REMOVAL OF CHROMIUM (VI) ION FROM LEATHER WASTEWATERS BY ADSORPTION

Yıl 2014, Cilt: 10 Sayı: 1, 11 - 24, 06.01.2015

Murat Canlı , Yüksel Abalı , Banu Öztekin Kamil Şirin

https://doi.org/10.18466/cbufbe.36355

Cited By: 2

Öz

Alternative wastewater treatment methods are developed in recent years. One elimination method of heavy metals from the waste water is the adsorption of heavy metals. Cr (VI) is a heavy metal which is cause of water pollution and toxic effect on the living structures. In this study, the adsorption of Cr (VI) and removal of other polluted parameters was researched using natural adsorbents as clinoptilolite, activated clinoptilolite with acid. The study consists of two experimental parts. In the first part, principal factors affecting the adsorption were investigated. Suitable mix rate, pH, particular size of adsorbent, concentration, amount of adsorbent, temperature were invented and the optimum conditions were determined for chromium (VI) solutions. In the second part, adsorption tests were done with waste water under pre-determined optimum conditions for the adsorbents. Experimental studies were taken place on removal of COD (Chemical Oxygen Demand), SS (Suspend Solid), BOD (Biological Oxygen Demand) and chromium (VI) from composite sample of the tannery waste water. The outputs of adsorption using clinoptilolite and activated clinoptilolite for COD, SS, BOİ and chromium(VI) respectively about %50, %55, %33, %80 was obtained

Anahtar Kelimeler

Clinoptilolite, chromium(VI), Leather industry wastewater, adsorption

DERİ SANAYİ ATIK SULARINDAN KROM (VI) İYONUNUN ADSORBSİYONU - REMOVAL OF CHROMIUM (VI) ION FROM LEATHER WASTEWATERS BY ADSORPTION

Öz

DERİ SANAYİ ATIK SULARINDAN KROM (VI) İYONUNUN ADSORBSİYONU

Son yıllarda atık suların arıtılmasında alternatif arıtım yöntemleri geliştirilmektedir. Atık sulardaki ağır metalleri gidermek için kullanılan yöntemlerden birisi de ağır metallerin adsorpsiyonudur. Bir ağır metal olan Cr(VI), su kirliliğine ve canlı bünyesinde toksik etkiye neden olur. Bu çalışmada klinoptilolit, asit ile aktive edilmiş klinoptilolit gibi doğal adsorbanlar kullanılarak Cr(VI) iyonunun adsorpsiyonu ve deri atık suyundaki diğer kirletici parametrelerin giderimi araştırılmıştır.Bu çalışmada, adsorpsiyona etki eden temel faktörler incelendikten sonra çalışma parametreleri olarak uygun karıştırma hızı, pH, adsorbanın uygun tanecik boyutu, uygun konsantrasyon, adsorban miktarı ve sıcaklık bulunmuştur. Krom (VI) çözeltileri için optimum şartlar belirlenmiştir. Daha sonra, kullanılan adsorban maddeler için önceden belirlenmiş optimum koşullarda atık su ile adsorpsiyon deneyleri yapılmıştır. Deneysel çalışmalarda bir deri endüstrisi atık sularından kompozit olarak alınan numunede, KOİ (Kimyasal Oksijen İhtiyacı), AKM (Askıda Katı Madde), BOİ (Biyolojik Oksijen İhtiyacı) ve Krom (VI) parametrelerinin giderimi üzerine çalışılmıştır. Klinoptilolit ve aktif klinoptilolit kullanımıyla sırasıyla KOİ, AKM, BOİ ve krom(VI) değerleri için; %50, %55, %33 ve % 80 civarında adsorpsiyon verimleri elde edilmiştir.

 

REMOVAL OF CHROMIUM (VI) ION FROM LEATHER WASTEWATERS BY ADSORPTION

Alternative wastewater treatment methods are developed in recent years. One elimination method of heavy metals from the waste water is the adsorption of heavy metals. Cr (VI) is a heavy metal which is cause of water pollution and toxic effect on the living structures. In this study, the adsorption of Cr (VI) and removal of other polluted parameters was researched using natural adsorbents as clinoptilolite, activated clinoptilolite with acid. The study consists of two experimental parts. In the first part, principal factors affecting the adsorption were investigated. Suitable mix rate, pH, particular size of adsorbent, concentration, amount of adsorbent, temperature were invented and the optimum conditions were determined for chromium (VI) solutions. In the second part, adsorption tests were done with waste water under pre-determined optimum conditions for the adsorbents. Experimental studies were taken place on removal of COD (Chemical Oxygen Demand), SS (Suspend Solid), BOD (Biological Oxygen Demand) and chromium (VI) from composite sample of the tannery waste water. The outputs of adsorption using clinoptilolite and activated clinoptilolite for COD, SS, BOİ and chromium(VI) respectively about %50, %55, %33, %80 was obtained.

 

 

 

Anahtar Kelimeler

Klinoptilolit, krom(VI), deri atık suyu, adsorpsiyon

Kaynakça

• Edesen, G., Han, A.; “Arıtmada Genel Kavramlar ve Pamuklu Tekstil Atık Sularının Arıtılması”, Sümerbank Holding AS., Yayın No : 127, Bursa, (1992).
• Toprak, R ve Girgin, İ. Aktifleştirilmiş Klinoptilolit ile Deri Sanayi Atık Sularından Kromun Giderilmesi. Turk J Engin Environ Sci 24 , 343- 351, (2000).
• Gündüz, T., Çevre Sorunları, 2. Baskı, Gazi Büro Kitabevi, Ankara, (1998).
• Sandel, P., Karlsson, S., Lohm, U.; “ Environmental Impacts of Old Mine Tailings Deposit Metal Concerations and Water Pathways”, Hydrology, 18, 301-302, (1987).
• Schmit, R.C., “ Lignin and It’s Degradation Products Are The Main Contributors to The Color and Toxicity of Bleanch, TAPPI, Vol:64, No:12, P:63, (1981).
• Uysal, Muradiye, “ Endüstriyel Atıksulardan Cr(VI)’nın Adsorpsiyon yöntemiyle Giderilmesi, Yüksek Lisans Tezi, Gazi Üniversitesi F.B.E, (2004).
• Kayar, V.N., “ Gediz Nehrindeki Bazı Kimyasal Kirlilik Parametrelerinin İncelenmesi” C.B.U, Yüksek Lisans Tezi, Manisa, (2000).
• Sarıkaya, Y. , Fizikokimya, Gazi Buro Kitabevi, Ankara, 633-641 (1997).
• Hıdıroğlu, B.N., Atık sulardaki Nikelin Adsorpsiyonla Giderimi, Yüksek Lisans Tezi, Gazi Üniversitesi F.B.E. (2003).
• Gak, V., Viraraghavan T., “ Removal of Heavy Metals at a Canadian Waste Water Treatment Plant, Journal of Environmental Science and Health, A 27, 13-23,
• Gharaibeh, S. H., Abu-El-Sha’r, W. Y., Al- Kofahi, M.M., “ Removal of Selected Heavy Metals from Aqueous Solutions using Processed Solid Residue of Olive Mill Products, Wat, Res., Vol. 32, No.2, 498-502, (1998).
• Pınarlı, V., Bilgic, S., Killerin Atık Su Arıtımında
• Sempozyumu, (27-30 Eylul 1995), Ankara. VII, Ulusal
• Kil . Rengaraj, S., Yeon, K., Kang, S., Leen, J., Kim, K., Moon, S., “ Studies on Adsorptive Removal of Co(II), Cr(III) and Ni(II) by IRN77 Cation-Exchange Resin, Journal of Hazardous Materials, B 92, s 185-198, (2002).
• Logar, N.Z., Siljeg, M., Arcon, I., Meden, A., Tusar, N.N., Stefanovic, S.C., Kovac, J., Kaucic, V., Sorption of Cr+3 on clinoptilolite tuff: A structural
• Mesoporous Materials, Vol. 93, p. 275-284 (2006). Microporous
• and . Chen, J. P., Wang, X. Y., “ Removing Copper, Zinc and Lead Ion by Granular Activated Carbon in Pretreated Fixed-Bed Columns, Separation and Purification (1999). 34(12),
• 2369-2381, [16]. Gharaibeh, S. H., Abu-El-Sha’r, W. Y., Al- Kofahi, M.M., “ Removal of Selected Heavy Metals from Aqueous Solutions using Processed Solid Residue of Olive Mill Products, Wat, Res.,
• Vol. 32, No.2, 498-502, (1998).
• Rengaraj, S., Yeon, K., Kang, S., Leen, J., Kim, K., Moon, S., “ Studies on Adsorptive Removal of Co(II), Cr(III) and Ni(II) by IRN77 Cation-Exchange Resin, Journal of Hazardous Materials, B 92, s 185-198, (2002).
• Motsi, T., Rowson, N.A., Simmons, M.J.H. Kinetic studies of the removal of heavy metals from acid mine drainage by natural zeolite, International Journal of Mineral Processing 101 (2011) 42–49.
• Santos Yabe, M. J., Oliveria, E., Heavy Metals Removal Industrial Effluents by Sequential Adsorbents Treatment, Departimento de Quimica, Universidade Estadual de Londrina,Londrina-PR, (2001), Brazil.
• Zorpas, A. A., Constantinides, T., Vlyssides, A. G., Haralambous, I., Loizidou, M., “ Heavy Metal Uptake by Natural Zeolite and Metals Partitioning
• Bioresource Technology, 72, 113-119, (2000). Sludge
• Composti [21]. Bilgin, A., “ Sulardaki Siyanürün Klinoptilolit Adsorpsiyonuyla Giderilmesi, Yüksek Lisans Tezi, Gazi Üniversitesi F.B.E. (2003).
• Erdoğan, B.C., Ülkü, S., Cr(VI) sorption by using clinoptilolite and bacteria loaded linoptilolite rich mineral, Microporous and Mesoporous Materials, Vol. 152, p. 253-261 (2012).
• Leyva-Ramos, R., Jacobo-Azuara, A., Diaz- Flores, P.E., Guerrero-Coronado, R.M., Mendoza- Barron, J., Berber-Mendoza, M.S., Adsorption of chromium(VI) from an aqueous solution on a surfactant-modified zeolite, Colloids and surfaces A, Physicochemical Engineering Aspects, Vol. 330, p.35-41, (2008).
• Bolortamir, T., Egashira, R., Removal of Hexavalent Chromium from Model Tannery Wastewater by Adsorption Using Mongolian Natural Zeolite, Journal of Chemical Engineering of Japan, Vol. 41(10), p.1003-1009, (2008).
• Orhan, Y., Kocaoba, S., Adsorption of toxic metals by natural and modified clinoptilolite, Annali Di Chimica, Vol. 97(8), p.781-790, (2007).
• Şengül, F., Endüstriyel Atık suların Özellikleri ve Arıtılması, Dokuz Eylül Üniversitesi Yayınları, 2. Baskı No: 172, İzmir. (1991).
• Türkiye Çevre Vakfı, “Türk Çevre Mevzuatı”, Cilt I, II, Ankara, Türkiye (1992).
• Pehlivanoğlu E., Ertas T. T., Tanık A., Kütahya A., “Chemical Treatability Of Dyeing Bath Wastewaters in Textile Industry”, First International Workshop on Enviromental Quality and Enviromental Engineering in The Middle East Region, p. 671-677, Konya,Turkey (1998).
• Vlyssides A.G., İsrailides C.J., Detoxification of Tannery Waste Liquors With an Electrolysis System, Environmental Pollution, Vol. 97, p. 147- 152 (1997).
• Farabegoli G., Carucci A, Majone M., Rolle E., “Biological Treatment of Tannery Wastewater in the Presence of Chromium”, Journal of Environmental Management, Vol. 71 p. 345–349 (2004).
• Topbaş M. T., Brohi A. R., Karaman M. R., “Cevre Kirliliği”, T.C. Çevre Bakanlığı Yayınları, Ankara, Turkiye (1998).
• Food and Nutrition Board : Subcommittee on the Ninth Edition of The RDAS, National Research Council, Recommended Dietary Allowances, 10th. Ed. Netl. Acad. Acad. Pres, Washingtion, DC. (1989).
• Diane M., “Is Chromium a Trace Essential Metal”, Biofactors, Vol.11, Issue 3, p 142 (2000).
• Tunay O., Ovez S., Alp K., Sakar S., Sunter İ., “Endustriyel Atıksuların On Arıtılması”, Teknoloji İletimi Semineri No: 1, İSO-SKATMK, İstanbul, Turkiye (1991).
• Özdemir, C., Dursun, Ş., Argun, M.E., Karataş, M., Doğan, S., Özcan, R., Çiçek, S., “Deri Endüstrisi Atık sularındaki Krom (VI) Arıtımında Alternatif
• Sempozyumu, Ege Ünv., p. 353 - 358, İzmir, (2004). 1. Ulusal
• Deri [36]. Zeng, Y., Woo, H., Lee, G., Park, J., Removal of chromate from water using surfactant modified Pohang clinoptilolite and Haruna chabazite, Desalination, Vol. 257 (1-3), p. 102-109, (2010).
• Rao M., Parwate A.V., Bhole A.G., “Removal of Cr6+ and Ni2+ from Aqueous Solution Using Bagasse and Fly Ash”, Waste Management, Vol. 28, p. 821-830, (2002). [38].
• Kullanılarak Atık Sulardan Kursun(II) İyonunun Adsorpsiyonu” , Celal Bayar Üniversitesi, Yüksek Lisans Tezi (2006), 117s.
• Çanlı, M., Abalı, Y., Bayça, S.U. Removal of methylene blue by natural and Ca and K-exchanged zeolite
• Physicochemical Problems of Mineral Processing 49(2), 481−496 (2013). hydrogen
• peroxide. Geliş Tarihi:26.11.2013
• Kabul Tarihi:05.03.2014