Development of Highly Sensitive Metal-Free Tetraphenylporphyrin-Based Optical Oxygen Sensing Materials along with ILs and AgNPs

Yıl 2019, Cilt: 15 Sayı: 1, 131 - 138, 22.03.2019

Merve Zeyrek Ongun

https://doi.org/10.18466/cbayarfbe.507626

Cited By: 2

Öz

An
oxygen sensitive optical chemical sensor has been developed based on
fluorescence quenching of the meso-tetraphenylporphyrin (H₂TPP)
immobilized in a silicone derivative along with silver nanoparticles (AgNPs)
and different ionic liquids (ILs). Emission spectra of the H₂TTP
doped thin film exhibited an increment due to the formation of an associated
complex between H₂TPP and AgNPs. The offered thin films responded to
the oxygen in the direction of quenching with extreme sensitivity. Emission and
decay-time measurements of the H₂TPP in thin solid matrices were
studied in the concentration range of 0-100% p(O₂). Utilization of
the porphyrin dye along with AgNPs and ionic liquid as an additive exhibited
higher oxygen sensitivity with respect to the additive-free forms and resulted
in many advances such as linear response, improvement in sensor dynamics and
extreme sensitivity. Together with additives, the
meso-tetraphenylporphyrin-based composites yielded higher Stern-Volmer constant
(Ksv), faster response time, and larger linear response range when compared
with the additive-free form. The response time of the sensor has been recorded
as 90 s

Anahtar Kelimeler

meso-tetraphenylporphyrin (H2TPP), silver nanoparticles, ionic liquids, O2, sensing

Kaynakça

• 1. Potyrailo, RA, Hieftje, GM, Oxygen detection by fluorescence quenching of tetraphenylporphyrin immobilized in the original cladding of an optical fiber, Analytica Chimica Acta, 1998; 370, 1–8.
• 2. Bussetti, G, Campione, M, Sassella, A, Duò, L, Optical and morphological properties of ultra-thin H2TPP, H4TPP and ZnTPP films, Physica Status Solidi (B), 2015, 252(1), 100–104.
• 3. Weegen, R, Abraham, JP, Meijer, EW, Directing the self-assembly behaviour of porphyrin-based supramolecular systems, Chemistry – A European Journal, 2017, 23, 3773 –3783.
• 4. Hasselman, GM, Watson, DF, Stromberg JR, Bocian, DF, Holten, D, Lindsey, JS, Meyer, GJ, Theoretical solar-to-electrical energy-conversion efficiencies of perylene−porphyrin light-harvesting arrays, The Journal of Physical Chemistry B, 2006, 110 (50), 25430–25440.
• 5. Yang, X, Peng, L, Yuan, L, Teng, P, Tian, F, Li, L, Luo, S, Oxygen gas optrode based on microstructured polymer optical fiber segment, Optics Communications, 2011, 284, 3462–3466.
• 6. Mosinger, J, Lang, K, Plistil, L, Jesenska, S, Hostomsky, J, Zelinger, Z, Kubat, P, Fluorescent polyurethane nanofabrics: A source of singlet oxygen and oxygen sensing, Langmuir, 2010, 26, 10050–10056.
• 7. Topal, SZ, Onal, E, Ertekin, K, Oter, O, Gürek AG, Hirel C, Significant sensitivity and stability enhancement of tetraphenylporphyrin-based optical oxygen sensing material in presence of perfluorochemicals, Journal of Porphyrins and Phthalocyanines, 2013, 17(6), 431-439.
• 8. Onal, E, Ay, Z, Yel, Z, Ertekin, K Gürek AG, Topal, SZ, Hirel C, Design of oxygen sensing nanomaterial: Synthesis, encapsulation of phenylacetylide substituted Pd(II) and Pt(II) meso-tetraphenylporphyrins into poly(1- trimethylsilyl-1-propyne) nanofibers and influence of silver nanoparticles, Royal Society of Chemistry Advances, 2016, 6, 9967–9977.
• 9. Kotiaho, A, Lahtinen, RM, Tkachenko, NV, Efimov, A, Kira, A, Imahori, H, Lemmetyinen, H, Gold nanoparticle enhanced charge transfer in thin film assemblies of porphyrin-fullerene dyads. Langmuir, 2007, 23, 13117–13125.
• 10. Oter, O, Sabancı, G, Ertekin, K, Enhanced CO2 sensing with ionic liquid modified electrospun nanofibers: Effect of ionic liquid type, Sensor Letters, 2013, 11(9), 1591-1599.
• 11. Solomon, SD, Bahadory, M, Jeyarajasingam, AV, Rutkowsky, SA, Boritz C, Mulfinger, L, Synthesis and study of silver nanoparticles, Journal of Chemical Education, 2007, 84(2), 322-325.
• 12. Lowe, KC, Perfluorochemical respiratory gas carriers: Benefits to cell culture systems, Journal of Fluorine Chemistry, 2002, 118, 19–26.
• 13. Topal, SZ, Ongun, MZ, Onal, E, Ertekin, K Hirel, C, Hyperporphyrin effect on oxygen sensitivity of free meso-tetraphenylporphyrins,  Dyes and Pigments, 2017, 144, 102-109.
• 14. Anthony, JL, Maginn, EJ, Brennecke, JFJ, Solubilities and thermodynamic properties of gases in the ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate, The Journal of Physical Chemistry B, 2002, 106, 7315–7320.
• 15. Ongun, MZ, Oter, O, Sabancı, G, Ertekin, K, Celik, E, Enhanced stability of ruthenium complex in ionic liquid doped electrospun fibers, Sensors and Actuators B, 2013, 183, 11–19.
• 16. Lakowicz, J.R, Principles of Fluorescence Spectroscopy; University of Maryland School of Medicine Baltimore, Press: Springer,Third Edition Maryland, USA, 2006.
• 17. MacCraith, BD, McDonagh, CM, O’Keeffe, G, Keyes, ET, Vos, JG, O’Kelly, B, McGlip, JF, Fibre optic oxygen sensor based on fluorescence quenching of evanescent-wave excited ruthenium complexes in sol–gel derived porous coatings, Analyst, 1993, 118, 385–388.
• 18. Ozturk, O, Oter, O, Yildirim, S, Subasi, E, Ertekin, K, Celik, E, Temel, H, Tuning oxygen sensitivity of ruthenium complex exploiting silver nanoparticles, Journal of Luminescence, 2014, 155, 191-197.