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Effect of FEC and VC Additives in Electrolyte on the Performance of Si Anode for Lithium Ion Cell

Yıl 2018, Cilt: 33 Sayı: 3, 113 - 120, 30.09.2018
https://doi.org/10.21605/cukurovaummfd.500594

Öz

The performance of a lithium-ion cell depends on the form of the solid−electrolyte interphase (SEI) layers which is composed on the electrode surface. Here, we present a components of the electrolyte solutions for LIBs, namely, fluoroethylene carbonate (FEC) and vinyl carbonate (VC). We discuss the effect of 2, 5 and 10% FEC and VC-based electrolyte solutions in LiPF6 in EC:DEC to understand the SEI layer formed on Si anode. 

Kaynakça

  • 1. http://www.emc2.cornell.edu/content/view/ battery -anodes.html, Alıntı Tarihi: 05.04.2018
  • 2. Pistoia, G., 2014. Lithium-Ion Batteries Advances and Applications, Chapter 1, Elsevier.
  • 3. Schmidt, G., Cayrefourcq, I., Paillet, S., Fréchette, J., Barray, F., Clément, D., Hovington, P., Guerfi, A., Zaghib, K., 2014. Evaluation of Litdi Vs. LiPF6 As Electrolytes in Contact with Several Cathodes and Anodes Materials, ECS Meeting Abstract, Session 11- Electrolyte, Materials, and Batteries Posters.
  • 4. Kalhoff, J., Eshetu, G.G., Bresser, D., Passerini, S., 2015. Safer Electrolytes for Lithium-Ion Batteries: State of the Art and Perspectives, Chemsuschem Energy & Materials, Volume 8(13), 2154–2175.
  • 5. Hofmanna, A., Hanemann, T., 2015. Novel Electrolyte Mixtures Based on Dimethyl Sulfone, Ethylene Carbonate and LiPF6 for Lithium-ion Batteries, Journal of Power Sources, 298(1), 322–330.
  • 6. Pailleta, S., Schmidtb, G., Ladouceur, S., Fréchettea, J., Barraya, F., Clémenta, D., Hovingtona, P., Guerfi, A., Vijha, A., Cayrefourcq, I., Zaghib, K., 2015. Power Capability of LiTDI-based Electrolytes for Lithium-ion Batteries, Journal of Power Sources, 294, 507–515.
  • 7. Birrozzi, A., Maroni, F., Raccichini, R., Tossici, R., Marassi, R., Nobili, F., 2015. Enhanced Stability of SnSb/graphene Anode Through Alternative Binder and Electrolyte Additive for Lithium Ion Batteries Application, Journal of Power Sources, 294, 248-253.
  • 8. McMillan, R., Slegr, H., Shu, Z. X., Wang, W., 1999. Fluoroethylene Carbonate Electrolyte and its use in Lithium Ion Batteries with Graphite Anodes, J. Power Sources, 81, 20-26.
  • 9. Tan, S., Ji, Y.J., Zhang, Z. R., Yang, Y., 2014. Recent Progress in Research on High-voltage Electrolytes for Lithium-ion Batteries. Chem Phys Chem 15(10), 1956-69.
  • 10. Arai, J., Katayama, H., Akahoshi, H., 2002. Binary Mixed Solvent Electrolytes Containing Trifluoropropylene Carbonate for Lithium Secondary Batteries, J. Electrochem. Society, 149(2), A217-A226.
  • 11. Benmayza, A., Lu, W., Ramani, V., Prakash, J., 2014. Electrochemical and Thermal Studies of LiNi0.8Co0.15Al0.015O2 under Fluorinated Electrolytes, Electrochim. Acta, 123, 7-13.
  • 12. Mcller, K.-C., Hodal, T., Appel, W. K., Winter, M., Besenhard, J.O., 2001. Fluorinated Organic Solvents in Electrolytes for Lithium Ion Cells J. Power Sources, 97–98, 595-597.
  • 13. O’Hagan, D., 2008. Understanding Organofluorine Chemistry. An Introduction to the C–F Bond, Chem. Soc. Rev., 37, 308-319 . 14. Eshetu, G. G., Grugeon, S., Gachot, G., Mathiron, D., Armand, M., Laruelle, S., 2013. LiFSI vs. LiPF6 Electrolytes in Contact with Lithiated Graphite: Comparing Thermal Stabilities and Identification of Specific SEIReinforcing Additives, Electrochimica Acta, 102, 133-141.
  • 15. Zhang, S.S., 2006. A Review on Electrolyte Additives for Lithium-ion Batteries, Journal of Power Sources, 162 (2), 1379-1394.
  • 16. Profatilova, I., Stock, C., Schmitz, A., Passerini, S., Winter, M., 2013. Enhanced Thermal Stability of a Lithiated Nano-silicon Electrode by Fluoroethylene Carbonate and Vinylene Carbonate J. Power Sources, 222, 140-149.
  • 17. Lee, H.H., Wang, Y.Y., Wan, C.C., Yang, M.- H., Wu, H.C., Shieh, D.T., 2005. The Function of Vinylene Carbonate as a Thermal Additive to Electrolyte in Lithium Batteries, Journal of Applied Electrochemistry, 35, 615-623.
  • 18. Xu, S.D., Zhuang, Q.C., Wang, J., Xu, Y.Q., Zhu, Y.B., 2013. New Insight into Vinylethylene Carbonate as a Film Forming Additive to Ethylene Carbonate-Based Electrolytes for LithiumIon Batteries, International Journal of Electrochemical Science, 8, 8058-8076.
  • 19. Yao, W., Zhang, Z., Gao, J., Li, J., Xu, J., Wang, Z., Yang, Y., 2009. Vinyl Ethylene Sulfite as a New Additive in Propylene Carbonate-based Electrolyte for Lithium Ion Batteries, Energy&Environmental Science, 2, 1102-1108
  • 20. Liu, B., Li, B., Guan, S., 2012. Effect of Fluoroethylene Carbonate Additive on Low Temperature Performance of Li-Ion Batteries, Electrochemical abd Solid-State Letters, 15, A77-A79.
  • 21. Liu, G., Xun, S., Vukmirovic, N., Song, X., Olalde-Velasco, P., Zheng, H., Battaglia, V.S., Wang, L., Yang, W. 2011. Polymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes. Adv. Mater. 23, 4679−4683.

FEC ve VC Katkılı Elektrolitin Lityum İyon Hücrelerde Si Anot Üzerine Etkisi

Yıl 2018, Cilt: 33 Sayı: 3, 113 - 120, 30.09.2018
https://doi.org/10.21605/cukurovaummfd.500594

Öz

Lityum iyon hücrelerin performansı, elektrot yüzeyinde oluşan Katı Elektrolit Arayüzey (KEY)’in yapısına bağlıdır. Bu çalışmada, elektrolit çözeltisinin bileşeni olarak FEC (floroetilen karbonat) ve VC (vinil karbonat)kullandık. %2, %5 ve %10 FEC ve VC katkılandırılmış EC:DEC içinde LiPF6 elektolitinin Si anot üzerinde oluşan KEY tabakasına etkileri tartışılmıştır.

Kaynakça

  • 1. http://www.emc2.cornell.edu/content/view/ battery -anodes.html, Alıntı Tarihi: 05.04.2018
  • 2. Pistoia, G., 2014. Lithium-Ion Batteries Advances and Applications, Chapter 1, Elsevier.
  • 3. Schmidt, G., Cayrefourcq, I., Paillet, S., Fréchette, J., Barray, F., Clément, D., Hovington, P., Guerfi, A., Zaghib, K., 2014. Evaluation of Litdi Vs. LiPF6 As Electrolytes in Contact with Several Cathodes and Anodes Materials, ECS Meeting Abstract, Session 11- Electrolyte, Materials, and Batteries Posters.
  • 4. Kalhoff, J., Eshetu, G.G., Bresser, D., Passerini, S., 2015. Safer Electrolytes for Lithium-Ion Batteries: State of the Art and Perspectives, Chemsuschem Energy & Materials, Volume 8(13), 2154–2175.
  • 5. Hofmanna, A., Hanemann, T., 2015. Novel Electrolyte Mixtures Based on Dimethyl Sulfone, Ethylene Carbonate and LiPF6 for Lithium-ion Batteries, Journal of Power Sources, 298(1), 322–330.
  • 6. Pailleta, S., Schmidtb, G., Ladouceur, S., Fréchettea, J., Barraya, F., Clémenta, D., Hovingtona, P., Guerfi, A., Vijha, A., Cayrefourcq, I., Zaghib, K., 2015. Power Capability of LiTDI-based Electrolytes for Lithium-ion Batteries, Journal of Power Sources, 294, 507–515.
  • 7. Birrozzi, A., Maroni, F., Raccichini, R., Tossici, R., Marassi, R., Nobili, F., 2015. Enhanced Stability of SnSb/graphene Anode Through Alternative Binder and Electrolyte Additive for Lithium Ion Batteries Application, Journal of Power Sources, 294, 248-253.
  • 8. McMillan, R., Slegr, H., Shu, Z. X., Wang, W., 1999. Fluoroethylene Carbonate Electrolyte and its use in Lithium Ion Batteries with Graphite Anodes, J. Power Sources, 81, 20-26.
  • 9. Tan, S., Ji, Y.J., Zhang, Z. R., Yang, Y., 2014. Recent Progress in Research on High-voltage Electrolytes for Lithium-ion Batteries. Chem Phys Chem 15(10), 1956-69.
  • 10. Arai, J., Katayama, H., Akahoshi, H., 2002. Binary Mixed Solvent Electrolytes Containing Trifluoropropylene Carbonate for Lithium Secondary Batteries, J. Electrochem. Society, 149(2), A217-A226.
  • 11. Benmayza, A., Lu, W., Ramani, V., Prakash, J., 2014. Electrochemical and Thermal Studies of LiNi0.8Co0.15Al0.015O2 under Fluorinated Electrolytes, Electrochim. Acta, 123, 7-13.
  • 12. Mcller, K.-C., Hodal, T., Appel, W. K., Winter, M., Besenhard, J.O., 2001. Fluorinated Organic Solvents in Electrolytes for Lithium Ion Cells J. Power Sources, 97–98, 595-597.
  • 13. O’Hagan, D., 2008. Understanding Organofluorine Chemistry. An Introduction to the C–F Bond, Chem. Soc. Rev., 37, 308-319 . 14. Eshetu, G. G., Grugeon, S., Gachot, G., Mathiron, D., Armand, M., Laruelle, S., 2013. LiFSI vs. LiPF6 Electrolytes in Contact with Lithiated Graphite: Comparing Thermal Stabilities and Identification of Specific SEIReinforcing Additives, Electrochimica Acta, 102, 133-141.
  • 15. Zhang, S.S., 2006. A Review on Electrolyte Additives for Lithium-ion Batteries, Journal of Power Sources, 162 (2), 1379-1394.
  • 16. Profatilova, I., Stock, C., Schmitz, A., Passerini, S., Winter, M., 2013. Enhanced Thermal Stability of a Lithiated Nano-silicon Electrode by Fluoroethylene Carbonate and Vinylene Carbonate J. Power Sources, 222, 140-149.
  • 17. Lee, H.H., Wang, Y.Y., Wan, C.C., Yang, M.- H., Wu, H.C., Shieh, D.T., 2005. The Function of Vinylene Carbonate as a Thermal Additive to Electrolyte in Lithium Batteries, Journal of Applied Electrochemistry, 35, 615-623.
  • 18. Xu, S.D., Zhuang, Q.C., Wang, J., Xu, Y.Q., Zhu, Y.B., 2013. New Insight into Vinylethylene Carbonate as a Film Forming Additive to Ethylene Carbonate-Based Electrolytes for LithiumIon Batteries, International Journal of Electrochemical Science, 8, 8058-8076.
  • 19. Yao, W., Zhang, Z., Gao, J., Li, J., Xu, J., Wang, Z., Yang, Y., 2009. Vinyl Ethylene Sulfite as a New Additive in Propylene Carbonate-based Electrolyte for Lithium Ion Batteries, Energy&Environmental Science, 2, 1102-1108
  • 20. Liu, B., Li, B., Guan, S., 2012. Effect of Fluoroethylene Carbonate Additive on Low Temperature Performance of Li-Ion Batteries, Electrochemical abd Solid-State Letters, 15, A77-A79.
  • 21. Liu, G., Xun, S., Vukmirovic, N., Song, X., Olalde-Velasco, P., Zheng, H., Battaglia, V.S., Wang, L., Yang, W. 2011. Polymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes. Adv. Mater. 23, 4679−4683.
Toplam 20 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mimarlık, Mühendislik
Bölüm Makaleler
Yazarlar

Neslihan Yuca Bu kişi benim

Yayımlanma Tarihi 30 Eylül 2018
Yayımlandığı Sayı Yıl 2018 Cilt: 33 Sayı: 3

Kaynak Göster

APA Yuca, N. (2018). Effect of FEC and VC Additives in Electrolyte on the Performance of Si Anode for Lithium Ion Cell. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, 33(3), 113-120. https://doi.org/10.21605/cukurovaummfd.500594
AMA Yuca N. Effect of FEC and VC Additives in Electrolyte on the Performance of Si Anode for Lithium Ion Cell. cukurovaummfd. Eylül 2018;33(3):113-120. doi:10.21605/cukurovaummfd.500594
Chicago Yuca, Neslihan. “Effect of FEC and VC Additives in Electrolyte on the Performance of Si Anode for Lithium Ion Cell”. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi 33, sy. 3 (Eylül 2018): 113-20. https://doi.org/10.21605/cukurovaummfd.500594.
EndNote Yuca N (01 Eylül 2018) Effect of FEC and VC Additives in Electrolyte on the Performance of Si Anode for Lithium Ion Cell. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi 33 3 113–120.
IEEE N. Yuca, “Effect of FEC and VC Additives in Electrolyte on the Performance of Si Anode for Lithium Ion Cell”, cukurovaummfd, c. 33, sy. 3, ss. 113–120, 2018, doi: 10.21605/cukurovaummfd.500594.
ISNAD Yuca, Neslihan. “Effect of FEC and VC Additives in Electrolyte on the Performance of Si Anode for Lithium Ion Cell”. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi 33/3 (Eylül 2018), 113-120. https://doi.org/10.21605/cukurovaummfd.500594.
JAMA Yuca N. Effect of FEC and VC Additives in Electrolyte on the Performance of Si Anode for Lithium Ion Cell. cukurovaummfd. 2018;33:113–120.
MLA Yuca, Neslihan. “Effect of FEC and VC Additives in Electrolyte on the Performance of Si Anode for Lithium Ion Cell”. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, c. 33, sy. 3, 2018, ss. 113-20, doi:10.21605/cukurovaummfd.500594.
Vancouver Yuca N. Effect of FEC and VC Additives in Electrolyte on the Performance of Si Anode for Lithium Ion Cell. cukurovaummfd. 2018;33(3):113-20.