One-pot Green Synthesis of Palladium Doped Reduced Graphene Oxide Composite For Electrochemical Determination of Hydrogen Peroxide

Abstract

In the present study, a modified electrosensor based on one-pot green synthesized palladium doped reduced graphene oxide composite (Pd@rGO) has been developed for the electrochemical determination of hydrogen peroxide. The electrochemical features of the electrosensor was appraised by cyclic voltammetry (CV) and differential puls voltammetry (DPV) techniques. The Pd@rGO modified glassy carbon electrode exhibited a superior electroactivity as against to unmodified glassy carbon electrode (GCE). It demonstrated a superior performance toward hydrogen peroxide in the concentration range of 10 μM and 1.0 mM with a detection limit of 0.12 μM. The selectivity of the sensor was investigated in the presence of various biological interferents like glucose, ascorbic acid, dopamine, paracetamol and uric acid. The results showed that the electrosensor had no considerable reponse to those of intererent substances.

Keywords

• Reduced graphene oxide
• Electrosensor
• Hydrogen peroxide
• Nanocomposite
• Green synthesis
• Reduced graphene oxide, Electrosensor, Hydrogen peroxide, Nanocomposite, Green synthesis

Hidrojen Peroksitin Elektrokimyasal Tayini İçin Paladyum Katkılı İndirgenmiş Grafen Oksit Kompozitinin Tek Basamaklı Yeşil Sentezi

Öz

Bu çalışmada, hidrojen peroksitin elektrokimyasal tayini için bir basamakta yeşil yöntemle sentezlenmiş paladyum katkılı indirgenmiş grafen oksit kompozitine (Pd@rGO) dayalı modifiye bir elektrosensör geliştirilmiştir. Elektrosensörün elektrokimyasal özellikleri, döngüsel voltametri (CV) ve diferansiyel puls voltametri (DPV) teknikleriyle değerlendirilmiştir. Pd@rGO kompozit ile modifiye edilmiş camsı karbon elektrot, modifiye edilmemiş camsı karbon elektroduna (GCE) göre üstün bir elektroaktivite sergilemiştir. Elektrosensor 0.12 μM saptama limiti ile 10 μM ve 1.0 mM derişim aralığında hidrojen peroksite karşı iyi bir performans göstermiştir. Sensörün seçiciliği, glikoz, askorbik asit, dopamin, parasetamol ve ürik asit gibi girişim yapan çeşitli biyolojik moleküllerin varlığında araştırılmıştır. Sonuçlar, elektrosensörün girişim yapan maddelere karşı önemli bir cevap vermediği belirlenmiştir.

Anahtar Kelimeler

• İndirgenmiş grafen oksit
• Elektrosensör
• Hidrojen peroksit
• Nanokompozit
• Yeşil sentez

Kaynakça

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