal carboxylates have appeared as metal-organic framework materials with potential applications in the literature. Lead(II) as a heavy p-block metal ion with flexible coordination environment and variable stereochemical activity has considerable attention because of the suitability to construct incredible network topologies with intriguing physical properties. In this review, structures of the lead(II) coordination polymers containing acetate and N-donor organic ligands are described

Anahtar Kelimeler

• Lead(II) complexes, Acetate, Coordination polymer

KURŞUN(II) ASETAT KOORDİNASYON POLİMERLERİ - LEAD(II) ACETATE COORDINATION POLYMERS

Öz

KURŞUN(II) ASETAT KOORDİNASYON POLİMERLERİ

Çok çeşitli topolojileri ve kataliz, moleküler tanımlama, ayırma, gaz depolama, iyon değişimi, kimyasal sensörler, manyetizm, doğrusal olmayan optikler ve lüminesans gibi pek çok olası uygulamaları nedeniyle çok çeşitli olağandışı yapılar ve özellikler gösteren koordinasyon polimerlerinin tasarım ve sentezi giderek artan öneme sahiptir. Son yıllarda, metal karboksilatları metal-organik çerçeve malzemeleri olarak olası uygulamaları ile literatürde öne çıkmaktadır. Ağır p-blok metal iyonu olan Pb(II), değişken koordinasyon sayısı ve stereokimyasal aktivitesi ile ilgi çekici fiziksel özellikler gösteren olağanüstü ağ topolojileri inşa etmeye uygunluğu nedeniyle dikkat çekici bir ilgiye sahiptir. Bu derlemede, asetat ve N-verici atomlu organik ligandlar içeren kurşun(II) koordinasyon polimerlerinin yapılarından bahsedilmiştir.

LEAD(II) ACETATE COORDINATION POLYMERS

The design and synthesis of coordination polymers with unusual structures and properties have growing interest due to their diverse topologies and numerous potential applications in catalysis, molecular recognition, separation, gas storage, ion exchange, chemical sensing, magnetism, nonlinear optics and luminescence. In recent years, metal carboxylates have appeared as metal-organic framework materials with potential applications in the literature. Lead(II) as a heavy p-block metal ion with flexible coordination environment and variable stereochemical activity has considerable attention because of the suitability to construct incredible network topologies with intriguing physical properties. In this review, structures of the lead(II) coordination polymers containing acetate and N-donor organic ligands are described.

 

 

 

Anahtar Kelimeler

• Kurşun(II) kompleksleri, Asetat, Koordinasyon polimeri

Kaynakça

1. Yaghi, O. M., Li, G. M. and Li, H. L., “Selective binding and removal of guests in a microporous metal-organic framework”, Nature, 378: 703-706, (1995).
2. James, S. L., “Metal-organic frameworks”, Chemical Society Reviews, 32: 276-288, (2003).
3. Maspoch, D., Ruiz-Molina, D., Veciana, J., “Old materials with new tricks: multifunctional open-framework materials”, Chemical Society Reviews, 36: 770-818, (2007).
4. Shi, Y.-J., Li, L.-H., Li, Y.-Z., Chen, X.-T., Xue, Z., You, X.-Z., “Syntheses and structures of two one-dimensional double-stranded lead polymers of dicyanamide with ususual coordination mode”, Polyhedron, 22: 917-923, (2003).
5. Xue, L., Luo, F., Che, Y.-X., Zheng, J.-M., “A noninterpenetrating 3D coordination network with rare (4,6)-connected (45362)2(42566483) topology”, Journal of Molecular Structure, 832 (1-3): 132-137, (2007).
6. Oh, M., Mirkin C. A., “Ion Exchange as a Way of Controlling the Chemical Compositions of Nano- and Microparticles Made from Infinite Coordination Polymers”, Angewandte Chemie, 118 (33): 5618-5620, (2006).
7. Xu, H., He, Y. B., Zhang, Z. J., Xiang, S. C., Cai, J. F., Cu, Y. J., Yang, Y., Qian, G. D., Chen, B. L., “A microporous metal–organic framework with both open metal and Lewis basic pyridyl sites for highly selective C2H2/CH4 and C2H2/CO2 gas separation at room temperature”, Journal of Material Chemistry, 1: 77-81, (2013).
8. Seayad A. M., Antonelli D. M., “Recent advances in hydrogen storage in metal-containing inorganic nanostructures and related materials”, Advanced Materials, 16 (9-10): 765-777, (2004).

9. Nguyen, L. T. L., Le, K. K. A., Truong, H. X. , Phan, N. T. S., “Metal–organic frameworks for catalysis: the Knoevenagel reaction using zeolite imidazolate framework ZIF-9 as an efficient heterogeneous catalyst”, Catalysis Science and Technology, 2: 521-528, (2012).
10. Cui, Z., Qi, J., Xu, X., “PANI/CPs composite material, a new type of coordination polymer based composite material: Fabrication and photocatalytic property study”, Inorganic Chemistry Communications, 35: 260-264, (2013).
11. Chu, Q., Su, Z., Fan, J., Okamura, T. A., Lv, G. C., Liu, G. X., Sun, W. Y., Ueyama, N., “Novel cobalt(II) coordination polymers constructed from 3,3′,4,4′-oxydiphthalic acid and N-donor ligands: syntheses, crystal structures, and magnetic properties”, Crystal Growth & Design, 11: 3885–3894, (2011).
12. Meng, X., Liu, Y., Song, Y., Hou, H., Fan, Y., Zhu, Y., “Novel Zn(II) and Pb(II) coordination networks with large circuits: Synthesis, crystal structures and self-focusing effects”, Inorganica Chimica Acta, 358: 3024-3032, (2005).
13. J.-H. Lee, J.-H., “Gas sensors using hierarchical and hollow oxide nanostructures: Overview”, Sensors and Actuators B, 140: 319-336, (2009).
14. Xu, Y., Yuan, D., Han, L., Ma E., Wu, M., Lin, Z., Hong, M., “Mono- and Bilayered Lead(II)bpno Polymers with Unusual Low Energy Emission Properties (bpno = 4,4-Bipyridine N,N-Dioxide)”, European Journal of Inorganic Chemistry, 2054-2059, (2005).
15. Lei, Z. H., Li, X., Dong, L. N. , “Synthesis, structure, and luminescence of a novel lead(II) coordination polymer with 1,2-phenylenediace-tic acid, Inorganic Chemical Communication, 13: 1383-1386, (2010).
16. Wang, L., Li, G. F., Liu, M., Deng, D., Pei, Y., Wang, X., “Lead(II) arenedisulfonate coordination polymer: Synthesis, crystal structure and properties”, Inorganic Chemistry Communications, 35: 192-194, (2013).
17. Masoomi, M. Y. and Morsali, A., “Appli-cations of metal-organic coordination polymers as precursors for preparation of nano-materials”, Coordination Chemistry Reviews, 256: 2921-2943, (2012).
18. Ma, Y., Cheng, A. L., Zhang, J. Y., Yue, Q., Gao, E. Q., “One-, two-, and three-dimensional coordination polymers of stilbenedicarboxylate with different metal ions”, Crystal Growth & Design, 9: 867-873, (2009).
19. Yang, J., Ma, J.-F., Liu, Y.-Y., Li, S.-Li, Zheng, G.-L., “Four Novel 3D Copper(II) Coordination Polymers with Different Topologies”, European Journal of Inorganic Chemistry, 2174-2180, (2005).
20. Siqueira, M. R., Tonetto, T. C., Rizzatti, M. R., Lang, E. S., Ellena, J., Burrow, R. A., “The role of solvent in coordination polymers: The structures of catena-[Hg(2-O2PPh2)2] and catena-[Hg(2-O2PPh2)2(NC5H5)2]”, Inorganic Chemistry Communications, 9: 537-540, (2006).
21. Liu, J.-Q., Wang, Y.-Y., Zhang, Y.-N., Liu, P., Shi, Q.-Z., Batten, S. R., “ Topological Diversification in Metal-Organic Frameworks: Secondary Ligand and Metal Effects”, European Journal of Inorganic Chemistry, 147-154, (2009).
22. Yang, J., Li, G.-D., Cao, J.-J., Yue, Q., Li, G.-H., Chen, J.-S., “Structural Variation from 1D to 3D: Effects of Ligands and Solvents on the Construction of Lead(II)-Organic Coordination Polymers”, Chemistry-A European Journal, 13: 3248-3261, (2007).
23. Yang, E. C., Li, J., Ding, B., Liang, Q. Q., Wang, X. G., Zhao, X. J., “An eight-connected 3D lead(II) metal-organic framework with octanuclear lead(II) as a secondary building unit: Synthesis, characterization and luminescent property”, Crystal Engineering Communications, 10: 158-161, (2008).
24. Zhao, Y. H., Xu, H. B., Fu, Y. M., Shao, K. Z., Yang, S. Y., Su, Z. M., Hao, X. R., Zhu, D. X., Wang, E. B., “A series of lead(II)-organic frameworks based on pyridyl carboxylate acid N-Oxide derivatives: Syntheses, structures, and luminescent properties”, Crystal Growth & Design, 8: 3566-3576, (2008).
25. Haddadian, H., Aslani, A., Morsali, A., “Syntheses of PbO nano-powders using new nano-structured lead(II) coordination polymers”, Inorganica Chimica Acta, 362: 1805-1809, (2009).
26. Sadeghzadeh, H., Morsali, A., Yilmaz, V. T., Büyükgüngör, O., “Sonochemical synthesis of nano-scale mixed-ligands lead(II) coordination polymers as precursors of PbO and PbBr(OH) nano-structures; thermal, structural and X-ray powder diffraction studies”, Ultrasonics Sonochemistry, 17: 592-597, (2010).
27. Safarifard, V. and Morsali, A., “Sonochemical syntheses and characterization of nano-sized lead(II) coordination polymer with ligand 1-H-1,2,4-triazole-3-carboxylate”, Ultrasonics Sonochemistry, 19: 300-306, (2012).
28. Liu, Y., Liu, P., Liu, Q., Pang, L.-Y., Ren, C.-Y., Wang, Y.-Y., “A new (3,3,6)-connected achiral 3D supramolecular network containing unique helical chains based on 1H-benzimidazole-5,6-dicarboxylato and Pb(II)”, Inorganic Chemistry Communications, 35: 321-325, (2013).
29. Shimoni-Livny, L., Glusker, J. P., Bock, C. W., “Lone Pair Functionality in Divalent Lead Compounds”, Inorganic Chemistry, 37: 1853-1867, (1998).
30. Deacon, G. B. and Phillips, R. J., “Relationships between the carbonoxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination”, Coordination Chemistry Reviews, 33: 227-250, (1980).
31. Hu, M.-L., Morsali, A., Aboutorabi, L., “Lead(II) carboxylate supramolecular componds: Coordination modes, structures and nano-structures aspects”, Coordination Chemistry Reviews, 255: 2821-2859, (2011).
32. Morsali, A., Payheghader, M., Monfared, S. S., “A New Polymer of Mixed-Anions Complex [Pb(phen)(O2CCH3)(O2NO)]n (phen = 1,10-phenanthroline)”, Zeitschrift für Anorganische und Allgemeine Chemie, 628: 12-14, (2002).
33. Hall, A. K., Harrowfield, J. M., Morsali, A., Soudi, A. A., Yanovsky, A., “Bons and lone pairs in the flexible coordination sphere of lead(II)”, Crystal Engineering Communications, 2: 82-85, (2000).
34. Cheng, M. Q., Ma, L. F., Wang L. Y., “Crystal structure of catena-[1,10-phenanthroline-N,N)bis(-acetato-O,O)lead(II)] Pb(C12H8N2)(CH3COO)2, Zeitschrift fur Kristallographie-New Crystal Structures, 221 (3): 299-300, (2006).
35. Morsali, A. and Chen, X.-M., “A new lead(II) complex of 2,2-bipyridine, acetate and thiocyanate ligands: Synthesis, characterzation and crystal structure of [Pb(bpy)(NCS)(OAc)]n”, Journal of Coordination Chemistry, 57 (14): 1233-1241, (2004).
36. Morsali, A., Yilmaz, V. T., Kazak, C, Zhu, L.-G., “Two-Dimensional Holo- and Hemidirec-ted Lead(II) Coordination Polymers: Synthesis, Spectroscopic, Thermal, and Structural Studies of [Pb(-SCN)2(-ebp)1.5]n and {[Pb(-OAc)(-ebp)](ClO4)}n (ebp = 4,4-[(1E)-Ethane-1,2-diyl]bis[pyridine]; OAc =Acetato)”, Helvetica Chimica Acta, 88: 2513-2522, (2005).
37. Taheri, S. and Morsali, A., “Unusual bridging modes for percholorate in a 2D polymeric lead(II) complex {[Pb(bpy)(-OAc)]2(-O2ClO2)(-OClO2O)}n”, Journal of Coordination Chemistry, 59 (4): 363-369, (2006).
38. Soudi, A. A., Morsali, A., Moazzenhi, S., “A first 1,2,4-triazole Pb(II) Complex: Thermal, spectroscopic and structural studies, [Pb2(trz)2(CH3COO)(NO2)]n, Inorganic Chemistry Communications, 9: 1259-1262, (2006).
39. Peedikakkal, A. M. P., Vittal, J. J., “Molecular fabric structure formed by the 1D coordination polymer, [Pb(bpe)(O2CCH3)(O2C-CF3)]”, Crystal Growth & Design, 8: 375–377, (2008).
40. Ramazani, A., Hamidi, S., Morsali, A., “A novel mixed-ligands holodirected two-dimensional lead(II) coordination polymer as precursor for preparation lead(II) oxide nanoparticles”, Journal of Molecular Liquids, 157: 73-77, (2010).