Yıl 2019, Cilt , Sayı 16, Sayfalar 159 - 165 2019-08-31

4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald®)'un Elektropolimerizayonu
Electropolymerization of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald®)

Mert Soysal [1]


Bu çalışmada, tek kullanımlık kalem grafit elektrot (PGE) üzerinde 4-amino-3-hidrazino-5-merkapto-1,2,4-triazolün (Purpald®) elektropolimerizasyonu tanımlanmış ve polimer film kaplı ve çıplak PG'nin elektroaktivitesi, pH 8 Britton Robinson (BR) tampon çözeltisi içerisinde hazırlanan  K3 [Fe (CN) 6] / K4 [Fe (CN) 6] çözeltisi ile test edildi. Purpald® filminin elektropolimerizasyonu döngülü voltammetri (CV) ile yapıldı. Elektrokimyasal empedans spektroskopisi (EIS) kullanılarak, Purpald® film kaplı elektrotun optimum koşulları belirlenmiştir. Purplad® ile modifiye edilmiş elektrotların iletkenliği, EIS tekniği ile çıplak ve p-fenilendiamin ile modifiye edilmiş PG elektrotları ile karşılaştırıldı. Sonuçlar, elektrosentezlenmiş poli (Purplad®) filmin, elektrokimyasal analizlerde ve sensör uygulamalarında kullanılacak elektrotların modifikasyonu için kullanılabileceğini göstermektedir.

In this study electropolymerization of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald®) on the disposable pencil graphite electrode (PGE) was described and the electroactivity of the polymer film coated and naked PG electrodes were checked against K3[Fe(CN)6] / K4[Fe(CN)6] in pH 8 Britton‑Robinson (BR) buffer solution. The electropolymerization of Purpald® film was performed with cyclic voltammetry (CV). The optimal conditions of Purpald® film coated electrode were performed using electrochemical impedance spectroscopy (EIS). The conductivity of the Purplad® modified electrodes was compared with bare and p-phenylenediamine modified PG electrodes by EIS technique. The results indicated that electrosynthesized poly(Purplad®) film could be used for modification of electrodes to be used in electrochemical analysis and sensor applications.

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Birincil Dil en
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Yazarlar

Orcid: 0000-0002-5685-0261
Yazar: Mert Soysal (Sorumlu Yazar)
Kurum: ADNAN MENDERES UNIVERSITY
Ülke: Turkey


Tarihler

Yayımlanma Tarihi : 31 Ağustos 2019

Bibtex @araştırma makalesi { ejosat550431, journal = {Avrupa Bilim ve Teknoloji Dergisi}, issn = {}, eissn = {2148-2683}, address = {}, publisher = {Osman SAĞDIÇ}, year = {2019}, volume = {}, pages = {159 - 165}, doi = {10.31590/ejosat.550431}, title = {Electropolymerization of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald®)}, key = {cite}, author = {Soysal, Mert} }
APA Soysal, M . (2019). Electropolymerization of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald®). Avrupa Bilim ve Teknoloji Dergisi , (16) , 159-165 . DOI: 10.31590/ejosat.550431
MLA Soysal, M . "Electropolymerization of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald®)". Avrupa Bilim ve Teknoloji Dergisi (2019 ): 159-165 <https://dergipark.org.tr/tr/pub/ejosat/issue/45333/550431>
Chicago Soysal, M . "Electropolymerization of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald®)". Avrupa Bilim ve Teknoloji Dergisi (2019 ): 159-165
RIS TY - JOUR T1 - Electropolymerization of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald®) AU - Mert Soysal Y1 - 2019 PY - 2019 N1 - doi: 10.31590/ejosat.550431 DO - 10.31590/ejosat.550431 T2 - Avrupa Bilim ve Teknoloji Dergisi JF - Journal JO - JOR SP - 159 EP - 165 VL - IS - 16 SN - -2148-2683 M3 - doi: 10.31590/ejosat.550431 UR - https://doi.org/10.31590/ejosat.550431 Y2 - 2019 ER -
EndNote %0 Avrupa Bilim ve Teknoloji Dergisi Electropolymerization of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald®) %A Mert Soysal %T Electropolymerization of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald®) %D 2019 %J Avrupa Bilim ve Teknoloji Dergisi %P -2148-2683 %V %N 16 %R doi: 10.31590/ejosat.550431 %U 10.31590/ejosat.550431
ISNAD Soysal, Mert . "Electropolymerization of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald®)". Avrupa Bilim ve Teknoloji Dergisi / 16 (Ağustos 2019): 159-165 . https://doi.org/10.31590/ejosat.550431
AMA Soysal M . Electropolymerization of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald®). Avrupa Bilim ve Teknoloji Dergisi. 2019; (16): 159-165.
Vancouver Soysal M . Electropolymerization of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (Purpald®). Avrupa Bilim ve Teknoloji Dergisi. 2019; (16): 165-159.