Fabrication and Characterization of γ-Fe2O3 Doped Three Dimensional Graphene Foam

Öz

Recently, three-dimensional graphene foams produced by CVD method have drawn significant attention due to their unique properties in many applications. In particular, their regularly interconnected structures provide a suitable platform for accommodating metal oxides, polymers etc. Therefore, these materials emerge as promising candidates for electrochemical applications. In this study, hydrothermal method of doping iron oxide nanoparticles on three-dimensional graphene foam was demonstrated for the first time. After doping the saturation magnetization value (Ms) of graphene foam was measured as 49,8 emu/g while the interconnected network structure of graphene foam was preserved. These results show that it is possible to use these materials for electrochemical applications.

Anahtar Kelimeler

• Three-dimensional graphene foam,γ-Fe2O3,CVD,Hydrothermal method

γ-Fe2O3 Nanoparçacık Katkılı Üç Boyutlu Grafen Köpüklerin Üretimi ve Karakterizasyonu

Öz

Kimyasal buhar biriktirme yöntemi ile üretilen üç boyutlu grafen köpükler, eşsiz özelliklerinden dolayı, son yıllarda pek çok alanda giderek dikkat çekmeye başlamışlardır. Özellikle; metal oksit, polimer gibi malzemelerle kaplanmaya uygun olan düzenli ağ yapılarıyla elektrokimyasal uygulamalar için de aday malzemeler haline gelmişlerdir.  Bu çalışmada, kimyasal buhar biriktirme yöntemi ile üretilen üç boyutlu grafen köpüklere ilk kez hidrotermal yöntem kullanılarak γ-Fe₂O₃ nanoparçacıkları katkılanmıştır. Katkılama işlemi sonucunda köpüklere ait doyum manyetizasyon değeri (Ms) 49,8 emu/g olarak ölçülmüş, grafen köpüğün ağ yapısının katkılama işlemi sonucunda da korunduğu görülmüştür. Elde edilen bu sonuçlar γ-Fe₂O₃ katkılı grafen köpüklerin elektrokimyasal uygulamalar için kullanılabileceği sonucunu ortaya çıkarmıştır.

Anahtar Kelimeler

• Üç boyutlu grafen köpük,γ-Fe2O3,CVD,Hidrotermal yöntem

Kaynakça

1. [1] Novaselov, K.S., Jiang, D., Schedin, F., Booth T.J., Khotkevich,V.V., Morozov, S.V., Geim, A.K. 2005. Two dimensional atomic crystals, PNAS, Cilt. 102, s. 10451-10453. DOI: 10.1073/pnas.0502848102.
2. [2] Allen, M.J., Tung, V.C., Kaner, R.B. 2010. Honeycomb Carbon: A Review of Graphene, Chem. Rev., Cilt. 110, s. 132-135. DOI: 10.1021/cr900070d.
3. [3] Gomez, De Arco L., Zhang ,Y., Schlenker, C.W., Ryu K., Thompson, M.E, Zhou, C. 2010. Continuous, highly flexible, and transparent graphene films by chemical vapor deposition for organic photovoltaics, ACS Nano, Cilt. 4, s. 2865–2873. DOI: 10.1021/nn901587x
4. [4] Kim, B.J., Jang, H., Lee, S.K., Hong, B.H., Ahn, J.H., Cho, J.H. 2010. High-performance flexible graphene field effect transistors with ion gel gate dielectrics, Nano letters Cilt. 10 (9), s.3464-3466. DOI: 10.1021/nl101559n
5. [5] Mattevi, C., Kim, H., Chhowalla, M. 2011. A Review of chemical vapor deposition of graphene on copper, Journal of Materials Chemistry, Cilt. 21, s. 3324-3334. DOI: 10.1039/C0JM02126A
6. [6] Miao, X., Tongay, S., Petterson, M.K., Berke, K., Rinzler, A.G., Appleton, B.R., Hebard A.F. 2012, High efficiency graphene solar cells by chemical doping, Nano Lett., Cilt.12, s.6–11. DOI: 10.1021/nl204414u
7. [7] Chen, Z., Ren,W., Gao, L., Li, B., Pei, S., Cheng, H.M. 2011. Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition, Nature Materials, Cilt. 10, s. 424–428. DOI:10.1038/nmat3001
8. [8] Fang, Q., Shen, Y., Chen, B. 2015. Synthesis, decoration and properties of three-dimensional graphene-based macrostructures: A review, Chemical Engineering Journal, Cilt. 264, s. 753-771. https://DOI.org/10.1016/j.cej.2014.12.001

9. [9] Li, C. ve Shi, G. 2012. Three-dimensional graphene architectures, Nanoscale, Cilt. 4, s. 5549. DOI: 10.1039/C2NR31467C
10. [10] Mao, S., Lu, G., Chen, J. 2015. Three-dimensional graphene-based composite for energy application, Nanoscale, Cilt. 7(16), s. 6924-6943. DOI:10.1039/c4nr06609j
11. [11] Zhang, L. ve Shi, G. 2011. Preparation of highly conductive graphene hydrogels for fabricating supercapacitors with high rate capability, Journal of Physical Chemistry C, Cilt. 115, s.17206-17212. DOI: 10.1021/jp204036a
12. [12] Zhang, X., Sui, Z., Xu, B., Yue, S., Luo, Y., Zhan, W., Liu, B. 2011. Mechanically strong and highly conductive graphene aerogel and its use as electrodes for electrochemical power sources, Journal of Materials Chemistry, Cilt. 21, s. 6494-6497. DOI:10.1039/C1JM10239G
13. [13] Yong, Y.C, Dong, Xi.C, Chan-Park, M. B., Song, H., Chen P. 2012. Macroporous and Monolithic Anode Based on Polyaniline Hybridized Three-Dimensional Graphene for High-Performance Microbial Fuel Cells, ACSNano, Cilt. 6(3), s. 2394–2400. DOI: 10.1021/nn204656d
14. [14] Cao, X., Shi, Y., Shi, W, Lu G. , Huang, X. , Yan, Q., Zhang, Q. , Hua, Z. 2011. Preparation of Novel 3D Graphene Networks for Supercapacitor Applications, Small, Cilt. 7(22), s. 3163–3168. DOI: 10.1002/smll.201100990
15. [15] Pettes, M. T., Ji, H., Ruoff, R.S., Shi ,L. 2012. Thermal Transport in Three-Dimensional Foam Architectures of Few- Layer Graphene and Ultrathin Graphite, Nano Lett., Cilt. 12, s. 2959−2964. DOI: 10.1021/nl300662q
16. [16] Lin, H., Xu, S., Wang ,X., Mei, N. 2013. Significantly reduced thermal diffusivity of free-standing two-layer graphene in graphene foam, Nanotechnology, Cilt. 24, s. 415706. DOI: 10.1088/0957-4484/24/41/415706
17. [17] Nguyen, D.D., Tai, N.H., Lee, S.B., Kuo,W.S. 2012. Superhydrophobic and superoleophilic properties of graphene-based sponges fabricated using a facile dip coating method, Energy Environ. Sci., Cilt. 5, s. 7908. DOI:10.1039/C2EE21848H
18. [18] Dong, X., Cao, Y., Wang, J., Chan-Park , M.B., Wang , L., Huang, W., Chen, P..2012. Hybrid structure of zinc oxide nanorods and three dimensional graphene foam for supercapacitor and electrochemical sensor applications, RSC Advances, Cilt. 2, s.4364–4369. DOI: 10.1039/C2RA01295B
19. [19] Xue, Y., Yu, D., Da,i L.,Wang, R., Li, D., Roy, A., Lu F., Chen, H., Liu, Y., Qu, J. 2013. Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction, Physical chemistry chemical physics, Cilt. 15, s. 12220-12226. DOI: 10.1039/C3CP51942B
20. [20] Yavari, F., Chen, Z., Thomas, A.V., Ren, W., Cheng, H.M., Karatkar, N. 2011. High Sensitivity Gas Detection Using a Macroscopic Three-Dimensional Graphene Foam Network, Scientific Reports, Cilt.1, s. 1-5. DOI: 10.1038/srep00166
21. [21] Lee, J.S., Ahn, H.J., Yoon, Y.C., Jang, J.H. 2012. Three-dimensional nano-foam of few-layer graphene grown by CVD for DSSC, Physical Chemistry Chemical Physics, Cilt. 14, s. 7938-7943. DOI: 10.1039/C2CP40810D
22. [22] Urbanova, V., Magro, M., Gedanken, A., Baratella, D., Vianello, F., Zboril, R. 2014. Nanocrystalline iron oxides, composites, and related materials as a platform for electrochemical, magnetic, and chemical biosensors. Chem. Mater. Cilt. 26, s. 6653−6673. DOI: 10.1021/cm500364x
23. [23] Gallo, J., Kamaly, N., Lavdas, I., Stevens, E., Nguyen, Q. D., Wylezinska-Arridge, M., Aboagye, E. O., Long, N. J. 2014. CXCR4−targeted and MMP−responsive iron oxide nanoparticles for enhanced magnetic resonance imaging. Angew. Chem., Int. Ed., Cilt.53. s. 9550-9554. DOI: 10.1002/anie.201405442
24. [24] Guo, Y., Wang, X., Sun, R. 2013. Cellulose-based self-assembled nanoparticles for antitumor drug delivery. J. Controlled Rd Release Cilt. 172, s. 17573-17581. DOI: 10.1021/acsami.5b05038.
25. [25] Laurent S., Forge D., Port M., Roch A., Robic C., Elst Vander E., Muller R.N. 2008. Magnetic iron nanoparticles: synthesis, stabilization, vectorization, physicochemical characterizations, and biological applications, Chem. Rev., Cilt. 108, s. 2064-2110. DOI: 10.1021/cr068445e.
26. [26] Shen-Nan S., Chao W., Zan-Zan Z., Yang-Long H., Venkatraman S.S., Zhi-Chuan X. 2014. Magnetic iron oxide nanoparticles: synthesis and surface coating techniques for biomedical applications, Chin. Phy. B., Cilt. 23, s.037503. DOI: 10.1088/16741056/23/3/037503
27. [27] Bang J.H., Suslick K.S. 2010. Application of ultrasound to the synthesis of nanostructures materials. 2010. Adv. Mater., Cilt. 22, s. 1039-1059. DOI: 10.1002/adma.200904093.
28. [28] Ferrari, A. C., 2007. Raman spectroscopy of graphene and graphite: Disorder, electron-phonon coupling, doping and nonadiabatic effects, Solid State Communications, Cilt.143(1-2), s. 47-57. https://DOI.org/10.1016/j.ssc.2007.03.052
29. [29] Ferrari, A. C., Meyer, J. C., Scardaci, V., Casiraghi, C., Lazzeri, M., Mauri, F., Piscanec, S., Jiang, D., Novoselov, K. S., Roth, S., and Geim, A. K., 2006. Raman Spectrum of Graphene and Graphene Layers, Physical Review Letters, Cilt. 97(18), s. 187401. DOI:10.1103/PhysRevLett.97.187401
30. [30] Ferrari, A. C., and Robertson, J., 2000. Interpretation of Raman spectra of disordered and amorphous carbon, Physical Review B, Cilt. 61(20), s. 14095. DOI: 10.1103/PhysRevB.61.14095.
31. [31] El Mendili Y., Bardeu J.F., Randrianantoandro N., Gourbil A., Greneche J.M., Mercier A.M., Grasset F.2015. Improvement of Thermal Stability of Maghemite Nanoparticles Coated with Oleic Acid and Oleylamine Molecules: Investigations under Laser Irradiation, The Journal of Physical Chemistry C, Cilt. 119, s. 10662-10668. DOI: 10.1021/acs.jpcc.5b00819
32. [32] Alexander, L., Klug, H.P. 1950. Determination of Crystallite Size with Xray Spectrometer, Journal of Applied Physics, Cilt. 21, s. 137-142. DOI: http://dx.DOI.org/10.1063/1.1699612
33. [33] Liu Z., Tu Z., L, Y., Yang F., Han S., Yang W., Zhang L., Wang G., Xu C., Gao J. 2012.Synthesis of three-dimensional graphene foam from petroleum asphalt by chemical vapor deposition, Mater. Lett., Cilt. 122, s. 285-288. https://DOI.org/10.1016/j.matlet.2014.02.077