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CR(VI) BIOSORPTION BY WASTE ACORN OF QUERCUS ITHABURENSIS IN FIXED BEDS

Yıl 2006, Cilt: 8 Sayı: 2, 31 - 45, 01.05.2006

Öz

In this paper, the biosorption of Cr(VI) ions onto waste acorn of Quercus ithaburensis, which was produced by valeks industries, was tested using fixed bed adsorption column. The experiments were carried out as a function of column height and Cr(VI) ion concentrations. The results of the biosorption studies indicated that an increase in Cr(VI) ion concentrations yielded increases in bed capacities and a decreases in the bed volumes (BV). Also an increase in column height resulted in increased breakthrough time, the bed volumes (BV) and bed capacities. The experimental data were analyzed to fitting to the Thomas model and the YoonNelson model

Kaynakça

  • Acar F.N., Malkoc E. (2004): “The Removal of Chromium(VI) from Aqueous Solutions by Fagus orientalis L.”, Bioresource Technology, Vol. 94, No.1, p. 13-15.
  • Aksu Z., Açıkel Ü., Kabasakal, E., Sezer S. (2002): “Equilibrium Modelling of Individual and Simultaneous Biosorption of Chromium(VI) and Nickel(II) onto Dried Activated Sludge”, Water Research, Vol. 36, p. 3063-3073.
  • Aksu Z., Gönen F. (2004): “Biosorption of Phenol by Immobilized Activated Sludge in a Continuous Packed Bed: Prediction of Breakthrough Curves”, Process Biochemistry, Vol. 39, p. 599-613.
  • Al-Asheh S., Abdel-Jabar N., Banat F. (2002): "Packed-Bed Sorption of Copper Using Spent Animal Bones: Factorial Experimental Design, Desorption and Column Regeneration”, Advances in Environmental Research, Vol. 6, p. 221-227.
  • Chandra Sekhar K., Subramanian S., Modak J.M., Natarajan K.A. (1998): “Removal of Metal Ions Using an Industrial Biomass with Reference to Environmental Control”, International Journal of Mineral Processing, Vol. 53, p. 107-120.
  • Chen J.P., Wang X. (2000): “Removing Copper, Zinc, and Lead Ion by Granular Activated Carbon in Pretreated Fixed Bed Columns”, Separation and Purification Technology, Vol. 19, p. 157-167.
  • Chu K.H. (2004): “Improved Fixed-Bed Models for Metal Biosorption”, Chemical Engineering Journal, Vol. 97, p. 233-239.
  • Ghorai S., Pant K.K. (2004): “Investigations on the Column Performance of Fluoride Adsorption by Activated Alumina in a Fixed-Bed”, Chemical Engineering Journal, Vol. 98, No. 1-2, p. 165-173.
  • Gupta V.K., Jain C.K., Ali I., Sharma M., Saini V.K. (2003): “Removal of Cadmium and Nickel from Wastewater Using Bagasse Fly Ash–a Sugar Industry Waste”, Water Research, Vol. 37, No. 16, p. 4038-4044.
  • Hasar H. (2003): Adsorption of Nickel(II) from Aqueous Solution onto Activated Carbon Prepared from Almond Husk”, Journal of Hazardous Materials, Vol. 97, p. 49-57.
  • İleri R., 2000, “Çevre Biyoreknolojisi”, Değişim Yayınları, Adapazarı.
  • Kaewsarn P. (2002): “Biosorption of Copper(II) from Aqueous Solutions By Pre-terated Biomass of Marine Algae Padina sp.”, Chemosphore, Vol. 47, p. 1081-1085.
  • Kahvecioğlu Ö., Kartal G., Güven A., Timur S. (2002): “Metallerin Çevresel Etkileri-I”, Metalurji ve Malzeme Müh.Bölümü, İTÜ, İstanbul.
  • Kapoor A., Viraraghavan T. (1998): “Removal of Heavy Metals from Aqueous Solutions Using Immobilized Fungal Biomass in Continuous Mode”, Water Res., Vol. 32, No. 6, p. 1968-1977.
  • Karpuzcu M. (1984): “Çevre Mühendisliğine Giriş”, İTÜ İnşaat Fakültesi Matbaası, İstanbul.
  • Kratochvil D., Volesky B. (1998): “Advances in the Biosorption of Heavy Metals”, Trends in Biotechnology, Vol.16, p. 291-300.
  • Ko D.C.K., Porter J.F., McKay G. (2000): “Optimised Correlations for the Fixed-Bed Adsorption of Metal Ions on Bone Char”, Chemical Engineering Science, Vol. 55, p. 5819-5829.
  • Ko D.C.K., Lee V.K.C., Porter J.F., McKay G. (2002): “Improved Design and Optimization Models for the Fixed Bed Adsorption of Acid Dye and Zinc Ions from Effluents”, J. Chem. Technol. Biotechnol., Vol. 77, p. 1289-1295.
  • Lehmann M., Zouboulis A.I., Matis K.A. (2001): “Modelling the Sorption of Metals from Aqueous Solutions on Goethite Fixed-Beds”, Env. Pol., Vol. 113, p. 121-128.
  • Malkoç E., Nuhoğlu Y., Abalı Y. (2006): “Cr(VI) Adsorption by Waste Acorn of Quercus ithaburensis in Fixed Beds: Prediction of Breakthrough Curves”, Chemical Eng. Journal, Vol. 119, p. 61-68.
  • McKay G., Bino M.J. (1990): “Simplified Optimization Procedure for Fixed Bed Adsorption Systems”, Water Air Soil Pollution, Vol. 51, p. 33-41.
  • McKay G., Porter J.F., Prasad G.R. (1999): “The Removal of Dye Colours from Aqueous Solutions by Adsorption on Low-Cost Materials”, Water Air and Soil Pollution, Vol.114, p. 423-438.
  • Paul Chen J., Yoon, J.T., Yiacoumi S. (2003): “Effects of Chemical and Physical Properties of Influent on Copper Sorption onto Activated Carbon Fixed–Bed Columns”, Vol. 41, p. 1635-1644.
  • Patterson J.W. (1985): “Industrial Wastewater Treatment Technology”, Butteworth Publishers, P. 466 (2 nd).
  • Perrich J.R. (1981): “Activated Carbon for Wastewater Treatment”, Boca Raton: CRC Press.
  • Rao M., Parwate A.V., Bhole A.G. (2002): “Removal of Cr6+ and Ni2+ from Aqueous Solution Using Bagasse and Fly Ash”, Waste Management, Vol. 22, p. 821-830.
  • Rich G., Cherry K. (1987): “Hazardous Waste Treatment Technologies”, Pudvan Publ. Co., Newyork.
  • Sağ Y. (1993): “Atıksulardaki Ağır Metal İyonlarının Giderilmesi ve Geri Kazanılması İçin En Uygun Biyosorbent Türünün Seçilmesi ve Değişik Reaktör Sistemlerinin Matematiksel İncelenmesi”, Doktora Tezi, Hacettepe Üniversitesi Fen Bilimleri Enstitüsü Kimya Mühendisliği Anabilim Dalı, p. 28.
  • Sarin V., Pant K.K. (2006): “Removal of Chromium from Industrial Waste by Using Eucalyptus bark”, Bioresource Technology, Vol. 97, No. 1, p. 15-20.
  • Tranter T.J., Herbst R.S., Todd T.A., Olson A.L., Eldredge H.B. (2003): “Application of a Second Order Kinetic Model for The Preliminary Design of an Adsorption Bed System Using Ammonium Molybdophosphate-Polyacrylonitrile for The Removal of 137Cs from Acidic Nuclear Waste Solutions”, Advances in Environmental Research, Vol. 7, p. 913- 923.
  • Tsai W.T., Chang C.Y., Ho C.Y., Chen L.Y. (1999): “Adsorption Properties and Breakthrough Model of 1,1-Dichloro-1-Fluoroethane on Activated Carbons”, Journal of Hazardous Materials, Vol. 69, p. 53-66.
  • Türkman A., Aslan Ş., Ege İ. (2001): “Doğal Zeolitlerle Atıksulardan Kurşun Giderimi (Lead Removal from Wastewaters by Natural Zeolıtes)”, DEÜ Mühendislik Fakültesi Fen ve Mühendislik Dergisi, Vol. 3, No. 2, p. 13-19.
  • Veglio F., Esposito A., Reverberi A.P. (2002): “Copper Adsorption on Calcium Alginate Beads: Equilibrium pH-Related Models”, Hydrometallurgy, Vol. 65, p. 43-57.
  • Volesky B. (1990): “Biosorption of Heavy Metals”, CRC Pres, Boca Raton, 396, Florida.
  • Volesky B., Prasetyo I. (1994): “Cadmium Removal in a Biosorption Column”, Biotechnol. Bioeng., Vol. 43, p. 1010-1015.
  • Yan G., Viraraghavan T. (2001): “Heavy Metal Removal in a Biosorption Column by Immobilized M. Rouxii Biomass”, Bioresource Technology, Vol. 78, p. 243-249.
  • Yu L.J., Shukla S.S., Dorris K.L., Shukla A., Margrave J.L .(2003): “Adsorption of Chromium from Aqueous Solutions by Maple Sawdust”, Journal of Hazardous Materials, Vol. 100, p. 53-63.
  • Zulfadhly Z., Mashitah M.D., Bhatia S. (2001): “Heavy Metals Removal in Fixed-Bed Column by the Macro Fungus Pycnoporus sanguineus”, Environmental Pollution, Vol. 112, p. 463-470.

PALAMUT MEŞESİ (Quercus ithaburensis) ATIĞI İLE SABİT YATAKLI KOLONDA Cr(VI) BİYOSORPSİYONU

Yıl 2006, Cilt: 8 Sayı: 2, 31 - 45, 01.05.2006

Öz

Bu çalışmada, deri sepileme maddesi üreten bir fabrikanın atığı olarak ortaya çıkan palamut meşesi (Quercus ithaburensis) atığı ile Cr(VI) iyonunun giderimi sabit yataklı adsorpsiyon kolonunda incelenmiştir. Cr(VI) biyosorpsiyonuna kolon yüksekliği ve Cr(VI) konsantrasyonunun etkisi araştırılmış; palamut meşesi atığı ile Cr6+ iyonunun gideriminde, besleme çözeltisindeki metal konsantrasyonunun artması ile yatak kapasitesinin arttığı, kullanılan yatak hacmi sayısı(BV)’nın azaldığı görülmüştür. Aynı zamanda, kolon yüksekliğinin artmasıyla kırılma zamanı, kullanılan yatak hacmi sayısı(BV) ve yatak kapasitesinin de arttığı gözlenmiştir. Elde edilen deneysel verilerin Thomas ve Yoon-Nelson modeline uygunluğu araştırılmıştır.

Kaynakça

  • Acar F.N., Malkoc E. (2004): “The Removal of Chromium(VI) from Aqueous Solutions by Fagus orientalis L.”, Bioresource Technology, Vol. 94, No.1, p. 13-15.
  • Aksu Z., Açıkel Ü., Kabasakal, E., Sezer S. (2002): “Equilibrium Modelling of Individual and Simultaneous Biosorption of Chromium(VI) and Nickel(II) onto Dried Activated Sludge”, Water Research, Vol. 36, p. 3063-3073.
  • Aksu Z., Gönen F. (2004): “Biosorption of Phenol by Immobilized Activated Sludge in a Continuous Packed Bed: Prediction of Breakthrough Curves”, Process Biochemistry, Vol. 39, p. 599-613.
  • Al-Asheh S., Abdel-Jabar N., Banat F. (2002): "Packed-Bed Sorption of Copper Using Spent Animal Bones: Factorial Experimental Design, Desorption and Column Regeneration”, Advances in Environmental Research, Vol. 6, p. 221-227.
  • Chandra Sekhar K., Subramanian S., Modak J.M., Natarajan K.A. (1998): “Removal of Metal Ions Using an Industrial Biomass with Reference to Environmental Control”, International Journal of Mineral Processing, Vol. 53, p. 107-120.
  • Chen J.P., Wang X. (2000): “Removing Copper, Zinc, and Lead Ion by Granular Activated Carbon in Pretreated Fixed Bed Columns”, Separation and Purification Technology, Vol. 19, p. 157-167.
  • Chu K.H. (2004): “Improved Fixed-Bed Models for Metal Biosorption”, Chemical Engineering Journal, Vol. 97, p. 233-239.
  • Ghorai S., Pant K.K. (2004): “Investigations on the Column Performance of Fluoride Adsorption by Activated Alumina in a Fixed-Bed”, Chemical Engineering Journal, Vol. 98, No. 1-2, p. 165-173.
  • Gupta V.K., Jain C.K., Ali I., Sharma M., Saini V.K. (2003): “Removal of Cadmium and Nickel from Wastewater Using Bagasse Fly Ash–a Sugar Industry Waste”, Water Research, Vol. 37, No. 16, p. 4038-4044.
  • Hasar H. (2003): Adsorption of Nickel(II) from Aqueous Solution onto Activated Carbon Prepared from Almond Husk”, Journal of Hazardous Materials, Vol. 97, p. 49-57.
  • İleri R., 2000, “Çevre Biyoreknolojisi”, Değişim Yayınları, Adapazarı.
  • Kaewsarn P. (2002): “Biosorption of Copper(II) from Aqueous Solutions By Pre-terated Biomass of Marine Algae Padina sp.”, Chemosphore, Vol. 47, p. 1081-1085.
  • Kahvecioğlu Ö., Kartal G., Güven A., Timur S. (2002): “Metallerin Çevresel Etkileri-I”, Metalurji ve Malzeme Müh.Bölümü, İTÜ, İstanbul.
  • Kapoor A., Viraraghavan T. (1998): “Removal of Heavy Metals from Aqueous Solutions Using Immobilized Fungal Biomass in Continuous Mode”, Water Res., Vol. 32, No. 6, p. 1968-1977.
  • Karpuzcu M. (1984): “Çevre Mühendisliğine Giriş”, İTÜ İnşaat Fakültesi Matbaası, İstanbul.
  • Kratochvil D., Volesky B. (1998): “Advances in the Biosorption of Heavy Metals”, Trends in Biotechnology, Vol.16, p. 291-300.
  • Ko D.C.K., Porter J.F., McKay G. (2000): “Optimised Correlations for the Fixed-Bed Adsorption of Metal Ions on Bone Char”, Chemical Engineering Science, Vol. 55, p. 5819-5829.
  • Ko D.C.K., Lee V.K.C., Porter J.F., McKay G. (2002): “Improved Design and Optimization Models for the Fixed Bed Adsorption of Acid Dye and Zinc Ions from Effluents”, J. Chem. Technol. Biotechnol., Vol. 77, p. 1289-1295.
  • Lehmann M., Zouboulis A.I., Matis K.A. (2001): “Modelling the Sorption of Metals from Aqueous Solutions on Goethite Fixed-Beds”, Env. Pol., Vol. 113, p. 121-128.
  • Malkoç E., Nuhoğlu Y., Abalı Y. (2006): “Cr(VI) Adsorption by Waste Acorn of Quercus ithaburensis in Fixed Beds: Prediction of Breakthrough Curves”, Chemical Eng. Journal, Vol. 119, p. 61-68.
  • McKay G., Bino M.J. (1990): “Simplified Optimization Procedure for Fixed Bed Adsorption Systems”, Water Air Soil Pollution, Vol. 51, p. 33-41.
  • McKay G., Porter J.F., Prasad G.R. (1999): “The Removal of Dye Colours from Aqueous Solutions by Adsorption on Low-Cost Materials”, Water Air and Soil Pollution, Vol.114, p. 423-438.
  • Paul Chen J., Yoon, J.T., Yiacoumi S. (2003): “Effects of Chemical and Physical Properties of Influent on Copper Sorption onto Activated Carbon Fixed–Bed Columns”, Vol. 41, p. 1635-1644.
  • Patterson J.W. (1985): “Industrial Wastewater Treatment Technology”, Butteworth Publishers, P. 466 (2 nd).
  • Perrich J.R. (1981): “Activated Carbon for Wastewater Treatment”, Boca Raton: CRC Press.
  • Rao M., Parwate A.V., Bhole A.G. (2002): “Removal of Cr6+ and Ni2+ from Aqueous Solution Using Bagasse and Fly Ash”, Waste Management, Vol. 22, p. 821-830.
  • Rich G., Cherry K. (1987): “Hazardous Waste Treatment Technologies”, Pudvan Publ. Co., Newyork.
  • Sağ Y. (1993): “Atıksulardaki Ağır Metal İyonlarının Giderilmesi ve Geri Kazanılması İçin En Uygun Biyosorbent Türünün Seçilmesi ve Değişik Reaktör Sistemlerinin Matematiksel İncelenmesi”, Doktora Tezi, Hacettepe Üniversitesi Fen Bilimleri Enstitüsü Kimya Mühendisliği Anabilim Dalı, p. 28.
  • Sarin V., Pant K.K. (2006): “Removal of Chromium from Industrial Waste by Using Eucalyptus bark”, Bioresource Technology, Vol. 97, No. 1, p. 15-20.
  • Tranter T.J., Herbst R.S., Todd T.A., Olson A.L., Eldredge H.B. (2003): “Application of a Second Order Kinetic Model for The Preliminary Design of an Adsorption Bed System Using Ammonium Molybdophosphate-Polyacrylonitrile for The Removal of 137Cs from Acidic Nuclear Waste Solutions”, Advances in Environmental Research, Vol. 7, p. 913- 923.
  • Tsai W.T., Chang C.Y., Ho C.Y., Chen L.Y. (1999): “Adsorption Properties and Breakthrough Model of 1,1-Dichloro-1-Fluoroethane on Activated Carbons”, Journal of Hazardous Materials, Vol. 69, p. 53-66.
  • Türkman A., Aslan Ş., Ege İ. (2001): “Doğal Zeolitlerle Atıksulardan Kurşun Giderimi (Lead Removal from Wastewaters by Natural Zeolıtes)”, DEÜ Mühendislik Fakültesi Fen ve Mühendislik Dergisi, Vol. 3, No. 2, p. 13-19.
  • Veglio F., Esposito A., Reverberi A.P. (2002): “Copper Adsorption on Calcium Alginate Beads: Equilibrium pH-Related Models”, Hydrometallurgy, Vol. 65, p. 43-57.
  • Volesky B. (1990): “Biosorption of Heavy Metals”, CRC Pres, Boca Raton, 396, Florida.
  • Volesky B., Prasetyo I. (1994): “Cadmium Removal in a Biosorption Column”, Biotechnol. Bioeng., Vol. 43, p. 1010-1015.
  • Yan G., Viraraghavan T. (2001): “Heavy Metal Removal in a Biosorption Column by Immobilized M. Rouxii Biomass”, Bioresource Technology, Vol. 78, p. 243-249.
  • Yu L.J., Shukla S.S., Dorris K.L., Shukla A., Margrave J.L .(2003): “Adsorption of Chromium from Aqueous Solutions by Maple Sawdust”, Journal of Hazardous Materials, Vol. 100, p. 53-63.
  • Zulfadhly Z., Mashitah M.D., Bhatia S. (2001): “Heavy Metals Removal in Fixed-Bed Column by the Macro Fungus Pycnoporus sanguineus”, Environmental Pollution, Vol. 112, p. 463-470.
Toplam 38 adet kaynakça vardır.

Ayrıntılar

Diğer ID JA86MU37VR
Bölüm Araştırma Makalesi
Yazarlar

Emine Malkoç Bu kişi benim

Yaşar Nuhoğlu Bu kişi benim

Yayımlanma Tarihi 1 Mayıs 2006
Yayımlandığı Sayı Yıl 2006 Cilt: 8 Sayı: 2

Kaynak Göster

APA Malkoç, E., & Nuhoğlu, Y. (2006). PALAMUT MEŞESİ (Quercus ithaburensis) ATIĞI İLE SABİT YATAKLI KOLONDA Cr(VI) BİYOSORPSİYONU. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen Ve Mühendislik Dergisi, 8(2), 31-45.
AMA Malkoç E, Nuhoğlu Y. PALAMUT MEŞESİ (Quercus ithaburensis) ATIĞI İLE SABİT YATAKLI KOLONDA Cr(VI) BİYOSORPSİYONU. DEUFMD. Mayıs 2006;8(2):31-45.
Chicago Malkoç, Emine, ve Yaşar Nuhoğlu. “PALAMUT MEŞESİ (Quercus Ithaburensis) ATIĞI İLE SABİT YATAKLI KOLONDA Cr(VI) BİYOSORPSİYONU”. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen Ve Mühendislik Dergisi 8, sy. 2 (Mayıs 2006): 31-45.
EndNote Malkoç E, Nuhoğlu Y (01 Mayıs 2006) PALAMUT MEŞESİ (Quercus ithaburensis) ATIĞI İLE SABİT YATAKLI KOLONDA Cr(VI) BİYOSORPSİYONU. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen ve Mühendislik Dergisi 8 2 31–45.
IEEE E. Malkoç ve Y. Nuhoğlu, “PALAMUT MEŞESİ (Quercus ithaburensis) ATIĞI İLE SABİT YATAKLI KOLONDA Cr(VI) BİYOSORPSİYONU”, DEUFMD, c. 8, sy. 2, ss. 31–45, 2006.
ISNAD Malkoç, Emine - Nuhoğlu, Yaşar. “PALAMUT MEŞESİ (Quercus Ithaburensis) ATIĞI İLE SABİT YATAKLI KOLONDA Cr(VI) BİYOSORPSİYONU”. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen ve Mühendislik Dergisi 8/2 (Mayıs 2006), 31-45.
JAMA Malkoç E, Nuhoğlu Y. PALAMUT MEŞESİ (Quercus ithaburensis) ATIĞI İLE SABİT YATAKLI KOLONDA Cr(VI) BİYOSORPSİYONU. DEUFMD. 2006;8:31–45.
MLA Malkoç, Emine ve Yaşar Nuhoğlu. “PALAMUT MEŞESİ (Quercus Ithaburensis) ATIĞI İLE SABİT YATAKLI KOLONDA Cr(VI) BİYOSORPSİYONU”. Dokuz Eylül Üniversitesi Mühendislik Fakültesi Fen Ve Mühendislik Dergisi, c. 8, sy. 2, 2006, ss. 31-45.
Vancouver Malkoç E, Nuhoğlu Y. PALAMUT MEŞESİ (Quercus ithaburensis) ATIĞI İLE SABİT YATAKLI KOLONDA Cr(VI) BİYOSORPSİYONU. DEUFMD. 2006;8(2):31-45.

Dokuz Eylül Üniversitesi, Mühendislik Fakültesi Dekanlığı Tınaztepe Yerleşkesi, Adatepe Mah. Doğuş Cad. No: 207-I / 35390 Buca-İZMİR.