Characterization of Thermo-Physical Properties of Nanoparticle Reinforced the Polyester Nanocomposite

Cenk Yanen; Ercan Aydoğmuş

TR EN

Nanopartikül Takviyeli Polyester Nanokompozitin Termo-Fiziksel Özelliklerinin Karakterizasyonu

Öz

Bu araştırmada, nanopartiküller kullanılarak üretilen doymamış polyester (UP) nanokompozitinin bazı termal ve fiziksel özellikleri araştırılmıştır. Nanopartikül olarak Füme Silika (FS), silisyum karbür (SiC) ve grafen nanoplate (GNP) kullanılmıştır. Sentezlenen polyester nanokompozitlere kütlece %0.2, %0.4, %0.6, %0.8 ve %1.0 oranlarında nanopartikül takviye edilmiştir. Üretilen polyester nanokompozitin ısıl iletkenlik katsayısını GNP ve SiC nanopartikül takviyeleri sırasıyla yaklaşık %64 ve %39 oranında arttırırken, FS takviyesi %12.5 oranında azaltmıştır. SiC nanopartikül, polyester nanokompozitin Shore D sertliğini % 0.1 takviye edildiği numunede %5.26 oranında arttırmıştır. Bu oran % 0.1 takviyeli FS için %3.85 ve %0.4 GNP için %1.9 olmuştur. Ayrıca, SiC ve GNP takviyesi polyester nanokompozitin yoğunluğunu arttırırken, FS takviyesi kompozitin yoğunluğunu azaltmıştır. Numunelerin termal kararlılık sıralaması FS, GNP ve SiC takviyeli nanokompozitler olarak tespit edilmiştir. En düşük termal kararlılığa sahip numunenin UP olduğu belirlenmiştir. Termal kararlılık deneylerinde elde edilen sonuçlara göre, güçlendirilmiş nanokompozitlerin termal bozunma sırasındaki kütle kayıpları karşılaştırılmıştır. Polyester nanokompozitlerin termal bozunma davranışı kinetik denklem ile modellenmiştir. Deneysel ve teorik model sonuçları karşılaştırıldı ve doğrusal olmayan regresyon kullanılarak istatistiksel analiz ile korelasyon sayıları hesaplanmıştır.

Anahtar Kelimeler

Polyester nanokompozit, Nanopartikül, Termal iletkenlik, Shore D sertlik, Termal stabilite

Characterization of Thermo-Physical Properties of Nanoparticle Reinforced the Polyester Nanocomposite

Öz

In this research, some thermal and physical properties of unsaturated polyester (UP) nanocomposite produced using nanoparticles were investigated. Fumed Silica (FS), silicon carbide (SiC) and graphene nanoplate (GNP) were used as nanoparticles. The synthesized polyester nanocomposites were reinforced with 0.2%, 0.4%, 0.6%, 0.8% and 1.0% nanoparticles by mass. GNP and SiC nanoparticle reinforcements increased the thermal conductivity coefficient of the produced polyester nanocomposite by approximately 64% and 39%, respectively, while FS reinforcement decreased it by 12.5%. SiC nanoparticle increased the Shore D hardness of the polyester nanocomposite by 5.26% in the sample with 0.1% reinforcement. This ratio was 3.85% for 0.1% supplemented FS and 1.9% for 0.4% GNP. In addition, SiC and GNP reinforcement increased the density of the polyester nanocomposite, while FS reinforcement decreased the density of the composite. The thermal stability order of the samples was determined as FS, GNP and SiC reinforced nanocomposites. It was determined that the sample with the lowest thermal stability was UP. According to the results obtained in thermal stability experiments, mass losses of reinforced nanocomposites during thermal decomposition were compared. The thermal decomposition behavior of polyester nanocomposites was modeled by the kinetic equation. Experimental and theoretical model results were compared and correlation numbers were calculated by statistical analysis using nonlinear regression.

Anahtar Kelimeler

Polyester nanocomposite, Nanoparticles, Thermal conductivity, Shore D hardness, Thermal stability

Kaynakça

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Ayrıntılar

Birincil Dil

İngilizce

Konular

Makine Mühendisliği

Bölüm

Araştırma Makalesi

Yazarlar

Cenk Yanen ^*
0000-0002-5092-8734
Türkiye

Ercan Aydoğmuş
0000-0002-1643-2487
Türkiye

Yayımlanma Tarihi

30 Aralık 2021

Gönderilme Tarihi

27 Haziran 2021

Kabul Tarihi

7 Temmuz 2021

Yayımlandığı Sayı

Yıl 2021 Cilt: 10 Sayı: 2

IZ

https://izlik.org/JA26LL86CK

APA

Yanen, C., & Aydoğmuş, E. (2021). Characterization of Thermo-Physical Properties of Nanoparticle Reinforced the Polyester Nanocomposite. Dicle Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 10(2), 121-132. https://izlik.org/JA26LL86CK

AMA

1.Yanen C, Aydoğmuş E. Characterization of Thermo-Physical Properties of Nanoparticle Reinforced the Polyester Nanocomposite. DÜFED. 2021;10(2):121-132. https://izlik.org/JA26LL86CK

Chicago

Yanen, Cenk, ve Ercan Aydoğmuş. 2021. “Characterization of Thermo-Physical Properties of Nanoparticle Reinforced the Polyester Nanocomposite”. Dicle Üniversitesi Fen Bilimleri Enstitüsü Dergisi 10 (2): 121-32. https://izlik.org/JA26LL86CK.

EndNote

Yanen C, Aydoğmuş E (01 Aralık 2021) Characterization of Thermo-Physical Properties of Nanoparticle Reinforced the Polyester Nanocomposite. Dicle Üniversitesi Fen Bilimleri Enstitüsü Dergisi 10 2 121–132.

IEEE

[1]C. Yanen ve E. Aydoğmuş, “Characterization of Thermo-Physical Properties of Nanoparticle Reinforced the Polyester Nanocomposite”, DÜFED, c. 10, sy 2, ss. 121–132, Ara. 2021, [çevrimiçi]. Erişim adresi: https://izlik.org/JA26LL86CK

ISNAD

Yanen, Cenk - Aydoğmuş, Ercan. “Characterization of Thermo-Physical Properties of Nanoparticle Reinforced the Polyester Nanocomposite”. Dicle Üniversitesi Fen Bilimleri Enstitüsü Dergisi 10/2 (01 Aralık 2021): 121-132. https://izlik.org/JA26LL86CK.

JAMA

1.Yanen C, Aydoğmuş E. Characterization of Thermo-Physical Properties of Nanoparticle Reinforced the Polyester Nanocomposite. DÜFED. 2021;10:121–132.

MLA

Yanen, Cenk, ve Ercan Aydoğmuş. “Characterization of Thermo-Physical Properties of Nanoparticle Reinforced the Polyester Nanocomposite”. Dicle Üniversitesi Fen Bilimleri Enstitüsü Dergisi, c. 10, sy 2, Aralık 2021, ss. 121-32, https://izlik.org/JA26LL86CK.

Vancouver

1.Cenk Yanen, Ercan Aydoğmuş. Characterization of Thermo-Physical Properties of Nanoparticle Reinforced the Polyester Nanocomposite. DÜFED [Internet]. 01 Aralık 2021;10(2):121-32. Erişim adresi: https://izlik.org/JA26LL86CK

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Nanopartikül Takviyeli Polyester Nanokompozitin Termo-Fiziksel Özelliklerinin Karakterizasyonu

Öz

Anahtar Kelimeler

Characterization of Thermo-Physical Properties of Nanoparticle Reinforced the Polyester Nanocomposite

Öz

Anahtar Kelimeler

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

IZ

Kaynak Göster