Congo Red Biosorption with Dried Mint Leaves; Isotherm and Kinetic Studies

Öz

The development of the industry has resulted in a proportional increase in waste materials. Waste industrial products play a major role in the pollution of nature along with seas, lakes, and various water resources around the world. Organic dyes, which do not degrade in nature and have carcinogenic effects, are important industrial wastes. The improvement of wastewater is a research topic that has gained importance in recent years. In this study, the biosorption of Congo red dye from aqueous solution with dried mint leaves was investigated. The experiments were carried out at 20 °C and the natural pH of the dye. The process was optimized by examining the parameters of initial dye concentration, amount of biosorbent and contact time. It was determined that the biosorption equilibrium conformed to the Langmuir isotherm (R2=0.9815) and the maximum biosorption capacity (qmax) was 60.24 mg/g. In addition, the process conforms to the pseudo-second-order (R2=0.9946) kinetic model. As a result of the process, the removal of the Congo red dye from the dried mint leaves from the aqueous solution was achieved at a level of approximately 70%.

Anahtar Kelimeler

• Mint
• Biosorption
• Congo red
• Isotherm
• Dye

Kaynakça

1. H. Chen, Y. Zheng, B. Cheng, J. Yu, C. Jiang, “Chestnut husk-like nickel cobaltite hollow microspheres for the adsorption of Congo red,” Journal of Alloys and Comp., vol. 735, pp. 1041–51, 2018.
2. A. Khan, A. Naeem, T. Mahmood, “Kinetic Studies of Methyl Orange and Congo Red Adsorption and Photocatalytic Degradation onto PVP-Functionalized ZnO,” Kinetics and Catalysis, vol. 61(5), pp. 730–9, 2020.
3. H. Kaur, R, Kaur, “Kinetic and Isotherm Studies of Congo Red Adsorption from Aqueous Solution by Biowaste Material,” Chem. Sci. Trans., vol. 3(4), pp. 1300–9, 2014.
4. M. Harja, G Buema, D. Bucur, “Recent advances in removal of Congo Red dye by adsorption using an industrial waste,” Sci. Rep., vol. 12(1), pp. 1–18, 2022.
5. C. Liu, H. Liu, K. Tang, K. Zhang, Z. Zou, X. Gao, “igh-Strength Chitin Based Hydrogels Reinforced by Tannic Acid Functionalized Graphene for Congo Red Adsorption,” J of Polymers and the Environ., vol. 28(3), pp. 984–94, 2020.
6. J. Wang, Q. Zhou, D. Song, B. Qi, Y. Zhang, Y. Shao, Z. Shao, “Chitosan–silica composite aerogels: preparation, characterization and Congo red adsorption,” Journal of Sol-Gel Sci and Tech. vol. 76(3), pp. 501–9, 2015.
7. O.A. Ramírez Calderón, O. M.Abdeldayem, A. Pugazhendhi, E.R. Rene, “Current Updates and Perspectives of Biosorption Technology: an Alternative for the Removal of Heavy Metals from Wastewater,” Current Poll. Rep., vol. 6(1), pp. 8–27, 2020.
8. I.A. Amar, E.A. Zayid, S.A. Dhikeel, M.Y. Najem, “Biosorption removal of methylene blue dye from aqueous solutions using phosphoric acid-treated balanites aegyptiaca seed husks powder,” Biointerface Research in Applied Chemistry, vol. 12(6), pp. 7845–62, 2022.

9. M. Malakootian, M.R. Heidari, “Reactive orange 16 dye adsorption from aqueous solutions by psyllium seed powder as a low-cost biosorbent: kinetic and equilibrium studies,” Applied Water Science, vol. 8(7), pp. 1–9, 2018