Tarla koşullarında yetiştirilen biberlerde lufenuron’un parçalanma kinetiğinin araştırılması

Öz

Biber, Capsicum annuum L. (Solanales: Solanaceae), dünyada üretimi son derece yaygın olan bir kültür bitkisi olup, biber üretiminde Türkiye global ölçekte üçüncü sırada yer almaktadır. Biber yetiştiriciliğinde üretimi sınırlayan zararlılar genellikle pestisit kullanımını gerekli kılmakta, bu durum pestisit kalıntıları ve gıda güvenliği ile ilgili endişelere yol açmaktadır. Bu çalışmada, 2022 yılında Türkiye'nin Tokat ilinde tarla koşullarında biberde lufenuron’un parçalanma davranışı araştırılmıştır. Analizler hızlı, kolay, ucuz, etkili, sağlam ve güvenilir bir yöntem olan QuEChERS tekniği ile sıvı kromatografisi-tandem kütle spektrometresi kullanılarak gerçekleştirilmiştir. Lufenuron için ortalama geri kazanım oranları %77 ile %97 arasında değişirken, bağıl standart sapma değeri %13 olarak kaydedilmiştir. Lufenuron kalıntıları, tek doz ve çift doz uygulamaları sonrasında, biberde birinci dereceden kinetik modele uygun olarak bozunmuş ve yarılanma ömrü Tokat’ta sırasıyla 4,33 ve 6,42 gün, Niksar’da ise 6,80 ve 7,45 gün olarak hesaplanmıştır. Ayrıca yapılan sağlık risk değerlendirmesi yapılmış ve lufenuron için akut ve kronik risk katsayı değerleri 1’den çok daha düşük olarak belirlenmiştir. Ayrıca yapılan sağlık risk değerlendirmesi sonucunda lufenuron için kronik risk katsayısının 1'den çok daha düşük olduğu görülmüştür. Elde edilen sonuçlara göre, önerilen dozlarda lufenuron kullanılmasının tüketiciler için herhangi bir sağlık riski oluşturmadığı ortaya konulmuştur.

Anahtar Kelimeler

• Kronik risk
• parçalanma kinetiği
• metot doğrulama
• QuEChERS
• pestisit kalıntısı

Investigation of the dissipation kinetics of lufenuron in pepper grown under field conditions

Abstract

Pepper, Capsicum annuum L. (Solanales: Solanaceae) production is widely cultivated worldwide, with Türkiye ranks third in global pepper production. However, pests in pepper cultivation often necessitate pesticide use, leading to concerns about pesticide residue levels and their potential impact on food safety. This study investigated the dissipation behavior of lufenuron in pepper under field conditions in Tokat, Türkiye in 2022. Liquid chromatography-tandem mass spectrometry coupled with the quick, easy, cheap, effective, rugged, and safe technique was used to analyze residues of lufenuron in pepper. The average recoveries varied from 77% to 97%, with relative standard deviations of 13% for lufenuron. Lufenuron residues administered as recommended dose and double dose degraded in pepper following a first-order kinetic model, with an estimated half-life (t1/2) of 4.33 and 6.42 days in Tokat, 6.80 and 7.45 days in Niksar, respectively. Furthermore, a health risk assessment was conducted, which showed that the chronic risk quotient for lufenuron was much lower than 1. The present results indicated that the health risks posed for consumers by the lufenuron residues were negligible at the recommended dosages.

Keywords

• Chronic risk
• degradation kinetics
• method verification
• QuEChERS
• pesticide residue

Kaynakça

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