Yıl 2019, Cilt 15 , Sayı 4, Sayfalar 351 - 356 2019-12-30

Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles

Salih GÜNNAZ [1]


In this study, bis-benzimidazole ligands (1a-d) were synthesized using linker groups and they were evaluated as catalyst generated in situ from [RuCl2(p-cymene)]2 for transfer hydrogenation (TH) of acetophenone. The bimetallic Ru (II) arene complex (2b) synthesized from ligand 1b which showed the best activity among the ligands in the catalytic TH reaction. The obtained ligands and 2b complex were characterized by 1H- and 13C-NMR, elemental analysis and IR spectroscopy. The catalytic activities of complexes having different chain lengths and Y (CH3 or H) groups were compared. The highest conversion (99%) was obtained with 2b.

0000-0002-7422-6593
Bis-benzimidazole, ruthenium, transfer hydrogenation
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Birincil Dil en
Bölüm Makaleler
Yazarlar

Orcid: 0000-0002-7422-6593
Yazar: Salih GÜNNAZ (Sorumlu Yazar)
Kurum: EGE UNIVERSITY
Ülke: Turkey


Tarihler

Yayımlanma Tarihi : 30 Aralık 2019

Bibtex @araştırma makalesi { cbayarfbe632188, journal = {Celal Bayar University Journal of Science}, issn = {1305-130X}, eissn = {1305-1385}, address = {}, publisher = {Celal Bayar Üniversitesi}, year = {2019}, volume = {15}, pages = {351 - 356}, doi = {10.18466/cbayarfbe.632188}, title = {Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles}, key = {cite}, author = {GÜNNAZ, Salih} }
APA GÜNNAZ, S . (2019). Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles. Celal Bayar University Journal of Science , 15 (4) , 351-356 . DOI: 10.18466/cbayarfbe.632188
MLA GÜNNAZ, S . "Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles". Celal Bayar University Journal of Science 15 (2019 ): 351-356 <https://dergipark.org.tr/tr/pub/cbayarfbe/issue/50875/632188>
Chicago GÜNNAZ, S . "Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles". Celal Bayar University Journal of Science 15 (2019 ): 351-356
RIS TY - JOUR T1 - Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles AU - Salih GÜNNAZ Y1 - 2019 PY - 2019 N1 - doi: 10.18466/cbayarfbe.632188 DO - 10.18466/cbayarfbe.632188 T2 - Celal Bayar University Journal of Science JF - Journal JO - JOR SP - 351 EP - 356 VL - 15 IS - 4 SN - 1305-130X-1305-1385 M3 - doi: 10.18466/cbayarfbe.632188 UR - https://doi.org/10.18466/cbayarfbe.632188 Y2 - 2019 ER -
EndNote %0 Celal Bayar Üniversitesi Fen Bilimleri Dergisi Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles %A Salih GÜNNAZ %T Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles %D 2019 %J Celal Bayar University Journal of Science %P 1305-130X-1305-1385 %V 15 %N 4 %R doi: 10.18466/cbayarfbe.632188 %U 10.18466/cbayarfbe.632188
ISNAD GÜNNAZ, Salih . "Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles". Celal Bayar University Journal of Science 15 / 4 (Aralık 2020): 351-356 . https://doi.org/10.18466/cbayarfbe.632188
AMA GÜNNAZ S . Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles. Celal Bayar Univ J Sci. 2019; 15(4): 351-356.
Vancouver GÜNNAZ S . Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles. Celal Bayar University Journal of Science. 2019; 15(4): 356-351.