4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald®)'un Elektropolimerizayonu

Yıl 2019, , 159 - 165, 31.08.2019

Mert Soysal

https://doi.org/10.31590/ejosat.550431

Cited By: 2

Öz

Bu çalışmada, tek kullanımlık kalem grafit elektrot (PGE) üzerinde 4-amino-3-hidrazino-5-merkapto-1,2,4-triazolün (Purpald®) elektropolimerizasyonu tanımlanmış ve polimer film kaplı ve çıplak PG'nin elektroaktivitesi, pH 8 Britton Robinson (BR) tampon çözeltisi içerisinde hazırlanan  K3 [Fe (CN) 6] / K4 [Fe (CN) 6] çözeltisi ile test edildi. Purpald® filminin elektropolimerizasyonu döngülü voltammetri (CV) ile yapıldı. Elektrokimyasal empedans spektroskopisi (EIS) kullanılarak, Purpald® film kaplı elektrotun optimum koşulları belirlenmiştir. Purplad® ile modifiye edilmiş elektrotların iletkenliği, EIS tekniği ile çıplak ve p-fenilendiamin ile modifiye edilmiş PG elektrotları ile karşılaştırıldı. Sonuçlar, elektrosentezlenmiş poli (Purplad®) filmin, elektrokimyasal analizlerde ve sensör uygulamalarında kullanılacak elektrotların modifikasyonu için kullanılabileceğini göstermektedir.

Anahtar Kelimeler

İletken polimer, Elektropolimerizasyon, Filmler, Triazole Türevleri, Kurşun Kalem Elektrotlar

Electropolymerization of 4-amino-3-hydrazino-5-mercapto-1,2,4- triazole (Purpald® )

Öz

In this study electropolymerization of
4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald^®) on the
disposable pencil graphite electrode (PGE) was described and the
electroactivity of the polymer film coated and naked PG electrodes were checked
against K₃[Fe(CN)₆] / K₄[Fe(CN)₆]
in pH 8 Britton‑Robinson (BR) buffer solution. The electropolymerization of
Purpald^® film was performed with cyclic voltammetry (CV). The
optimal conditions of Purpald^® film coated electrode were performed
using electrochemical impedance spectroscopy (EIS). The conductivity of the
Purplad^® modified electrodes was compared with bare and
p-phenylenediamine modified PG electrodes by EIS technique. The results
indicated that electrosynthesized poly(Purplad^®) film could be used
for modification of electrodes to be used in electrochemical analysis and
sensor applications.

Anahtar Kelimeler

Conducting polymer, electropolymerization, Films, Triazole derivatives, Pencil graphide electrode

Kaynakça

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