Effect of Graphene Addition on Erosion Corrosion Behavior of 3005 Alloy Coated by Micro-Arc Oxidation Method

Yıl 2024, Cilt: 39 Sayı: 1, 47 - 56, 28.03.2024

Aysun Ayday , Yaren Balaban , Ayça Şimşek

https://doi.org/10.21605/cukurovaumfd.1459357

Öz

In the study, surface modification of 3005 aluminum alloy was carried out (different coating time and graphene ratios) with micro arc oxidation (MAO) technology. Surface characterization, phase analysis and erosion corrosion test of the coated samples were performed. After the process, it was observed that the alloy was coated successfully with MAO method, a denser coating layer was obtained with the addition of graphene and the pores on the surface were reduced. After MAO coating, it was detected a significant increase in erosion-corrosion resistance. It was determined that there was a 17.4% improvement in corrosion resistance with increasing graphene content.

Anahtar Kelimeler

Aluminum, 3005, Graphene, Micro-arc oxidation, Erosion corrosion

Grafen Katkısının Mikro Ark Oksidasyon ile Kaplanmış 3005 Alaşımının Erozyon Korozyon Davranışı Üzerine Etkisi

Öz

Çalışmada 3005 alüminyum alaşımı, mikro ark oksidasyon (MAO) teknolojisi ile farklı işlem sürelerinde ve farklı oranlarda grafen ilavesi ile yüzey modifikasyonu gerçekleştirilmiştir. Kaplanan numunelerin yüzey karakterizasyonu, faz analizi ve erozyon korozyonu testi gerçekleştirilmiştir. İşlem sonrası alaşımın MAO yöntemi ile başarılı bir şekilde kaplandığı, grafen ilavesi ile daha yoğun bir kaplama tabakası elde edildiği ve yüzeydeki porların azaldığı gözlemlenmiştir. MAO sonrası numunelerde erozyon-korozyon dayanımında belirgin bir artış tespit edilmiştir. Artan grafen oranı ile erozyon korozyonu dayanımının iyileşme gösterdiği raporlanmış ve işlemsiz numuneye göre korozyon dayanımında 17,4% oranında iyileşme olduğu tespit edilmiştir.

Anahtar Kelimeler

Alüminyum, 3005, Grafen, Mikro ark oksidasyon, Erozyon korozyonu

Kaynakça

• 1. Ling K., Mo Q., Lv X., Qin G., Yang W., Li, L., Li, W., 2022. Growth Characteristics and Corrosion Resistance of Micro-Arc Oxidation Coating on Al–Mg Composite Plate. Vacuum, 195, 110640.
• 2. Chen, Q., Jiang, Z., Tang, S., Dong, W., Tong, Q., Li, W., 2017. Influence of Graphene Particles on the Micro-Arc Oxidation Behaviors of 6063 Aluminum Alloy and the Coating Properties. Applied Surface Science, 423, 939-950.
• 3. Dai, W., Zhang, C., Zhao, L., Li, C., 2022. Effects of Cu Content in Al-Cu Alloys on Microstructure, Adhesive Strength, and Corrosion Resistance of Thick Micro-Arc Oxidation Coatings. Materials Today Communications, 33, 104195.
• 4. Korkmaz, K., Çakır, A., 2017. Mikro-Ark Oksidasyon Yöntemi İle Oksitlenen 2017A Alüminyumun Erozyon- Korozyon Direncinin İncelenmesi. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 23(8), 979-983.
• 5. Huang, J., Dun, Y., Wan, Q., Wu, Z., Zhao, X., Tang, Y., Zhang, X., Zuo, Y., 2022. Improved Corrosion Resistance of MAO Coating on Mg-Li Alloy by RGO Modified Silanization. Journal of Alloys and Compounds, 929, 167283.
• 6. Zhang, J., Dai, W., Wang, X., Wang, Y., Yue, H., Li, Q., Yang, X., Guo, C., Li, C., 2023. Micro-Arc Oxidation of Al Alloys: Mechanism, Microstructure, Surface Properties, and Fatigue Damage Behavior. Journal of Materials Research and Technology, 23, 4307-4333.
• 7. Guan, S., Qi, M., Li, Y., Wang, W., 2020. Morphology Evolution of the Porous Coatings on Ti–xAl Alloys by Al Adding Into Ti During Micro-Arc Oxidation in Na2B4O7 Electrolyte. Surface and Coatings Technology, 395, 125948.
• 8. Chen, Y., Wu, L., Yao, W., Wu, J., Yuan, Y., Xie, Z., Jiang, B., Pan, F., 2022. Synergistic Effect of Graphene Oxide/Ternary Mg-Al-La Layered Double Hydroxide for Dual Self-Healing Corrosion Protection of Micro-Arc Oxide Coating of Magnesium Alloy. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 655, 130339.
• 9. Ayday, A., 2018. Coatings of Bioactive TiO2 Films on Ti6Al4V Alloy by Micro Arc Oxidation. Acta Physica Polonica A, 134.
• 10. Kaseem, M., Lee, Y.H., Ko, Y.G., 2016. Incorporation of MoO2 and ZrO2 Particles Into the Oxide Film Formed on 7075 Al Alloy Via Micro-Arc Oxidation. Materials Letters, 182, 260-263.
• 11. Liu, W., Liu, Y., Lin, Y., Zhang, Z., Feng, S., Talha, M., Shi, Y., Shi, T., 2019. Effects of Graphene on Structure and Corrosion Resistance of Plasma Electrolytic Oxidation Coatings Formed on D16T Al Alloy. Applied Surface Science, 475, 645-659.
• 12. Sundararajan, G., Krishna, L.R., 2003. Mechanisms Underlying the Formation of Thick Alumina Coatings Through the MAO Coating Technology. Surface and Coatings Technology, 167, 269-277.
• 13. Aydin, F., Ayday, A., Turan, M.E., Zengin, H., 2020. Role of Graphene Additive on Wear and Electrochemical Corrosion Behaviour of Plasma Electrolytic Oxidation (PEO) Coatings on Mg–MWCNT Nanocomposite. Surface Engineering, 36(8), 791-799.