BibTex RIS Kaynak Göster

Boric Acid Production From Sodium Metaborate With Sulfuric Acid

Yıl 2015, Cilt: 11 Sayı: 3, 0 - , 23.12.2015

Hilal Demirel Taylan İnce Duygu Uysal Bekir Uysal

https://doi.org/10.18466/cbujos.22763
Cited By: 1

Öz

In this study, boric acid production with aqueous phase reaction of sodium metaborate with sulfuric acid is investigated. Sodium metaborate is the byproduct of catalytic hydrolysis of sodium borohydride reaction. It was reacted batchwise at 90oC for 30 minutes with 98% H2SO4 solution. After the boric acid production, purification was investigated using ethanol, acetone and saturated boric acid solution. 97.78%, 93.13% and 100% pure boric acid products were obtained, respectively. These results, supported by XRD analysis, indicate that the proposed method was successful and it is possible to produce boric acid by reacting sodium metaborate directly with sulfuric acid.

Anahtar Kelimeler

sodium metaborate; boric acid; sodium borohydride

Kaynakça

  • http://www.etimaden.gov.tr/borik-asit-113s.htm , 02.07.2015
  • Newman, A. 1932. Process of preparing boric Acid. ABD Patent (1,888,391).
  • Taylor, D. S. 1953. Production and seperation of anhydrous alkali metal sulfate and boric acid. ABD Patenti (2,637,626)
  • Taylor, D. S. 1956. Production of boric acid and anhydrous sodium sulfate, ABD Patenti (2,746,841).
  • Bedri, D. E. & Tolun, R. 1979. Boric Acid and Sodium Sulphate Produciton from Tincale ,Tubitak Report .
  • Boric Acid Production from Tincal, A. Mergen, H. Demirhan, M. Bilen, H. Cebi & M, Gündüz Eti Holding A.Ş., Directorate of Ress.&Dev. Department, Ankara, TURKEY, 2001.
  • http://www.boren.gov.tr/tr/projeler/proje-ciktilari/uretim-ve-uygulama-teknolojisi-gelistirilen-urunler, 14.07.2015
  • İ. Kayacan, Ö. M. Dogan, B. Z. Uysal, Int Jr of Hydrogen Energy, 2011, 36 (13), 7410-7415.
  • Gögce, Ö. Ö, U. G. Zafer, B. Z. Uysal, Proceedings of 4th Intn. Boron Symposium, 2009, Ed. A. Konuk et al., Eskişehir, 267-271.
  • Schlesinger, H. I., H. C. Brown, A. E. Finhold, Jr of American Chemical Society, 1953, 75, 205-209.
  • Product Data Sheet Sodium Metaborate 8 Mol, 20 Mule Team Borax.
  • Product Data Sheet Optibor Boric Acids, 20 Mule Team Borax.
  • Perry, R . Perry's Chemical Engineers' Handbook, 6th edition, McGraw-Hill Book Company,1984.

Yıl 2015, Cilt: 11 Sayı: 3, 0 - , 23.12.2015

Hilal Demirel Taylan İnce Duygu Uysal Bekir Uysal

https://doi.org/10.18466/cbujos.22763
Cited By: 1

Öz

Kaynakça

  • http://www.etimaden.gov.tr/borik-asit-113s.htm , 02.07.2015
  • Newman, A. 1932. Process of preparing boric Acid. ABD Patent (1,888,391).
  • Taylor, D. S. 1953. Production and seperation of anhydrous alkali metal sulfate and boric acid. ABD Patenti (2,637,626)
  • Taylor, D. S. 1956. Production of boric acid and anhydrous sodium sulfate, ABD Patenti (2,746,841).
  • Bedri, D. E. & Tolun, R. 1979. Boric Acid and Sodium Sulphate Produciton from Tincale ,Tubitak Report .
  • Boric Acid Production from Tincal, A. Mergen, H. Demirhan, M. Bilen, H. Cebi & M, Gündüz Eti Holding A.Ş., Directorate of Ress.&Dev. Department, Ankara, TURKEY, 2001.
  • http://www.boren.gov.tr/tr/projeler/proje-ciktilari/uretim-ve-uygulama-teknolojisi-gelistirilen-urunler, 14.07.2015
  • İ. Kayacan, Ö. M. Dogan, B. Z. Uysal, Int Jr of Hydrogen Energy, 2011, 36 (13), 7410-7415.
  • Gögce, Ö. Ö, U. G. Zafer, B. Z. Uysal, Proceedings of 4th Intn. Boron Symposium, 2009, Ed. A. Konuk et al., Eskişehir, 267-271.
  • Schlesinger, H. I., H. C. Brown, A. E. Finhold, Jr of American Chemical Society, 1953, 75, 205-209.
  • Product Data Sheet Sodium Metaborate 8 Mol, 20 Mule Team Borax.
  • Product Data Sheet Optibor Boric Acids, 20 Mule Team Borax.
  • Perry, R . Perry's Chemical Engineers' Handbook, 6th edition, McGraw-Hill Book Company,1984.
Toplam 13 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Makaleler
Yazarlar

Hilal Demirel Bu kişi benim

Taylan İnce Bu kişi benim

Duygu Uysal Bu kişi benim

Bekir Uysal

Yayımlanma Tarihi 23 Aralık 2015
Yayımlandığı Sayı Yıl 2015 Cilt: 11 Sayı: 3

Kaynak Göster

APA Demirel, H., İnce, T., Uysal, D., Uysal, B. (2015). Boric Acid Production From Sodium Metaborate With Sulfuric Acid. Celal Bayar University Journal of Science, 11(3). https://doi.org/10.18466/cbujos.22763
AMA Demirel H, İnce T, Uysal D, Uysal B. Boric Acid Production From Sodium Metaborate With Sulfuric Acid. CBUJOS. Aralık 2015;11(3). doi:10.18466/cbujos.22763
Chicago Demirel, Hilal, Taylan İnce, Duygu Uysal, ve Bekir Uysal. “Boric Acid Production From Sodium Metaborate With Sulfuric Acid”. Celal Bayar University Journal of Science 11, sy. 3 (Aralık 2015). https://doi.org/10.18466/cbujos.22763.
EndNote Demirel H, İnce T, Uysal D, Uysal B (01 Aralık 2015) Boric Acid Production From Sodium Metaborate With Sulfuric Acid. Celal Bayar University Journal of Science 11 3
IEEE H. Demirel, T. İnce, D. Uysal, ve B. Uysal, “Boric Acid Production From Sodium Metaborate With Sulfuric Acid”, CBUJOS, c. 11, sy. 3, 2015, doi: 10.18466/cbujos.22763.
ISNAD Demirel, Hilal vd. “Boric Acid Production From Sodium Metaborate With Sulfuric Acid”. Celal Bayar University Journal of Science 11/3 (Aralık 2015). https://doi.org/10.18466/cbujos.22763.
JAMA Demirel H, İnce T, Uysal D, Uysal B. Boric Acid Production From Sodium Metaborate With Sulfuric Acid. CBUJOS. 2015;11. doi:10.18466/cbujos.22763.
MLA Demirel, Hilal vd. “Boric Acid Production From Sodium Metaborate With Sulfuric Acid”. Celal Bayar University Journal of Science, c. 11, sy. 3, 2015, doi:10.18466/cbujos.22763.
Vancouver Demirel H, İnce T, Uysal D, Uysal B. Boric Acid Production From Sodium Metaborate With Sulfuric Acid. CBUJOS. 2015;11(3).

Cited By

Boric Acid: A Mild and Efficient Green Catalyst for Organic Transformations
SynOpen
https://doi.org/10.1055/a-2110-2785