Removal of Reactive Red 141 and Disperse Red 13 Dyes from Aqueous Solutions Using Different Coagulants: An Optimization and Comparison Study

Yıl 2023, Cilt: 11 Sayı: 3, 1269 - 1281, 31.07.2023

Ahmed Albahnasawi

https://doi.org/10.29130/dubited.1183818

Cited By: 1

Öz

This study investigated the performance of different coagulants for the removal of different dye types from synthetic dye solutions. The ability to use each of the following: aluminium sulphate (Al2(SO4)3, aluminium chloride (AlCl3), and ferric chloride (FeCl3) as chemical coagulants were examined for removing reactive red 141 (RR 141) dye and disperse red 13 (DR 13) from dye solution. Coagulation studies determined the optimum pH, mixing time, coagulant dosages, and initial dye concentrations. The maximum efficiency for removing RR 141 was 65.7% by aluminium chloride at the operation condition of pH 8, mixing time 10 min, and dye concentration of 100 mg/L. In contrast, under the same conditions, ferric chloride could remove more than 98% of DR 13. Since the disperse dye type has better colour removal, the maximum volume of sludge was 0.3 kg/m3 which was produced when FeCl3 was used as a coagulant. The results demonstrated that coagulation is a promising technology for dye removal, especially for dispersed dyes as it has some characteristics such as colloidal dispersion and very low water solubility.

Anahtar Kelimeler

: Textile Wastewater, Chemical Coagulation, Reactive Dye, Disperse Dye.

Destekleyen Kurum

Yok.

Proje Numarası

Yok.

Teşekkür

The author would like to thank Eng. Ahmet Selçuk GÖVER for helping conductt the experiments.

Farklı Koagülanlar Kullanılarak Sulu Çözeltilerden Reaktif Kırmızı 141 ve Dispers Red 13 Boyalarının Giderimi: Bir Optimizasyon ve Karşılaştırma Çalışması

Öz

Bu çalışmada, farklı boya türlerinin sentetik boya çözeltilerinden gideriminde çeşitli koagülanların performansı araştırılmıştır. Boyarmadde olarak Reaktif kırmızı 141 (RR 141) ve dispers kırmızı 13 ( DR 13) seçilmiş, koagülan olarak da alüminyum sülfat, alüminyum klorür ve demir klorür kullanılmıştır. Boya gideriminde pH, karıştırma süresi, koagülan dozajı ve başlangıç boya konsantrasyonlarının etkisi incelenmiştir. RR141 boyasının maksimum giderim (%65.7) koşulları pH 8, 10 dakika karıştırma süresi ve 100 mg/l başlangıç boya konsantrasyonu altında alüminyum klorür ile elde edilirken, demir klorür ise aynı deney şartları altında DR 13 boyasını 98% oranında gidermiştir. Dispers boya tipinde daha iyi renk giderimi elde edildiğinden, olduğundan, demir klorür kullanıldığında açığa çıkan çamur miktarı da fazla olmuştur (~0.3 kg/m3). Elde edilen sonuçlar, koagülasyonun, kolloidal dispersiyon ve çok düşük suda çözünürlük gibi bazı özelliklere sahip olması nedeniyle, özellikle dispers boyalar için boya giderimi için umut verici bir teknoloji olduğunu göstermiştir.

Anahtar Kelimeler

Tekstil atıksuları, Kimyasal Koagülasyon, Reaktif Boya, Dispers Boya.

Proje Numarası

Yok.

Kaynakça

• [1] S. Vajnhandl and J. V. Valh, “The status of water reuse in European textile sector,” J. Environ. Manage., vol. 141, pp. 29–35, Aug. 2014.
• [2] B. Merzouk, B. Gourich, K. Madani, C. Vial, and A. Sekki, “Removal of a disperse red dye from synthetic wastewater by chemical coagulation and continuous electrocoagulation. A comparative study,” Desalination, vol. 272, no. 1–3, pp. 246–253, May 2011.
• [3] K. L. Yeap, T. T. Teng, B. T. Poh, N. Morad, and K. E. Lee, “Preparation and characterization of coagulation/flocculation behavior of a novel inorganic–organic hybrid polymer for reactive and disperse dyes removal,” Chem. Eng. J., vol. 243, pp. 305–314, May 2014.
• [4] D. Pathania, A. Sharma, and Z. M. Siddiqi, “Removal of congo red dye from aqueous system using Phoenix dactylifera seeds,” J. Mol. Liq., vol. 219, pp. 359–367, Jul. 2016.
• [5] B. Kakoi, J. W. Kaluli, P. Ndiba, and G. Thiong’o, “Optimization of Maerua Decumbent bio-coagulant in paint industry wastewater treatment with response surface methodology,” J. Clean. Prod., vol. 164, pp. 1124–1134, Oct. 2017.
• [6] A. Albahnasawi, E. Yüksel, M. Eyvaz, E. Gürbulak, E. Polat, and S. Arslan, “Performances of anoxic-aerobic membrane bioreactors for the treatment of real textile wastewater,” Glob. Nest J., vol. 22, no. 1, 2020.
• [7] V. Katheresan, J. Kansedo, and S. Y. Lau, “Efficiency of various recent wastewater dye removal methods: A review,” J. Environ. Chem. Eng., vol. 6, no. 4, pp. 4676–4697, 2018.
• [8] X. Florenza, A. M. S. Solano, F. Centellas, C. A. Martínez-Huitle, E. Brillas, and S. Garcia-Segura, “Degradation of the azo dye Acid Red 1 by anodic oxidation and indirect electrochemical processes based on Fenton’s reaction chemistry. Relationship between decolorization, mineralization and products,” Electrochim. Acta, vol. 142, pp. 276–288, Oct. 2014.
• [9] U. Morales, C. J. Escudero, M. J. Rivero, I. Ortiz, J. M. Rocha, and J. M. Peralta-Hernández, “Coupling of the electrochemical oxidation (EO-BDD)/photocatalysis (TiO2-Fe-N) processes for degradation of acid blue BR dye,” J. Electroanal. Chem., vol. 808, no. November 2017, pp. 180–188, 2018.
• [10] M. Santhanam, R. Selvaraj, V. Veerasubbian, and M. Sundaram, “Bacterial degradation of electrochemically oxidized textile effluent: Performance of oxic, anoxic and hybrid oxic-anoxic consortium,” Chem. Eng. J., vol. 355, no. August 2018, pp. 186–195, 2019.
• [11] A. Albahnasawi, E. Yüksel, E. Gürbulak, and F. Duyum, “Fate of aromatic amines through decolorization of real textile wastewater under anoxic-aerobic membrane bioreactor,” J. Environ. Chem. Eng., vol. 8, no. 5, p. 104226, 2020.
• [12] J. Korenak, J. Ploder, J. Trček, C. Hélix-Nielsen, and I. Petrinic, “Decolourisations and biodegradations of model azo dye solutions using a sequence batch reactor, followed by ultrafiltration,” Int. J. Environ. Sci. Technol., vol. 15, no. 3, pp. 483–492, 2018.
• [13] A. Albahnasawi et al., “Performance of aerobic sequential batch reactor in the treatment of textile wastewaters,” Int. J. Environ. Sci. Technol., pp. 1–10, Feb. 2022.
• [14] S. Khamparia and D. K. Jaspal, “Adsorption in combination with ozonation for the treatment of textile waste water: a critical review,” Front. Environ. Sci. Eng., vol. 11, no. 1, pp. 1–18, 2017.
• [15] Z. Maderova, E. Baldikova, K. Pospiskova, I. Safarik, and M. Safarikova, “Removal of dyes by adsorption on magnetically modified activated sludge,” Int. J. Environ. Sci. Technol., vol. 13, no. 7, pp. 1653–1664, 2016.
• [16] M. Choudhary, R. Kumar, and S. Neogi, “Activated biochar derived from Opuntia ficus-indica for the efficient adsorption of malachite green dye, Cu+2 and Ni+2 from water,” J. Hazard. Mater., vol. 392, no. February, p. 122441, 2020.
• [17] J. Dotto, M. R. Fagundes-Klen, M. T. Veit, S. M. Palácio, and R. Bergamasco, “Performance of different coagulants in the coagulation/flocculation process of textile wastewater,” J. Clean. Prod., vol. 208, pp. 656–665, 2019.
• [18] X. Huang et al., “Effects of compound bioflocculant on coagulation performance and floc properties for dye removal,” Bioresour. Technol., vol. 165, pp. 116–121, Aug. 2014.
• [19] A. M. T. Mata, A. Ligneul, N. D. Lourenço, and H. M. Pinheiro, “Advanced oxidation for aromatic amine mineralization after aerobic granular sludge treatment of an azo dye containing wastewater,” Desalin. Water Treat., vol. 91, pp. 168–174, 2017.
• [20] H. Zazou et al., “Treatment of textile industry wastewater by electrocoagulation coupled with electrochemical advanced oxidation process,” J. Water Process Eng., vol. 28, no. December 2018, pp. 214–221, 2019.
• [21] S. Ma, K. Kim, S. Chun, S. Y. Moon, and Y. Hong, “Plasma-assisted advanced oxidation process by a multi-hole dielectric barrier discharge in water and its application to wastewater treatment,” Chemosphere, vol. 243, p. 125377, 2020.
• [22] A. Gasmi et al., “Comparative Study of Chemical Coagulation and Electrocoagulation for the Treatment of Real Textile Wastewater: Optimization and Operating Cost Estimation,” ACS Omega, 2022.
• [23] X. Huang et al., “Effects of compound bioflocculant on coagulation performance and floc properties for dye removal,” Bioresour. Technol., vol. 165, no. C, pp. 116–121, Aug. 2014.
• [24] M. B. Bahrodin, N. S. Zaidi, N. Hussein, M. Sillanpää, D. D. Prasetyo, and A. Syafiuddin, “Recent Advances on Coagulation-Based Treatment of Wastewater: Transition from Chemical to Natural Coagulant,” Curr. Pollut. Reports, vol. 7, no. 3, pp. 379–391, 2021.
• [25] C. A. Igwegbe and O. D. Onukwuli, “Removal of Total Dissolved Solids (TDS) from Aquaculture Wastewater by Coagulation-flocculation Process using Sesamum indicum extract: Effect of Operating Parameters and Coagulation-Flocculation kinetics,” Pharm. Chem. J., vol. 6, no. 4, pp. 32–45, 2019.
• [26] M. I. Ejimofor, I. G. Ezemagu, and M. C. Menkiti, “Physiochemical, Instrumental and thermal characterization of the post coagulation sludge from paint industrial wastewater treatment,” South African J. Chem. Eng., vol. 37, no. May, pp. 150–160, 2021.
• [27] P. Ghorbannezhad, A. Bay, M. Yolmeh, R. Yadollahi, and J. Y. Moghadam, “Optimization of coagulation–flocculation process for medium density fiberboard (MDF) wastewater through response surface methodology,” Desalin. Water Treat., vol. 57, no. 56, pp. 26916–26931, 2016.
• [28] F. R. Furlan, L. G. de Melo da Silva, A. F. Morgado, A. A. U. de Souza, and S. M. A. Guelli Ulson de Souza, “Removal of reactive dyes from aqueous solutions using combined coagulation/flocculation and adsorption on activated carbon,” Resour. Conserv. Recycl., vol. 54, no. 5, pp. 283–290, Mar. 2010.
• [29] N. Wei, Z. Zhang, D. Liu, Y. Wu, J. Wang, and Q. Wang, “Coagulation behavior of polyaluminum chloride: Effects of pH and coagulant dosage,” Chinese J. Chem. Eng., vol. 23, no. 6, pp. 1041–1046, Jun. 2015.
• [30] T. K. Hussein and N. A. Jasim, “Removal of Reactive Green 12 Dye and COD from Simulated Wastewater Using Different Coagulants,” Assoc. Arab Univ. J. Eng. Sci., vol. 26, no. 2, pp. 6–11, 2019.
• [31] M. Irfan, T. Butt, N. Imtiaz, N. Abbas, R. A. Khan, and A. Shafique, “The removal of COD, TSS and colour of black liquor by coagulation–flocculation process at optimized pH, settling and dosing rate,” Arab. J. Chem., vol. 10, pp. S2307–S2318, May 2017.
• [32] S. K. A. Solmaz, A. Birgül, G. E. Üstün, and T. Yonar, “Colour and COD removal from textile effluent by coagulation and advanced oxidation processes,” Color. Technol., vol. 122, no. 2, pp. 102–109, Apr. 2006.
• [33] S. Ihaddaden, D. Aberkane, A. Boukerroui, and D. Robert, “Removal of methylene blue (basic dye) by coagulation-flocculation with biomaterials (bentonite and Opuntia ficus indica),” J. Water Process Eng., vol. 49, p. 102952, Oct. 2022.
• [34] A. Ibrahim and A. Z. Yaser, “Colour removal from biologically treated landfill leachate with tannin-based coagulant,” J. Environ. Chem. Eng., vol. 7, no. 6, p. 103483, Dec. 2019.
• [35] M. H. Zonoozi, M. R. Alavi Moghaddam, and M. Arami, “Removal of Acid Red 398 dye from aqueous solutions by coagulation/flocculation process,” Environ. Eng. Manag. J., vol. 7, no. 6, pp. 695–699, 2008.
• [36] A. Anouzla, Y. Abrouki, S. Souabi, M. Safi, and H. Rhbal, “Colour and COD removal of disperse dye solution by a novel coagulant: Application of statistical design for the optimization and regression analysis,” J. Hazard. Mater., vol. 166, no. 2–3, pp. 1302–1306, Jul. 2009.
• [37] H. Najafi and H. R. Movahed, “Improvement of COD and TOC reactive dyes in textile wastewater by coagulation chemical material,” African J. Biotechnol., vol. 8, no. 13, pp. 3053–3059, Oct. 2010.