PİRAZOL BAZLI DİSAZO BOYARMADDELERİN SENTEZİ, KARAKTERİZASYONU VE ABSORPSİYON ÖZELLİKLERİNİN İNCELENMESİ

Yıl 2017, Cilt: 19 Sayı: 55, 194 - 202, 01.01.2017

Çiğdem Karabacak Atay Merve Gökalp Tahir Tilki

https://doi.org/10.21205/deufmd.2017195515

Öz

Çalışmamızda, o-, m-, p-NO2 sübstitüe anilin türevleri diazolanmış ve etilsiyanoasetat ile kenetlenerek etil 2-siyano-2-(2-(nitrofenil) hidrazon)asetat bileşikleri elde edilmiştir. Elde edilen etil 2-siyano-2-(2(nitrofenil) hidrazon)asetat bileşikleri, hidrazinhidrat ile reaksiyona sokularak bir seri 5-amino-4-((nitrofenil) diazenil)-1H-pirazol-3-ol türevleri sentezlenmiştir. Sentezlenen 5-amino-4-((nitrofenil) diazenil)1H-pirazol-3-ol bileşiklerinin 3,5-dimetil-1H-pirazol ve 3,5-dimetil-1-fenil1H-pirazol bileşikleri ile kenetlenme reaksiyonu sonucunda ise sırasıyla 5((3,5-dimetil-1H-pirazol-4-il)diazenil)-4-((nitrofenil) diazenil)-1H-pirazol3-ol ve 5-((3,5-dimetil-1-fenil-1H-pirazol-4-il)diazenil)-4-((nitrofenil) diazenil)-1H-pirazol-3-ol disazo boyarmaddeleri elde edilmiştir. Elde edilen bu disazo boyarmaddeleri FT- IR (Fourier-Transform Infrared Spektroskopisi), Spektroskopisi) gibi spektral yöntemlerle karakterize edilmiş ve görünür bölge absorpsiyon spektrumları üzerine değişik çözücü etkisi incelenmiştir. Böylece hem diazo hem de kenetlenme bileşeni heterosiklik olan yeni disazo boyarmaddeler sentezlenerek daha batokromik renklerin elde edilmesi amaçlanmıştır

Anahtar Kelimeler

Disazo Boyar madde, Heterosi klik Bileşik, Pirazol

Synthesis, Characterization and Investigation of Absorption Propertiesof Pyrazole Based Disazo Dyes

Öz

diazotised and coupled with ethylcyanoacetate to give ethyl 2-cyano-2-(2- (nitrophenyl) hydrazono)acetate. Ethyl 2-cyano-2-(2-(nitrophenyl) hydrazono)acetate were then reacted with hydrazinehydrate to give 5- amino-4-(nitrophenyl) diazenyl)-1H-pyrazol-3-ol derivatives. As a result of the coupling reactions of synthesized 5-amino-4-(nitrophenyl) diazenyl)-1H-pyrazol-3-ol compounds with 3,5-dimethyl-1H-pyrazole and 3,5-dimethyl-1-phenyl-1H-pyrazole, respectively, 5-((3,5-dimethyl-1H- pyrazol-4-yl)diazenyl)-4-(nitrophenyl) diazenyl)-1H-pyrazol-3-ol and 5- ((3,5-dimethyl-1-phenyl-1H-pyrazol-4-yl) diazenyl)-1H-pyrazol-3-ol disazo dyes were obtained. The synthesized disazo dyes were characterized by spectral methods such as FT-IR and 1H- NMR. The effect of varying solvent, upon the absorption ability of dyes was

Anahtar Kelimeler

Abstract: In our study, o-, m-, p-NO2 sübstitüe aniline derivatives were

Kaynakça

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