Öz
In this study, we prepared a novel fluorescent chemosensor containing an imidazole molecule and the chemosensor characterized utilizing 1H-NMR, 13C-NMR spectroscopy, FT-IR spectrometer and elemental analyzer. Prepared sensor was utilized as an effectively selective and a fastly responsive chemical fluorescent sensor for ‘’turn off’’ determination of mercury (II) ions in EtOH. A clear complex between 2-((4-(1H-phenanthro[9,10-d] imidazol-2-yl)benzylidene)amino) phenol (PENIM) and Hg+ ions was determined and calculated employing the Job’s method and also the limit of detection value was found to be 2.1 nM on the basis of 3σ/k. Furthermore, the sensor-Hg2+ displayed and reversible property for mercapto containing cysteine molecules. Also, the fluorescence enhancement and quenching studies were supported by computational experiments based on the density functional theory (DFT) calculations.
Anahtar Kelimeler
Teşekkür
The author is grateful to the KMU Scientific Research Project Center for their support with the project numbers 30-M-16 and to provide the Gaussian 09W and Gauss view 5.0.8 programs.
Kaynakça
- Chen, G., Guo, Z., Zeng, G., & Tang, L. (2015). Fluorescent and colorimetric sensors for environmental mercury detection. Analyst, 140(16), 5400–5443. https://doi.org/10.1039/c5an00389j
- Chen, J. F., Han, B. B., Ma, J. F., Liu, X., Yang, Q. Y., Lin, Q., Wei, T. B. (2017). Pillar[5]arene-based fluorescent polymer for selective detection and removal of mercury ions. RSC Advances, 7(75), 47709–47714. https://doi.org/10.1039/c7ra10326c
- Chen, L., Yang, L., Li, H., Gao, Y., Deng, D., Wu, Y., & Ma, L. J. (2011). Tridentate lysine-based fluorescent sensor for Hg(II) in aqueous solution. Inorganic Chemistry, 50(20), 10028–10032. https://doi.org/10.1021/ic200790g
- Guo, C., & Irudayaraj, J. (2011). Fluorescent Ag clusters via a protein-directed approach as a Hg(II) ion sensor. Analytical Chemistry, 83(8), 2883–2889. https://doi.org/10.1021/ac1032403
- Han, B., Yuan, J., & Wang, E. (2009). Sensitive and selective sensor for biothiols in the cell based on the recovered fluorescence of the CdTe quantum dots-Hg(II) system. Analytical Chemistry, 81(13), 5569–5573. https://doi.org/10.1021/ac900769h
- Jiao, Y., Zhang, L., & Zhou, P. (2016). A rhodamine B-based fluorescent sensor toward highly selective mercury (II) ions detection. Talanta, 150, 14–19. https://doi.org/10.1016/j.talanta.2015.11.065
- Karuk Elmas, Ş. N., & Yilmaz, I. (2018). A Turn off-on Fluorescent Chemosensor for Sequential Determination of Mercury and Biothiols. Journal of Fluorescence, 28(6), 1451–1458. https://doi.org/10.1007/s10895-018-2320-6
- Li, G., Ma, L., Liu, G., Fan, C., & Pu, S. (2017). A diarylethene-based “on-off-on” fluorescence sensor for the sequential recognition of mercury and cysteine. RSC Advances, 7(33), 20591–20596. https://doi.org/10.1039/c6ra27773j
- Li, M., Zhou, X., Ding, W., Guo, S., & Wu, N. (2013). Fluorescent aptamer-functionalized graphene oxide biosensor for label-free detection of mercury(II). Biosensors and Bioelectronics, 41(1), 889–893. https://doi.org/10.1016/j.bios.2012.09.060
- Li, Q., Wang, C., Tan, H., Tang, G., Gao, J., & Chen, C. H. (2016). A turn on fluorescent sensor based on lanthanide coordination polymer nanoparticles for the detection of mercury(II) in biological fluids. RSC Advances, 6(22), 17811–17817. https://doi.org/10.1039/c5ra26849d
- Taki, M., Akaoka, K., Iyoshi, S., & Yamamoto, Y. (2012). Rosamine-based fluorescent sensor with femtomolar affinity for the reversible detection of a mercury ion. Inorganic Chemistry, 51(24), 13075–13077. https://doi.org/10.1021/ic301822r.
- Lin W., Long L., Yuan L., Cao Z., Chen B., and Tan W., (2008). A Ratiometric Fluorescent Probe for Cysteine and Homocysteine Displaying a Large Emission Shift, Org. Lett., 10(24), 5577-5580. https://doi.org/10.1021/ol802436j.
Öz
In this study, we prepared a novel fluorescent chemosensor containing an imidazole molecule and the chemosensor characterized utilizing 1H-NMR, 13C-NMR spectroscopy, FT-IR spectrometer and elemental analyzer. Prepared sensor was utilized as an effectively selective and a fastly responsive chemical fluorescent sensor for ‘’turn off’’ determination of mercury (II) ions in EtOH. A clear complex between 2-((4-(1H-phenanthro[9,10-d] imidazol-2-yl)benzylidene)amino) phenol (PENIM) and Hg+ ions was determined and calculated employing the Job’s method and also the limit of detection value was found to be 2.1 nM on the basis of 3σ/k. Furthermore, the sensor-Hg2+ displayed and reversible property for mercapto containing cysteine molecules. Also, the fluorescence enhancement and quenching studies were supported by computational experiments based on the density functional theory (DFT) calculations.
Anahtar Kelimeler
Kaynakça
- Chen, G., Guo, Z., Zeng, G., & Tang, L. (2015). Fluorescent and colorimetric sensors for environmental mercury detection. Analyst, 140(16), 5400–5443. https://doi.org/10.1039/c5an00389j
- Chen, J. F., Han, B. B., Ma, J. F., Liu, X., Yang, Q. Y., Lin, Q., Wei, T. B. (2017). Pillar[5]arene-based fluorescent polymer for selective detection and removal of mercury ions. RSC Advances, 7(75), 47709–47714. https://doi.org/10.1039/c7ra10326c
- Chen, L., Yang, L., Li, H., Gao, Y., Deng, D., Wu, Y., & Ma, L. J. (2011). Tridentate lysine-based fluorescent sensor for Hg(II) in aqueous solution. Inorganic Chemistry, 50(20), 10028–10032. https://doi.org/10.1021/ic200790g
- Guo, C., & Irudayaraj, J. (2011). Fluorescent Ag clusters via a protein-directed approach as a Hg(II) ion sensor. Analytical Chemistry, 83(8), 2883–2889. https://doi.org/10.1021/ac1032403
- Han, B., Yuan, J., & Wang, E. (2009). Sensitive and selective sensor for biothiols in the cell based on the recovered fluorescence of the CdTe quantum dots-Hg(II) system. Analytical Chemistry, 81(13), 5569–5573. https://doi.org/10.1021/ac900769h
- Jiao, Y., Zhang, L., & Zhou, P. (2016). A rhodamine B-based fluorescent sensor toward highly selective mercury (II) ions detection. Talanta, 150, 14–19. https://doi.org/10.1016/j.talanta.2015.11.065
- Karuk Elmas, Ş. N., & Yilmaz, I. (2018). A Turn off-on Fluorescent Chemosensor for Sequential Determination of Mercury and Biothiols. Journal of Fluorescence, 28(6), 1451–1458. https://doi.org/10.1007/s10895-018-2320-6
- Li, G., Ma, L., Liu, G., Fan, C., & Pu, S. (2017). A diarylethene-based “on-off-on” fluorescence sensor for the sequential recognition of mercury and cysteine. RSC Advances, 7(33), 20591–20596. https://doi.org/10.1039/c6ra27773j
- Li, M., Zhou, X., Ding, W., Guo, S., & Wu, N. (2013). Fluorescent aptamer-functionalized graphene oxide biosensor for label-free detection of mercury(II). Biosensors and Bioelectronics, 41(1), 889–893. https://doi.org/10.1016/j.bios.2012.09.060
- Li, Q., Wang, C., Tan, H., Tang, G., Gao, J., & Chen, C. H. (2016). A turn on fluorescent sensor based on lanthanide coordination polymer nanoparticles for the detection of mercury(II) in biological fluids. RSC Advances, 6(22), 17811–17817. https://doi.org/10.1039/c5ra26849d
- Taki, M., Akaoka, K., Iyoshi, S., & Yamamoto, Y. (2012). Rosamine-based fluorescent sensor with femtomolar affinity for the reversible detection of a mercury ion. Inorganic Chemistry, 51(24), 13075–13077. https://doi.org/10.1021/ic301822r.
- Lin W., Long L., Yuan L., Cao Z., Chen B., and Tan W., (2008). A Ratiometric Fluorescent Probe for Cysteine and Homocysteine Displaying a Large Emission Shift, Org. Lett., 10(24), 5577-5580. https://doi.org/10.1021/ol802436j.
Ayrıntılar
| Birincil Dil | İngilizce |
|---|---|
| Konular | Mühendislik |
| Bölüm | Makaleler |
| Yazarlar | |
| Yayımlanma Tarihi | 31 Aralık 2019 |
| Yayımlandığı Sayı | Yıl 2019 Sayı: 17 |
