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Boron Removal from Colemanite Mine Wastewater by Coagulation using Zinc Hydroxide―A Factorial Optimization Study

Yıl 2022, , 77 - 83, 25.03.2022
https://doi.org/10.18466/cbayarfbe.951542

Öz

In this study, boron removal from synthetic solutions and colemanite mine wastewater by coagulation method using in-situ generated zinc hydroxide from zinc chloride salt was investigated. The parameters for Jar test experiments were solution pH (8-12), concentration (50-750 mg/L), temperature (12-40oC), and zinc chloride dosage (1.0204-10.204 g). The saturation pH of zinc hydroxide is 8.93. The boron adsorption capacity reached to maximum value at pH value of 9 and this pH was selected as optimum value. Boron adsorption capacity increased with increasing concentration due to increasing driving force of concentration. High dosages increased the removal percentage. The adsorption of boron to zinc hydroxide had exothermic nature. The optimum conditions obtained from synthetic solutions were applied to the colemanite mine wastewater by 22 factorial design. The maximum boron adsorption capacity of zinc hydroxide from colemanite mine wastewater was calculated as 43.57 mg/g. The used material and process was promising for boron mine wastewater.

Destekleyen Kurum

Balıkesir Üniversitesi BAP birimi

Proje Numarası

BAP.2014

Teşekkür

The authors are gratefull for financial support of Balıkesir University Scientific Research Project Department

Kaynakça

  • [1] Korkmaz, M., Özmetin, C., and Fil, B.A. 2016. Modelling of Boron Removal from Solutions Using Purolite S 108 in a Batch Reactor. CLEAN–SoilAir Water; 44: 949–958.
  • [2] Vanlı, Ö. 2007. Removal of Pb, Cd, B Elements From Soil By Chelate Assisted Phytoremediation Method. Istanbul Technical University, Institute of Science and Technology, Master in Science Thesis, Istanbul.
  • [3] Bayar, D. 2001. Boron removal from aqueous solution by adsorption and experimental design”,Osman Gazi University, Institute of Science and Technology, Master in ScienceThesis, Eskişehir.
  • [4] Korkmaz, M., Fil, B.A., Özmetin, C., and Yaşar, Y. 2014. Full factorial design of experiments for boron removal from Colemanite mine wastewater using Purolite S 108 resin. Bulgarian Chemical Communucations; 46:594–601.
  • [5] Özmetin, C., Aydın, Ö., Kocakerim, M.M., Korkmaz, M., and Özmetin, E. 2009. An empirical kinetic model for calcium removal from calcium impurity-containing saturated boric acid solution by ion exchange technology using Amberlite IR–120 resin. Chemical Engineering Journal; 148: 420–424.
  • [6] Yılmaz, A.E. 2009. The Boron Removal from industrial wastewater by electrocoagulation method”, Atatürk University, Institute of Science and Technology, Ph.D. Thesis, Erzurum.
  • [7] Dural, E. 1998. Researching of production wastes of borax and boric acid fabrics of Etibank in Bandırma area bletoused in glaze composition (1000 oC-1200 oC). Anadolu University, Institute of Science and Technology, Master in Science Thesis, Eskişehir.
  • [8] Kutlu, M., Aydoğan, G., and Mumcu, E. 2007. Mutagenicity analysis of water samples from Seydisuyu (Kırka, Turkey) stream under the influence of boron production complex, Food and Chemical Toxicology; 45:2064–2068.
  • [9] Yilmaz, A.E., Boncukcuoğlu, R., Kocakerim, M.M., Yilmaz, M.T., and Paluluoğlu, C. 2008. Boron removal from geothermal waters by Electrocoagulation. Journal of Hazardous Materials; 153:146–151.
  • [10] Kluczka, J., Ciba, J., Trojanowska, J., Zolotajkin, M., Turek, M., and Dydo, P. 2007. Removal of boron dissolved in water. Environmental Progress; 26:71–77.
  • [11] Öztürk, N., and Köse, T.E. 2008. Boron removal from aqueous solutions by ion-exchange resin: Batch studies. Desalination; 227: 233–240.
  • [12] Na, J.W., and Lee, K.J., 1993. Characteristics of boronbadsorption on strong-base anion-exchange resin. Annals of Nuclear Energy; 20;455–462.
  • [13] Sayiner, G., Kandemirli, F., and Dimoglo, A. 2008. Evaluation of boron removal by electrocoagulation using iron and aluminum electrodes. Desalination; 230:205–212.
  • [14] Vasudevan, S., Lakshmi, J. and Sozhan, G. 2013. Electrochemically assisted coagulation for the removal of boron from water using zinc anode. Desalination; 310:122–129.
  • [15] Oo, M.H., and Song, L. 2009. Effect of pH and ionic strength on boron removal by RO membranes. Desalination; 246: 605–612.
  • [16] Hu, J., Pu, Y., Ueda, M., Zhang, X., and Wang, L. 2016. Charge-aggregate induced (CAI) reverse osmosis membrane for sea water desalination and boron removal. Journal of Membrane Science; 520:1–7.
  • [17] Yazicigil, Z., and Öztekin,Y. 2006. Boron removal by electrodialysis with anion-exchange membranes. Desalination; 190:71–78.
  • [18] Karakaş, Z.K., Yilmaz, M.T., Boncukçuoğlu, R., and Karakaş, İ.H. 2013. The Effect of the pH of the Solution in the Boron Removal using Poly aluminium Chloride (PAC) Coagulant with Chemical Coagulation Method. Journal Selcuk University Natural and Applied Science; 2; 339–346.
  • [19] Karcıoğlu, Z., Yılmaz, M.T., and Yılmaz, A.E. 2012. Boron Removal From Industrial Waste Waters By Using Aluminum Sulfate Coagulant With Chemical Methods. Iğdır University Journal of the Institute of Science and Technology; 2:15–22.
  • [20] Yilmaz, A.E., Boncukcuoğlu, R., and Kocakerim, M.M. 2007. A quantitative comparison between electrocoagulation and chemical coagulation for boron removal from boron-containing solution. Journal of Hazardous Materials; 149-475–481.
  • [21] Golder, A.K., Dhaneesh, V.S., Samanta, A.N. and Ray, S.2008. Removal of nickel and boron from plating rinse effluent by electrochemical and chemical techniques. Chemical Engineering Technology; 31:143-148.
  • [22] Foote, F.J.1932. Determination of boron in waters: Method for direct titration of boric acid. Industrial&Engineering ChemistryAnalytical Edition; 4:39–42.
  • [23] Davis, M.L. Water and wastewater engineering design principles and practice; The McGraw-Hill Companies, Inc., (2010).
  • [24] Kavak, D. 2011. Boron adsorption by clinoptilolite using factorial design. Environmental Progress&Sustainable Energy; 30: 527–532.
  • [25] Korkmaz, M., Özmetin, C., Özmetin, E., Ziyanak, Ö. 2020.Boron removal by coagulation using Al(OH)3 and factorial optimization of data for boron mine wastewater. Balıkesir Üniversitesi Fen Bilimleri Enstüsü Dergisi; 22(2): 687-697.
  • [26] Özmetin, C., Korkmaz,M. 2019. Full factorial design of experiments for boron removal by iron hydroxide from colemanite mine wastewater. Balıkesir Üniversitesi Fen Bilimleri Enstüsü Dergisi; 21(1):244-253.
Yıl 2022, , 77 - 83, 25.03.2022
https://doi.org/10.18466/cbayarfbe.951542

Öz

Proje Numarası

BAP.2014

Kaynakça

  • [1] Korkmaz, M., Özmetin, C., and Fil, B.A. 2016. Modelling of Boron Removal from Solutions Using Purolite S 108 in a Batch Reactor. CLEAN–SoilAir Water; 44: 949–958.
  • [2] Vanlı, Ö. 2007. Removal of Pb, Cd, B Elements From Soil By Chelate Assisted Phytoremediation Method. Istanbul Technical University, Institute of Science and Technology, Master in Science Thesis, Istanbul.
  • [3] Bayar, D. 2001. Boron removal from aqueous solution by adsorption and experimental design”,Osman Gazi University, Institute of Science and Technology, Master in ScienceThesis, Eskişehir.
  • [4] Korkmaz, M., Fil, B.A., Özmetin, C., and Yaşar, Y. 2014. Full factorial design of experiments for boron removal from Colemanite mine wastewater using Purolite S 108 resin. Bulgarian Chemical Communucations; 46:594–601.
  • [5] Özmetin, C., Aydın, Ö., Kocakerim, M.M., Korkmaz, M., and Özmetin, E. 2009. An empirical kinetic model for calcium removal from calcium impurity-containing saturated boric acid solution by ion exchange technology using Amberlite IR–120 resin. Chemical Engineering Journal; 148: 420–424.
  • [6] Yılmaz, A.E. 2009. The Boron Removal from industrial wastewater by electrocoagulation method”, Atatürk University, Institute of Science and Technology, Ph.D. Thesis, Erzurum.
  • [7] Dural, E. 1998. Researching of production wastes of borax and boric acid fabrics of Etibank in Bandırma area bletoused in glaze composition (1000 oC-1200 oC). Anadolu University, Institute of Science and Technology, Master in Science Thesis, Eskişehir.
  • [8] Kutlu, M., Aydoğan, G., and Mumcu, E. 2007. Mutagenicity analysis of water samples from Seydisuyu (Kırka, Turkey) stream under the influence of boron production complex, Food and Chemical Toxicology; 45:2064–2068.
  • [9] Yilmaz, A.E., Boncukcuoğlu, R., Kocakerim, M.M., Yilmaz, M.T., and Paluluoğlu, C. 2008. Boron removal from geothermal waters by Electrocoagulation. Journal of Hazardous Materials; 153:146–151.
  • [10] Kluczka, J., Ciba, J., Trojanowska, J., Zolotajkin, M., Turek, M., and Dydo, P. 2007. Removal of boron dissolved in water. Environmental Progress; 26:71–77.
  • [11] Öztürk, N., and Köse, T.E. 2008. Boron removal from aqueous solutions by ion-exchange resin: Batch studies. Desalination; 227: 233–240.
  • [12] Na, J.W., and Lee, K.J., 1993. Characteristics of boronbadsorption on strong-base anion-exchange resin. Annals of Nuclear Energy; 20;455–462.
  • [13] Sayiner, G., Kandemirli, F., and Dimoglo, A. 2008. Evaluation of boron removal by electrocoagulation using iron and aluminum electrodes. Desalination; 230:205–212.
  • [14] Vasudevan, S., Lakshmi, J. and Sozhan, G. 2013. Electrochemically assisted coagulation for the removal of boron from water using zinc anode. Desalination; 310:122–129.
  • [15] Oo, M.H., and Song, L. 2009. Effect of pH and ionic strength on boron removal by RO membranes. Desalination; 246: 605–612.
  • [16] Hu, J., Pu, Y., Ueda, M., Zhang, X., and Wang, L. 2016. Charge-aggregate induced (CAI) reverse osmosis membrane for sea water desalination and boron removal. Journal of Membrane Science; 520:1–7.
  • [17] Yazicigil, Z., and Öztekin,Y. 2006. Boron removal by electrodialysis with anion-exchange membranes. Desalination; 190:71–78.
  • [18] Karakaş, Z.K., Yilmaz, M.T., Boncukçuoğlu, R., and Karakaş, İ.H. 2013. The Effect of the pH of the Solution in the Boron Removal using Poly aluminium Chloride (PAC) Coagulant with Chemical Coagulation Method. Journal Selcuk University Natural and Applied Science; 2; 339–346.
  • [19] Karcıoğlu, Z., Yılmaz, M.T., and Yılmaz, A.E. 2012. Boron Removal From Industrial Waste Waters By Using Aluminum Sulfate Coagulant With Chemical Methods. Iğdır University Journal of the Institute of Science and Technology; 2:15–22.
  • [20] Yilmaz, A.E., Boncukcuoğlu, R., and Kocakerim, M.M. 2007. A quantitative comparison between electrocoagulation and chemical coagulation for boron removal from boron-containing solution. Journal of Hazardous Materials; 149-475–481.
  • [21] Golder, A.K., Dhaneesh, V.S., Samanta, A.N. and Ray, S.2008. Removal of nickel and boron from plating rinse effluent by electrochemical and chemical techniques. Chemical Engineering Technology; 31:143-148.
  • [22] Foote, F.J.1932. Determination of boron in waters: Method for direct titration of boric acid. Industrial&Engineering ChemistryAnalytical Edition; 4:39–42.
  • [23] Davis, M.L. Water and wastewater engineering design principles and practice; The McGraw-Hill Companies, Inc., (2010).
  • [24] Kavak, D. 2011. Boron adsorption by clinoptilolite using factorial design. Environmental Progress&Sustainable Energy; 30: 527–532.
  • [25] Korkmaz, M., Özmetin, C., Özmetin, E., Ziyanak, Ö. 2020.Boron removal by coagulation using Al(OH)3 and factorial optimization of data for boron mine wastewater. Balıkesir Üniversitesi Fen Bilimleri Enstüsü Dergisi; 22(2): 687-697.
  • [26] Özmetin, C., Korkmaz,M. 2019. Full factorial design of experiments for boron removal by iron hydroxide from colemanite mine wastewater. Balıkesir Üniversitesi Fen Bilimleri Enstüsü Dergisi; 21(1):244-253.
Toplam 26 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Mustafa Korkmaz 0000-0001-8424-6339

Cengiz Özmetin 0000-0003-3962-9255

Elif Ozmetin 0000-0002-3318-4083

Elif Çalgan 0000-0002-6794-1863

Öznur Ziyanak 0000-0003-2592-8641

Proje Numarası BAP.2014
Yayımlanma Tarihi 25 Mart 2022
Yayımlandığı Sayı Yıl 2022

Kaynak Göster

APA Korkmaz, M., Özmetin, C., Ozmetin, E., Çalgan, E., vd. (2022). Boron Removal from Colemanite Mine Wastewater by Coagulation using Zinc Hydroxide―A Factorial Optimization Study. Celal Bayar Üniversitesi Fen Bilimleri Dergisi, 18(1), 77-83. https://doi.org/10.18466/cbayarfbe.951542
AMA Korkmaz M, Özmetin C, Ozmetin E, Çalgan E, Ziyanak Ö. Boron Removal from Colemanite Mine Wastewater by Coagulation using Zinc Hydroxide―A Factorial Optimization Study. CBUJOS. Mart 2022;18(1):77-83. doi:10.18466/cbayarfbe.951542
Chicago Korkmaz, Mustafa, Cengiz Özmetin, Elif Ozmetin, Elif Çalgan, ve Öznur Ziyanak. “Boron Removal from Colemanite Mine Wastewater by Coagulation Using Zinc Hydroxide―A Factorial Optimization Study”. Celal Bayar Üniversitesi Fen Bilimleri Dergisi 18, sy. 1 (Mart 2022): 77-83. https://doi.org/10.18466/cbayarfbe.951542.
EndNote Korkmaz M, Özmetin C, Ozmetin E, Çalgan E, Ziyanak Ö (01 Mart 2022) Boron Removal from Colemanite Mine Wastewater by Coagulation using Zinc Hydroxide―A Factorial Optimization Study. Celal Bayar Üniversitesi Fen Bilimleri Dergisi 18 1 77–83.
IEEE M. Korkmaz, C. Özmetin, E. Ozmetin, E. Çalgan, ve Ö. Ziyanak, “Boron Removal from Colemanite Mine Wastewater by Coagulation using Zinc Hydroxide―A Factorial Optimization Study”, CBUJOS, c. 18, sy. 1, ss. 77–83, 2022, doi: 10.18466/cbayarfbe.951542.
ISNAD Korkmaz, Mustafa vd. “Boron Removal from Colemanite Mine Wastewater by Coagulation Using Zinc Hydroxide―A Factorial Optimization Study”. Celal Bayar Üniversitesi Fen Bilimleri Dergisi 18/1 (Mart 2022), 77-83. https://doi.org/10.18466/cbayarfbe.951542.
JAMA Korkmaz M, Özmetin C, Ozmetin E, Çalgan E, Ziyanak Ö. Boron Removal from Colemanite Mine Wastewater by Coagulation using Zinc Hydroxide―A Factorial Optimization Study. CBUJOS. 2022;18:77–83.
MLA Korkmaz, Mustafa vd. “Boron Removal from Colemanite Mine Wastewater by Coagulation Using Zinc Hydroxide―A Factorial Optimization Study”. Celal Bayar Üniversitesi Fen Bilimleri Dergisi, c. 18, sy. 1, 2022, ss. 77-83, doi:10.18466/cbayarfbe.951542.
Vancouver Korkmaz M, Özmetin C, Ozmetin E, Çalgan E, Ziyanak Ö. Boron Removal from Colemanite Mine Wastewater by Coagulation using Zinc Hydroxide―A Factorial Optimization Study. CBUJOS. 2022;18(1):77-83.