Aktifleştirilmiş Zeolit ve Polivinilprolidon Kullanılarak Sulu Çözeltiden Metilen Mavisinin Giderilmesinde Adsorpsiyon Parametrelerinin Belirlenmesi

Filiz Kar; Melek Yılgın; Neslihan Duranay

doi:10.29130/dubited.472089

EN TR

Aktifleştirilmiş Zeolit ve Polivinilprolidon Kullanılarak Sulu Çözeltiden Metilen Mavisinin Giderilmesinde Adsorpsiyon Parametrelerinin Belirlenmesi

Abstract

Bu çalışmada, sulu çözeltilerden metilen mavisinin (MM) giderilmesi için adsorban olarak doğal zeolit (DZ) ve aktifleştirilmiş zeolit (AZ) ile polivinil prolidonun (PVP) kullanımı araştırılmıştır. Doğal zeolit; KOH, NaOH, HCI, saf su, H3P04 ve H3BO3 ile aktive edilmiştir. Saf su kullanılarak yıkanan ve 400 oC’de aktive edilen zeolitin kullanıldığı deneylerde en yüksek adsorpsiyon verimine ulaşılmıştır. Farklı sıcaklıklarda adsorpsiyon işleminin sonunda elde edilen denge verileri Langmuir, Freundlich, Temkin ve Harkins Jura modellerine uygulanmış ve model parametreleri hesaplanmıştır. Buna göre adsorpsiyonu en iyi temsil eden modelin Langmuir olduğu ve adsorpsiyon entalpisinin 12.70 kJ/mol olduğu tespit edilmiştir. PVP ile yapılan deneylerde de adsorpsiyonu en iyi temsil eden modelin Langmuir olduğu görülmüştür. Adsorbent olarak PVP’nin kullanıldığı adsorpsiyon işleminde adsorpsiyon entalpisi 14.32 kJ/mol olarak belirlenmiştir.

Keywords

Zeolit,Metilen Mavisi,Adsorpsiyon İzotermi,Termodinamik Parametreler

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Details

Primary Language

Turkish

Subjects

Engineering

Journal Section

Research Article

Authors

Filiz Kar ^*
0000-0002-4534-4064
Türkiye

Melek Yılgın
0000-0002-4177-8025
Türkiye

Neslihan Duranay
0000-0001-7259-1864
Türkiye

Publication Date

January 31, 2019

Submission Date

October 19, 2018

Acceptance Date

December 11, 2018

Published in Issue

Year 2019 Volume: 7 Number: 1

DOI

https://doi.org/10.29130/dubited.472089

IZ

https://izlik.org/JA26AJ24GA

APA

Kar, F., Yılgın, M., & Duranay, N. (2019). Aktifleştirilmiş Zeolit ve Polivinilprolidon Kullanılarak Sulu Çözeltiden Metilen Mavisinin Giderilmesinde Adsorpsiyon Parametrelerinin Belirlenmesi. Duzce University Journal of Science and Technology, 7(1), 1-14. https://doi.org/10.29130/dubited.472089

AMA

1.Kar F, Yılgın M, Duranay N. Aktifleştirilmiş Zeolit ve Polivinilprolidon Kullanılarak Sulu Çözeltiden Metilen Mavisinin Giderilmesinde Adsorpsiyon Parametrelerinin Belirlenmesi. DUBİTED. 2019;7(1):1-14. doi:10.29130/dubited.472089

Chicago

Kar, Filiz, Melek Yılgın, and Neslihan Duranay. 2019. “Aktifleştirilmiş Zeolit Ve Polivinilprolidon Kullanılarak Sulu Çözeltiden Metilen Mavisinin Giderilmesinde Adsorpsiyon Parametrelerinin Belirlenmesi”. Duzce University Journal of Science and Technology 7 (1): 1-14. https://doi.org/10.29130/dubited.472089.

EndNote

Kar F, Yılgın M, Duranay N (January 1, 2019) Aktifleştirilmiş Zeolit ve Polivinilprolidon Kullanılarak Sulu Çözeltiden Metilen Mavisinin Giderilmesinde Adsorpsiyon Parametrelerinin Belirlenmesi. Duzce University Journal of Science and Technology 7 1 1–14.

IEEE

[1]F. Kar, M. Yılgın, and N. Duranay, “Aktifleştirilmiş Zeolit ve Polivinilprolidon Kullanılarak Sulu Çözeltiden Metilen Mavisinin Giderilmesinde Adsorpsiyon Parametrelerinin Belirlenmesi”, DUBİTED, vol. 7, no. 1, pp. 1–14, Jan. 2019, doi: 10.29130/dubited.472089.

ISNAD

Kar, Filiz - Yılgın, Melek - Duranay, Neslihan. “Aktifleştirilmiş Zeolit Ve Polivinilprolidon Kullanılarak Sulu Çözeltiden Metilen Mavisinin Giderilmesinde Adsorpsiyon Parametrelerinin Belirlenmesi”. Duzce University Journal of Science and Technology 7/1 (January 1, 2019): 1-14. https://doi.org/10.29130/dubited.472089.

JAMA

1.Kar F, Yılgın M, Duranay N. Aktifleştirilmiş Zeolit ve Polivinilprolidon Kullanılarak Sulu Çözeltiden Metilen Mavisinin Giderilmesinde Adsorpsiyon Parametrelerinin Belirlenmesi. DUBİTED. 2019;7:1–14.

MLA

Kar, Filiz, et al. “Aktifleştirilmiş Zeolit Ve Polivinilprolidon Kullanılarak Sulu Çözeltiden Metilen Mavisinin Giderilmesinde Adsorpsiyon Parametrelerinin Belirlenmesi”. Duzce University Journal of Science and Technology, vol. 7, no. 1, Jan. 2019, pp. 1-14, doi:10.29130/dubited.472089.

Vancouver

1.Filiz Kar, Melek Yılgın, Neslihan Duranay. Aktifleştirilmiş Zeolit ve Polivinilprolidon Kullanılarak Sulu Çözeltiden Metilen Mavisinin Giderilmesinde Adsorpsiyon Parametrelerinin Belirlenmesi. DUBİTED. 2019 Jan. 1;7(1):1-14. doi:10.29130/dubited.472089