Sulu ortamda gerçek zamanlı civa iyonunun tayini için yeni bir rodamin bazlı floresans ve kolorimetrik kimyasal sensör
Öz
A novel nitro-benzene thiosemicarbazide appended rhodamine (the chemosensor BODN) was designed and prepared as a fluorescence ''turn-on'' and colorimetric chemosensor for the determination of Hg2+ ion in the presence of other metal cations. The chemosensor BODN showed an emission enhancing at 580 nm toward Hg2+ ions because of ''FRET-on'' (Fluorescence resonance energy transfer-on) proces. All spectral experiments were carried out in H2O/ACN (v/v, 20/80, pH=7.0) media at room temperature. The binding stoichiometry between the chemosensor BODN and Hg2+ was found to be 2:1 by job’s method and ESI-MS technique. The chemosensor BODN could detect Hg2+ ions at a concentration as low as 3.21 nM
Anahtar Kelimeler
Chemosensor colorimetric fluorescence mercury rhodamine turn-on
Kaynakça
- Aydin, D. (2018). A Turn Off Fluorescent Probe for Selective Detection of Hg2+ Ions. European Journal of Science and Technology, (17), 483-490. https://doi.org/10.31590/ejosat.634119
- Aydin, D. (2020). A Novel Turn on Fluorescent Probe for the Determination of Al3+ and Zn2+ Ions and Its Cells Applications. Talanta 210: 120615. https://doi.org/10.1016/j.talanta.2019.120615
- Chen, G., Guo, Z., Zeng, G., & Tang, L. (2015). Fluorescent and colorimetric sensors for environmental mercury detection. Analyst, 140(16), 5400–5443. https://doi.org/10.1039/c5an00389j
- Chen, J. F., Han, B. B., Ma, J. F., Liu, X., Yang, Q. Y., Lin, Q., Wei, T. B. (2017). Pillar[5]arene-based fluorescent polymer for selective detection and removal of mercury ions. RSC Advances, 7(75), 47709–47714. https://doi.org/10.1039/c7ra10326c
- Chen, L., Yang, L., Li, H., Gao, Y., Deng, D., Wu, Y., & Ma, L. J. (2011). Tridentate lysine-based fluorescent sensor for Hg(II) in aqueous solution. Inorganic Chemistry, 50(20), 10028–10032. https://doi.org/10.1021/ic200790g
- Erdemir, S. (2019). Fluorimetric Dual Sensing of Hg2+ and Al3+ by Novel Triphenylamine Appended Rhodamine Derivative in Aqueous Media. Sensors & Actuators: B. Chemical 290: 558–64. https://doi.org/10.1016/j.snb.2019.04.037
- Karuk Elmas, Ş. N., Ozen, F., Koran, K., Yilmaz, I., Gorgulu, A. O., Erdemir, S. (2017). Coumarin Based Highly Selective ‘off-on-off’ Type Novel Fluorescent Sensor for Cu2+ and S2− in Aqueous Solution. Journal of Fluorescence 27(2). 27, doi: 10.1007/s10895-016-1972-3.
- Kan, C., Xiaotao S., Fan, S., Jinbao, X., Jing, Z., and Lei, D. (2019). Bioimaging of a Fluorescence Rhodamine-Based Probe for Reversible Detection of Hg (II) and Its Application in Real Water Environment. Microchemical Journal 150.104142. https://doi.org/10.1016/j.microc.2019.104142
- Karuk Elmas, Ş. N., & Yilmaz, I. (2018). A Turn off-on Fluorescent Chemosensor for Sequential Determination of Mercury and Biothiols. Journal of Fluorescence, 28(6), 1451–1458. https://doi.org/10.1007/s10895-018-2320-6
- Kilic, H. & Bozkurt E. (2018). A Rhodamine-Based Novel Turn on Trivalent Ions Sensor. Journal of Photochemistry and Photobiology A: Chemistry 363: 23–30. https://doi.org/10.1016/j.jphotochem.2018.05.024.
- Liu, Y., Lv, X., Liu, J., Sun, Y. Q., Guo, W. (2015). Construction of a Selective Fluorescent Probe for GSH Based on a Chloro-Functionalized Coumarin-Enone Dye Platform. Chemistry - A European Journal 21(12): 4747–54. https://doi.org/10.1002/chem.201406004
- Maniyazagan, M., Mariadasse, R., Jeyakanthan, J., Lokanath, N. K., Naveen, S., Premkumar, K., Muthuraja, P., Manisankar, P., Stalin, T. (2017). Rhodamine Based ‘Turn–on’ Molecular Switch FRET–Sensor for Cadmium and Sulfide Ions and Live Cell Imaging Study. Sensors and Actuators, B: Chemical 238: 565–77. http://doi.org/10.1016/j.snb.2016.07.102.
- Sikdar, A., Swapnadip, R., Kakali, H., Soma, S., Sujit, S. P. (2013). Rhodamine-Based Cu2+-Selective Fluorosensor: Synthesis, Mechanism, and Application in Living Cells. Journal of Fluorescence 23(3):495–501. https://doi.org/10.1007/s10895-013-1169-y
A new rhodamine-based colorimetric and fluorescence chemosensor for the real-time determination of Hg2+ in aqueous media
Öz
A novel nitro-benzene thiosemicarbazide appended rhodamine (the chemosensor BODN) was designed and prepared as a fluorescence ''turn-on'' and colorimetric chemosensor for the determination of Hg2+ ion in the presence of other metal cations. The chemosensor BODN showed an emission enhancing at 580 nm toward Hg2+ ions because of ''FRET-on'' (Fluorescence resonance energy transfer-on) proces. All spectral experiments were carried out in H2O/ACN (v/v, 20/80, pH=7.0) media at room temperature. The binding stoichiometry between the chemosensor BODN and Hg2+ was found to be 2:1 by job’s method and ESI-MS technique. The chemosensor BODN could detect Hg2+ ions at a concentration as low as 3.21 nM
Anahtar Kelimeler
Chemosensor colorimetric fluorescence mercury rhodamine turn-on
Kaynakça
- Aydin, D. (2018). A Turn Off Fluorescent Probe for Selective Detection of Hg2+ Ions. European Journal of Science and Technology, (17), 483-490. https://doi.org/10.31590/ejosat.634119
- Aydin, D. (2020). A Novel Turn on Fluorescent Probe for the Determination of Al3+ and Zn2+ Ions and Its Cells Applications. Talanta 210: 120615. https://doi.org/10.1016/j.talanta.2019.120615
- Chen, G., Guo, Z., Zeng, G., & Tang, L. (2015). Fluorescent and colorimetric sensors for environmental mercury detection. Analyst, 140(16), 5400–5443. https://doi.org/10.1039/c5an00389j
- Chen, J. F., Han, B. B., Ma, J. F., Liu, X., Yang, Q. Y., Lin, Q., Wei, T. B. (2017). Pillar[5]arene-based fluorescent polymer for selective detection and removal of mercury ions. RSC Advances, 7(75), 47709–47714. https://doi.org/10.1039/c7ra10326c
- Chen, L., Yang, L., Li, H., Gao, Y., Deng, D., Wu, Y., & Ma, L. J. (2011). Tridentate lysine-based fluorescent sensor for Hg(II) in aqueous solution. Inorganic Chemistry, 50(20), 10028–10032. https://doi.org/10.1021/ic200790g
- Erdemir, S. (2019). Fluorimetric Dual Sensing of Hg2+ and Al3+ by Novel Triphenylamine Appended Rhodamine Derivative in Aqueous Media. Sensors & Actuators: B. Chemical 290: 558–64. https://doi.org/10.1016/j.snb.2019.04.037
- Karuk Elmas, Ş. N., Ozen, F., Koran, K., Yilmaz, I., Gorgulu, A. O., Erdemir, S. (2017). Coumarin Based Highly Selective ‘off-on-off’ Type Novel Fluorescent Sensor for Cu2+ and S2− in Aqueous Solution. Journal of Fluorescence 27(2). 27, doi: 10.1007/s10895-016-1972-3.
- Kan, C., Xiaotao S., Fan, S., Jinbao, X., Jing, Z., and Lei, D. (2019). Bioimaging of a Fluorescence Rhodamine-Based Probe for Reversible Detection of Hg (II) and Its Application in Real Water Environment. Microchemical Journal 150.104142. https://doi.org/10.1016/j.microc.2019.104142
- Karuk Elmas, Ş. N., & Yilmaz, I. (2018). A Turn off-on Fluorescent Chemosensor for Sequential Determination of Mercury and Biothiols. Journal of Fluorescence, 28(6), 1451–1458. https://doi.org/10.1007/s10895-018-2320-6
- Kilic, H. & Bozkurt E. (2018). A Rhodamine-Based Novel Turn on Trivalent Ions Sensor. Journal of Photochemistry and Photobiology A: Chemistry 363: 23–30. https://doi.org/10.1016/j.jphotochem.2018.05.024.
- Liu, Y., Lv, X., Liu, J., Sun, Y. Q., Guo, W. (2015). Construction of a Selective Fluorescent Probe for GSH Based on a Chloro-Functionalized Coumarin-Enone Dye Platform. Chemistry - A European Journal 21(12): 4747–54. https://doi.org/10.1002/chem.201406004
- Maniyazagan, M., Mariadasse, R., Jeyakanthan, J., Lokanath, N. K., Naveen, S., Premkumar, K., Muthuraja, P., Manisankar, P., Stalin, T. (2017). Rhodamine Based ‘Turn–on’ Molecular Switch FRET–Sensor for Cadmium and Sulfide Ions and Live Cell Imaging Study. Sensors and Actuators, B: Chemical 238: 565–77. http://doi.org/10.1016/j.snb.2016.07.102.
- Sikdar, A., Swapnadip, R., Kakali, H., Soma, S., Sujit, S. P. (2013). Rhodamine-Based Cu2+-Selective Fluorosensor: Synthesis, Mechanism, and Application in Living Cells. Journal of Fluorescence 23(3):495–501. https://doi.org/10.1007/s10895-013-1169-y
Ayrıntılar
| Birincil Dil | İngilizce |
|---|---|
| Konular | Mühendislik |
| Bölüm | Makaleler |
| Yazarlar | |
| Yayımlanma Tarihi | 31 Ocak 2021 |
| Yayımlandığı Sayı | Yıl 2021 Sayı: 21 |
