BibTex RIS Kaynak Göster

İndigo boyar maddesi içeren atıksu renginin elektro-fenton prosesi ile giderimi

Yıl 2013, Cilt: 29 Sayı: 2, 129 - 134, 01.04.2013

Öz

Bu çalışmada biyolojik arıtıma dirençli olan indigo boyaması yapan tekstil endüstrisi atıksuyunda renk giderimi için elektro - Fenton yönteminin uygulaması gerçekleştirilmiştir. Bu atıksuda en iyi renk giderimini sağlamak amacıyla sistemde elektriksel akım uygulaması ile farklı pH seviyelerinde, değişen Fe +2 konsantrasyonlarında ve farklı H 2 O 2 dozajlarında deneyler gerçekleştirilmiştir. Farklı başlangıç pH seviyelerinde çalışılan deney serilerinde pH: 4 için elde edilen renk giderimi %100 olarak bulunmuştur. Ayrıca ortama ilave edilen H 2 O 2 dozajı optimize edilerek ve pH:4’de çözünen Fe +2 konsantrasyonuna göre Fe +2 : H 2 O 2 molar oranı 1: 73 olarak belirlenmiştir.

Kaynakça

  • Anotai, J., et al., Kinetics of aniline degradation by Fenton and electro-Fenton processes, Water Res. 40 (9), 1841–1847, 2006.
  • APHA, Standard Methods for the Examination of Water and Wastewater, American Public Health Association, Washington DC, 1995.
  • Brillas, E., et al., Aniline mineralization by AOP’s: anodic oxidation, photocatalysis, electro-Fenton and photoelectro-Fenton processes. Appl. Catal. B: Environ. 16 (1), 31–42, 1998.
  • Brillas, E., Casado, J., Aniline degradation by Electro-Fenton and peroxicoagulation processes using a flow reactor for wastewater treatment, Chemosphere 47, 241–248, 2002.
  • Brillas, E., et al., Electro-Fenton process and related electrochemical technologies based on Fenton’s reaction chemistry. Chem. Rev. 109 (12), 6570– , 2009.
  • Chung, K.T., et al., Mutagenicity testing of some commonly used dyes, Appl. Environ. Microbiol. 42, –648, 1981.
  • Correia, V.M., et al., Characterization of textile wastewaters-a review, Environ. Technol. 15, 917– , 1994.
  • Do, J.S., Chen, C.P., In situ oxidative degradation of formaldehyde peroxide. J. Electrochem. Soc. 140 (6), 1632–1637, electrogenerated hydrogen
  • Edgar J., et al., Mineralization of Acid Yellow 36 azo dye by electro-Fenton and solar photoelectro- Fenton processes with a boron-doped diamond anode, Chemosphere 82, 495–501, 2011.
  • El-Desoky, H.S., et al., Decolorizaiton and degradation of Ponceau S azo-dye in aqueous solutions by the electrochemical advanced Fenton oxidation, Desalination 264, 143-150, 2010.
  • Forgacs, E., et al., Decolorization of wastewaters: a review, Environ. Int. 30 953–971, 2004.
  • Fockedey, E., Van Lierde, A., Coupling of anodic and cathodic reactions for phenol electro-oxidation using three-dimensional electrodes,Water Res. 36, –4175, 2002.
  • Garrote, J.I., et al., Treatment of tannery effluent by a two step coagulation/floculation processe, Water Res. 29 2605–2608, 1995.
  • Ghoneim, M., et al., Electro-Fenton oxidation of Sunset Yellow FCF azo-dye in aqueous solutions, Desalination, 274, 22-30, 2011.
  • González, K. C., et al., Determination of optimum operating decolorization by electro-Fenton process using BDD cathode, Chemical Engineering Journal 160, 199– , 2010. for Acid Yellow
  • Haug, W., et al., Mineralization of the sulfonated azo aminonaphthalene- 2-sulfonate-degrading bacterial consortium, Appl. Environ. Microbiol. 57, 3144– , 1991. Yellow by a
  • Huang, Y-H., et al., Comparative study of oxidation of dye-Reactive Black B by different advanced oxidation processes: Fenton, electro-fenton and photo-fenton, J.Hazard. Mater. 154, 655-662, 2008.
  • Kudlich, M., Simultaneous anaerobic and aerobic degradation of the sulfonated azo dye Mordant Yellow 3 by immobilized cells from a naphthalenesulfonate-degrading Appl.Microbiol. Biotechnol. 46, 597–603, 1996.
  • Lahkimi, A.et al., Removal of textile dyes from water by the electro-Fenton process, Environ. Chem. Lett. 5, –39, 2007.
  • Lei, H., et al., Electro-Fenton degradation of cationic red X-GRL using an activated carbon fiber cathode, Process Safety and Environmental Protection 88, 431– , 2010.
  • Martínez-Huitle, C.A., Brillas, E., Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods: a general review. Appl. Catal. B: Environ. 87 (3–4), 105–145, 2009.
  • Oturan, M.A., et al., Hydroxylation of aromatic drugs by the electro-Fenton method. Formation and identification of the metabolites of Riluzole. New J. Chem. 23 (8), 793–794, 2009. Oturan, M.A., Pinson, J., Hydroxylation by
  • Electrochemically Generated Hydroxyl Radicals Mono and Polyhydroxylation of Benzoic Acid: Products And İsomers’distribution. J. Phys. Chem., 99: 13948- , 1995.
  • Pinheiro, H.M., et al., Aromatic amines from azo dye reduction: status review with emphasis on direct UV spectrophotometric detection in textile industry wastewaters, Dyes Pigment 61, 121–139, 2004.
  • Rosales, E., et al., Electro-fenton decoloration of dyes in a continuous reactor: A promising technology in colored wastewater treatment, Chemical Eng. J., 155, 67, 2009.
  • Solmaz, S.K.A., et al., Colour and COD removal from textile effluent by coagulation and advanced oxidation processes, Soc. Dyers Colorists Color. Technol. 122, –109, 2006.
  • Yuan, S., et al., Treatment of nitrophenols by cathode reduction and electro-Fenton methods. J. Hazard. Mater. 137 (1), 573–580, 2006.
  • Zhou, M., et al., Electro-Fenton method for the removal of methyl red in an efficient electrochemical system, Sep. Purif. Technol. 57, 380–387, 2007.

Color removal from ındigo dye containing wastewater by electro-fenton process

Yıl 2013, Cilt: 29 Sayı: 2, 129 - 134, 01.04.2013

Öz

In this study, electro - Fenton technique was applied for the removal of color from the textile wastewater contaminated with indigo dyes. To achieve the complete decolorization, a series of experiments were carried out at different initial pH and Fe +2 and H 2 O 2 concentrations . The complete decoloration for indigo dyes was obtained at pH 4. Additionally, Fe +2 : H 2 O 2 dosage was found to be 1: 73 by optimizing the H 2 O 2 dosage, considering the concentration of Fe +2 in the reactor

Kaynakça

  • Anotai, J., et al., Kinetics of aniline degradation by Fenton and electro-Fenton processes, Water Res. 40 (9), 1841–1847, 2006.
  • APHA, Standard Methods for the Examination of Water and Wastewater, American Public Health Association, Washington DC, 1995.
  • Brillas, E., et al., Aniline mineralization by AOP’s: anodic oxidation, photocatalysis, electro-Fenton and photoelectro-Fenton processes. Appl. Catal. B: Environ. 16 (1), 31–42, 1998.
  • Brillas, E., Casado, J., Aniline degradation by Electro-Fenton and peroxicoagulation processes using a flow reactor for wastewater treatment, Chemosphere 47, 241–248, 2002.
  • Brillas, E., et al., Electro-Fenton process and related electrochemical technologies based on Fenton’s reaction chemistry. Chem. Rev. 109 (12), 6570– , 2009.
  • Chung, K.T., et al., Mutagenicity testing of some commonly used dyes, Appl. Environ. Microbiol. 42, –648, 1981.
  • Correia, V.M., et al., Characterization of textile wastewaters-a review, Environ. Technol. 15, 917– , 1994.
  • Do, J.S., Chen, C.P., In situ oxidative degradation of formaldehyde peroxide. J. Electrochem. Soc. 140 (6), 1632–1637, electrogenerated hydrogen
  • Edgar J., et al., Mineralization of Acid Yellow 36 azo dye by electro-Fenton and solar photoelectro- Fenton processes with a boron-doped diamond anode, Chemosphere 82, 495–501, 2011.
  • El-Desoky, H.S., et al., Decolorizaiton and degradation of Ponceau S azo-dye in aqueous solutions by the electrochemical advanced Fenton oxidation, Desalination 264, 143-150, 2010.
  • Forgacs, E., et al., Decolorization of wastewaters: a review, Environ. Int. 30 953–971, 2004.
  • Fockedey, E., Van Lierde, A., Coupling of anodic and cathodic reactions for phenol electro-oxidation using three-dimensional electrodes,Water Res. 36, –4175, 2002.
  • Garrote, J.I., et al., Treatment of tannery effluent by a two step coagulation/floculation processe, Water Res. 29 2605–2608, 1995.
  • Ghoneim, M., et al., Electro-Fenton oxidation of Sunset Yellow FCF azo-dye in aqueous solutions, Desalination, 274, 22-30, 2011.
  • González, K. C., et al., Determination of optimum operating decolorization by electro-Fenton process using BDD cathode, Chemical Engineering Journal 160, 199– , 2010. for Acid Yellow
  • Haug, W., et al., Mineralization of the sulfonated azo aminonaphthalene- 2-sulfonate-degrading bacterial consortium, Appl. Environ. Microbiol. 57, 3144– , 1991. Yellow by a
  • Huang, Y-H., et al., Comparative study of oxidation of dye-Reactive Black B by different advanced oxidation processes: Fenton, electro-fenton and photo-fenton, J.Hazard. Mater. 154, 655-662, 2008.
  • Kudlich, M., Simultaneous anaerobic and aerobic degradation of the sulfonated azo dye Mordant Yellow 3 by immobilized cells from a naphthalenesulfonate-degrading Appl.Microbiol. Biotechnol. 46, 597–603, 1996.
  • Lahkimi, A.et al., Removal of textile dyes from water by the electro-Fenton process, Environ. Chem. Lett. 5, –39, 2007.
  • Lei, H., et al., Electro-Fenton degradation of cationic red X-GRL using an activated carbon fiber cathode, Process Safety and Environmental Protection 88, 431– , 2010.
  • Martínez-Huitle, C.A., Brillas, E., Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods: a general review. Appl. Catal. B: Environ. 87 (3–4), 105–145, 2009.
  • Oturan, M.A., et al., Hydroxylation of aromatic drugs by the electro-Fenton method. Formation and identification of the metabolites of Riluzole. New J. Chem. 23 (8), 793–794, 2009. Oturan, M.A., Pinson, J., Hydroxylation by
  • Electrochemically Generated Hydroxyl Radicals Mono and Polyhydroxylation of Benzoic Acid: Products And İsomers’distribution. J. Phys. Chem., 99: 13948- , 1995.
  • Pinheiro, H.M., et al., Aromatic amines from azo dye reduction: status review with emphasis on direct UV spectrophotometric detection in textile industry wastewaters, Dyes Pigment 61, 121–139, 2004.
  • Rosales, E., et al., Electro-fenton decoloration of dyes in a continuous reactor: A promising technology in colored wastewater treatment, Chemical Eng. J., 155, 67, 2009.
  • Solmaz, S.K.A., et al., Colour and COD removal from textile effluent by coagulation and advanced oxidation processes, Soc. Dyers Colorists Color. Technol. 122, –109, 2006.
  • Yuan, S., et al., Treatment of nitrophenols by cathode reduction and electro-Fenton methods. J. Hazard. Mater. 137 (1), 573–580, 2006.
  • Zhou, M., et al., Electro-Fenton method for the removal of methyl red in an efficient electrochemical system, Sep. Purif. Technol. 57, 380–387, 2007.
Toplam 28 adet kaynakça vardır.

Ayrıntılar

Diğer ID JA79SH85BZ
Bölüm Makaleler
Yazarlar

Yusuf Saatçi Bu kişi benim

Özge Hanay Bu kişi benim

Yayımlanma Tarihi 1 Nisan 2013
Yayımlandığı Sayı Yıl 2013 Cilt: 29 Sayı: 2

Kaynak Göster

APA Saatçi, Y., & Hanay, Ö. (2013). İndigo boyar maddesi içeren atıksu renginin elektro-fenton prosesi ile giderimi. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi, 29(2), 129-134.
AMA Saatçi Y, Hanay Ö. İndigo boyar maddesi içeren atıksu renginin elektro-fenton prosesi ile giderimi. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi. Nisan 2013;29(2):129-134.
Chicago Saatçi, Yusuf, ve Özge Hanay. “İndigo Boyar Maddesi içeren atıksu Renginin Elektro-Fenton Prosesi Ile Giderimi”. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi 29, sy. 2 (Nisan 2013): 129-34.
EndNote Saatçi Y, Hanay Ö (01 Nisan 2013) İndigo boyar maddesi içeren atıksu renginin elektro-fenton prosesi ile giderimi. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi 29 2 129–134.
IEEE Y. Saatçi ve Ö. Hanay, “İndigo boyar maddesi içeren atıksu renginin elektro-fenton prosesi ile giderimi”, Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi, c. 29, sy. 2, ss. 129–134, 2013.
ISNAD Saatçi, Yusuf - Hanay, Özge. “İndigo Boyar Maddesi içeren atıksu Renginin Elektro-Fenton Prosesi Ile Giderimi”. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi 29/2 (Nisan 2013), 129-134.
JAMA Saatçi Y, Hanay Ö. İndigo boyar maddesi içeren atıksu renginin elektro-fenton prosesi ile giderimi. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi. 2013;29:129–134.
MLA Saatçi, Yusuf ve Özge Hanay. “İndigo Boyar Maddesi içeren atıksu Renginin Elektro-Fenton Prosesi Ile Giderimi”. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi, c. 29, sy. 2, 2013, ss. 129-34.
Vancouver Saatçi Y, Hanay Ö. İndigo boyar maddesi içeren atıksu renginin elektro-fenton prosesi ile giderimi. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi. 2013;29(2):129-34.

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