Elektro Eğirme Yöntemiyle ZnO Nanofiberlerin Üretilmesi ve Karakterizasyonu

Deniz Kadir Takcı

doi:10.29130/dubited.1158475

Araştırma Makalesi

Fabrication and Characterization of ZnO nanofibers by Electrospinning Technique

Yıl 2022, Cilt: 10 Sayı: 4, 2178 - 2185, 25.10.2022

Deniz Kadir Takcı

https://doi.org/10.29130/dubited.1158475

Öz

In this study, 1D ZnO nanofibers were synthesized from zinc acetate and polyvinyl alcohol (PVA) precursor solution using electrospinning technique, and then calcined in air environment at 400°C for 2 hours. Electron microscope analyzes (SEM) showed the rough surface of the nanofiber structures after annealing, and EDX analyzes demonstrated that the Zn:O atomic ratio was 1:1 and impurity. XRD characterization revealed the polycrystalline structure and the RAMAN spectrum indicated optical phonon modes. ZnO functional group analyzes were determined by FTIR.

Anahtar Kelimeler

Electrospinning technique, Nanofiber, PVA, ZnO

Kaynakça

[1] Y. Chang, N. Zhang, M. Zhuang, and X. Lu, “Characterization of electrospun zinc oxide nanofibers,” International Conference on Materials for Renewable Energy and Environment (IEEE), 2013, pp. 124-127.
[2] S. An, B. N. Joshi, M. W. Lee, N. Y. Kim, and S. S. Yoon, “Electrospun graphene-ZnO nanofiber mats for photocatalysis applications,” Applied surface science, vol. 294, pp. 24-28, 2014.
[3] S. Wu, J. Li, S. C. Lo, Q. Tai, and F. Yan, “Enhanced performance of hybrid solar cells based on ordered electrospun ZnO nanofibers modified with CdS on the surface,” Organic Electronics, vol. 13, no. 9, pp. 1569-1575, 2012.
[4] A. Gupta, D. V. Nandanwar, and S. R. Dhakate, “Electrospun self-assembled ZnO nanofibers structures for photocatalytic activity in natural solar radiations to degrade acid fuchsin dye,” Advanced Material Letters, vol. 6, no. 8, pp. 706-710, 2015.
[5] P. T. Patil, R. S. Anwane, and S. B. Kondawar, “Development of electrospun polyaniline/ZnO composite nanofibers for LPG sensing,” Procedia Materials Science, vol. 10, pp. 195-204, 2015.
[6] A. Di Mauro, M. Zimbone, M. E. Fragalà, and G. Impellizzeri, “Synthesis of ZnO nanofibers by the electrospinning process,” Materials Science in Semiconductor Processing, vol. 42, pp. 98-101, 2016.
[7] E. Ghafari, Y. Feng, Y. Liu, I. Ferguson, and N. Lu, “Investigating process-structure relations of ZnO nanofiber via electrospinning method,” Composites Part B: Engineering, vol. 116, pp. 40-45 2017.
[8] H. Wu, and W. Pan, “Preparation of zinc oxide nanofibers by electrospinning,” Journal of the American Ceramic Society, vol. 89, no. 2, pp. 699-701, 2006.
[9] T. Blachowicz, and A. Ehrmann, “Recent developments in electrospun ZnO nanofibers: A short review,” Journal of Engineered Fibers and Fabrics, vol. 15, pp. 1-6, 2020.
[10] J. Mu, C. Shao, Z. Guo, Z. Zhang, M. Zhang, P. Zhang, B. Chen, and Y. Liu, “High photocatalytic activity of ZnO− carbon nanofiber heteroarchitectures,” ACS applied materials & interfaces, vol. 3, no. 2, pp. 590-596, 2011.
[11] M. Chen, P. Liu, J. H. He, H. L. Wang, H. Zhang, X. Wang, and R. Chen, “Nanofiber template-induced preparation of ZnO nanocrystal and its application in photocatalysis,” Scientific reports, vol. 11, no. 1, pp. 1-8, 2021.
[12] F. Majid, M. Bashir, I. Bibi, A. Raza, S. Ezzine, N. Alwadai, and M. Iqbal, “ZnO nanofibers fabrication by hydrothermal route and effect of reaction time on dielectric, structural and optical properties,” Journal of Materials Research and Technology, vol. 18, pp. 4019-4029, 2022.
[13] N. Z. N. Azman, W. F. I. W. Mohamed, and R. M. Ramli, “Synthesis and characterization of electrospun n-ZnO/n-Bi2O3/epoxy-PVA nanofiber mat for low X-ray energy shielding application,” Radiation Physics and Chemistry, vol. 195, 110102, 2022.
[14] A. K. Das, M. Kar, and A. Srinivasan, “Room temperature ferromagnetism in undoped ZnO nanofibers prepared by electrospinning,” Physica B: Condensed Matter, vol, 448, pp. 112-114, 2014.
[15] H. A. Khorami, M. Keyanpour-Rad, and M. R. Vaezi, “Synthesis of SnO2/ZnO composite nanofibers by electrospinning method and study of its ethanol sensing properties,” Applied surface science, vol, 257, no. 18, pp. 7988-7992, 2011.
[16] S. Ata, A. Tabassum, I. Bibi, S. Ghafoor, A. Ahad, M. A. Bhatti, A. Islam, H. Rizvi, and M. Iqbal, “Synthesis and characterization of ZnO nanorods as an adsorbent for Cr (VI) sequestration,” Zeitschrift für Physikalische Chemie, vol. 233, no. 7, pp. 995-1017, 2019.
[17] J. A. Park, J. Moon, S. J. Lee, S. C. Lim, and T. Zyung, “Fabrication and characterization of ZnO nanofibers by electrospinning,” Current Applied Physics, vol. 9, no. 3, pp. S210-S212, 2009.
[18] M. Yalcin, “Microwave-assisted synthesis of ZnO nanoflakes: structural, optical and dielectric characterization,” Materials Research Express, vol. 7, no. 5, 055019, 2020.
[19] T. Ramezanpour, H. M. Chenari, and H. Kangarlou, “Fabrication of electrospun Mn1− xZnxMoO4 (x= 2.5%, 5%, and 10% Zn) nanofibers: Microstructure parameters, surface morphology and Kramers-Kronig (KK) analysis,” Ceramics International, vol. 44, no. 6, pp. 6791-6800, 2018.
[20] D. Gultekin, and H. Akbulut, “Raman studies of ZnO products synthesized by solution based methods,”Acta Physica Polinica A, vol. 129, pp. 803-805, 2016.
[21] P. Shankar, and J. B. B. Rayappan, “Room temperature ethanol sensing properties of ZnO nanorods prepared using an electrospinning technique,” Journal of Materials Chemistry C, vol. 5, no. 41, pp. 10869-10880, 2017.
[22] J. Yi, Y. Song, Z. Cao, C. Li, and C. Xiong, “Gram-scale Y-doped ZnO and PVDF electrospun film for piezoelectric nanogenerators,” Composites Science and Technology, vol. 215, 109011, 2021.