Malachite Green Dye Removal from Aqueous Solutions Using Invader Centaurea Solstitialis Plant and Optimization by Response Surface Method: Kinetic, Isotherm, And Thermodynamic Study

Yıl 2019, Sayı: 17, 755 - 768, 31.12.2019

Mohammed Saleh Mutlu Yalvaç Hüdaverdi Arslan Melis Gün

https://doi.org/10.31590/ejosat.643238

Cited By: 12

Öz

Invasive plants
reduce the yield by inhibiting the development of agricultural products. In
this study, invasive (CS) plant which is agricultural waste was used as
adsorbent for removal of Malachite Green (MG) from aqueous solution. The
adsorbent - adsorbate relationship was examined by the spectrophotometric
method and Fourier transform infrared (FTIR). The surface morphology was
determined by scanning electron microscope (SEM). CS surface area was measured
by Brunauer, the Emmett and Teller (BET) analysis. The experiments were
designed and modeled by RSM. The correlation factor of the developed model was
0.984. The capacity of 90.816 mg.g^-1 was achieved when MG solution
with concentration of 312.5 mg.L^-1 was adsorbed onto 0.325 g CS for
75 min at a pH of 7.5. In this work the shaking velocity and the adsorbent size
were 150 rpm and 30 mesh respectively. Langmuir, Freundlich, Temkin, and
Dubinin-Radushkevich (D-R) isotherms were studied. Temkin isotherm had the
highest R² of 0.997. The kinetics models of the adsorption process
were investigated and fitted with pseudo-second-order kinetic (R² =
0.9982). The intraparticle diffusion model reflected the involved two steps;
the first comprehended the boundary diffusion layer, while the second
introduced the intraparticle diffusion effects. The adsorption was found to be
endothermic with a Gibbs free energy of -4.47 KJ.mol^-1. It was noted
that the adsorption process was irreversible with a max percentage of
desorption process of 2.16%. Column experiments were conducted to realize the
adsorption process. The efficiency of the column reached 99.5% after 40 min and
stilled constant. As a result, CS has shown a potential for MG removal
from aqueous solution.

Anahtar Kelimeler

Malachite Green; Centaurea solstitialis, Adsorption process, Response Surface Method

İstilacı Centaurea Solstitialis Bitkisi Kullanılarak Sulu Çözeltilerden Malahit Yeşil Boya Giderimi ve Tepki Yüzey Yöntemi ile Optimizasyon: Kinetik, İzoterm ve Termodinamik Çalışma

Öz

İstilacı bitkiler,
tarım ürünlerinin gelişimini engelleyerek ürün verimini azaltmaktadır. Bu
çalışmada, sentetik bir boya olan Malachite Green (MG)'nin sulu çözeltiden
uzaklaştırılmasında tarımsal atık olan istilacı Centaurea Solstitialis (CS)
bitkisi adsorban olarak  kullanılmıştır.
Adsorbent - adsorbate ilişkisi, spektrofotometrik yöntem ve Fourier dönüşüm
infrared (FTIR) ile incelenmiştir. Yüzey morfolojisi taramalı elektron
mikroskobu (SEM) ile belirlenmiştir. CS yüzey alanı Brunauer, Emmett ve Teller
(BET) analizi ile ölçülmüştür. Deney tasarımı ve modellemesinde RSM kullanılmış
ve korelasyon faktörü 0,984 olarak bulunmuştur. Optimum çalışma koşulu olan
312.5 mg.L^-1MG içeren çözeltiye (pH=7.5) 0.325 g CS (30 mesh)
koyularak 150 rpm’de 75 dakika çalkalanmıştır. Çalışmada CS tanecik boyutu 30
mesh ve çalkalama hızı 150 rpm sabit tutulmuştur. Optimum çalışma koşullarında
CS’nin maksimum adsorpsiyon kapasitesi 90.816 mg.g^-1 bulunmuştur.
Sonuçlar Langmuir, Freundlich, Temkin ve Dubinin-Radushkevich (D-R) izotermleri
ile değerlendirilmiştir. Sonuç olarak adsorpsiyon işleminin Temkin izotermine
(0,997 R²) uyan yalancı ikinci dereceden (R² = 0.9982)
bir kinetik reaksiyon olduğu bulunmuştur. İntrapartikül difüzyon modeli,
sırasıyla sınır difüzyon tabakası ve partikül içi difüzyon etkilerini
göstermiştir. Adsorpsiyonun -4,47 KJ.mol^-1 Gibbs serbest enerjisi
ile endotermik olduğu bulunmuştur. Desorpsiyon çalışmasında maksimum %2.16’lık
bir verim elde edilmiştir. Bu sonuç CS üzerine adsorbe olan MG’nin tekrar suya
karışma ihtimalinin düşük olduğunu göstermektedir.  Daha sonra kolon çalışmalarına
geçilmiştir.  Kolonun verimliliği, 40.
dakikada % 99.5'e ulaşmış ve bundan sonra sabit kalmıştır. Sonuç olarak,
CS’nin, sulu çözeltiden MG gideriminde etkili bir adsorbent olduğu bulunmuştur.

Anahtar Kelimeler

Malahit Yeşili, Centaurea solstitialis, Adsorpsiyon işlemi, Tepki Yüzey Yöntemi

Kaynakça

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