Magnetic Properties of Borided Co-Cr-Mo Alloy

Öz

The magnetic properties of a borided Co-Cr-Mo alloy were studied in this work. The boron process was performed by the powder pack method with Ekabor HM and Ekabor III boron sources at 1123 and 1323 K for 9 h. The magnetic properties were characterized with a vibrating sample magnetometer (VSM). The results show that the non-magnetic Co-Cr-Mo alloy has a low magnetization with the boriding process. In addition, the saturation magnetization (Ms) varies with the boron source and temperature.

Anahtar Kelimeler

• Co-Cr-Mo alloy
• saturation magnetization
• magnetic behavior
• boriding
• boron source

Kaynakça

1. [1] Ozturk, O., Turkan, U and Eroglu, A., (2006) Metal ion release from nitrogen ion implanted CoCrMo orthopedic implant material, Surface and Coatings Technology, 200, 5687–5697.
2. [2] Duan, J., Yang, Y., Zhang, E and Wang, H., (2020) Co-Cr-Mo-Cu alloys for clinical implants with osteogenic effect by increasing bone induction, formation and development in a rabbit model, Burns Trauma, 8, tkaa036.
3. [3] Bahçe, E., Aslan A. K., Çakır, N and Güler, M. S., (2019)., Investigation of the Surface Properties TaN Based Thin Film Coatings on the CoCrMo Alloy, The Black Sea Journal of Sciences, 9, 223-237.
4. [4] Cuao-Moreu, C. A., Hernández-Sanchéz, E., Alvarez-Vera, M., Garcia-Sanchez, E. O., Perez-Unzueta, A and Hernandez-Rodriguez, M. A. L., (2019) Tribological behavior of borided surface on CoCrMo cast alloy, Wear, 426–427, 204–211.
5. [5] Delgado-Brito, A. M., Mejía-Caballero, I., AContla-Pacheco, A. D., Pérez Pasten-Borja, R., Castrejón-Sánchez, V. H., Hernández-Ramírez, E. J and Campos-Silva, I., (2024) Bio-tribocorrosion resistance of CoB–Co2B and Co2B layers on CoCrMo alloy, Journal of Vacuum Science and Technology A 42, 023106.
6. [6] Tsai, C.-Y., Tseng, L.-W., Tzeng, Y.-C and Lee, P.-Y., (2022) Magnetic Properties of FeNiCoAlTiNb Shape Memory Alloys, Crystals, 12,121.
7. [7] Kazantseva, N. V., Davydov, D. I., Terent’ev, P. B., Shishkin, D. A., Demakov, S. L., Yurovskikh, A. S and Romanov, E. P., (2017) Mechanical and Magnetic Properties of Alloys near the Concentration Range of the Existence of Co3(Al,W) Intermetallic Compound, Physics of Metals and Metallography, 118, 432–438.
8. [8] Mustapić, M., Pajić, D., Novosel, N., Babić, E., Zadro, K., Cindrić, M., Horvat, J., Skoko, Z., Bijelić, M and Shcherbakov, A., (2010) Synthesis, Structural Characterization and Magnetic Properties of Iron Boride Nanoparticles with or without Silicon Dioxide Coating, Croatica Chemica Acta, 83, 275–282.

9. [9] Akkurt, I., Calik, A and Akyildirım, H., (2011) The boronizing effect on the radiation shielding and magnetization properties of AISI 316L austenitic stainless steel, Nuclear Engineering and Design, 241, 55-58.
10. [10] Ekinci, C., (2021) Investigation of magnetic and some mechanical properties of borided Fe-Ni alloys, PhD thesis, Süleyman Demirel University, Turkey.
11. [11] Ono, Y., (2010) Co-Cr-Mo alloy fine wire, manufacturing method therefor, and planar body, tubular body, stranded wire and cable formed of wire, NHK Spring Co., Ltd. United States Patent.
12. [12] Ucar, N., Gülüstan, C and Calik, A., (2021) Microstructural Characterization of Borided Co-Cr-Mo Alloy, Advences in materials Science, 21, 90-98.
13. [13] Khitouni, N., Hammami, B., Llorca-Isern, N., Mbarek, W. B., Suñol, J. J and Khitouni,M., (2022) Microstructure and Magnetic Properties of Nanocrystalline Fe60-xCo25Ni15Six Alloy Elaborated by High-Energy Mechanical Milling, Materials,15, 6483.
14. [14] Matthew, A and . Willard, M. D., (2013) Nanocrystalline Soft Magnetic Alloys Two Decades of Progress, Handbook of Magnetic Materials, 21, 173-342.
15. [15] Kulkarni, R., Murty, B.S and Srinivas, V., (2018) Study of microstructure and magnetic properties of AlNiCo(CuFe) high entropy alloy. Journal of Alloys and Compounds, 746, 194–199.
16. [16] Kartal, L., (2023) Cobalt Boride (Co2 B) Particle Synthesis by One-step Carbothermic Reduction, Hittite Journal of Science and Engineering, 10, 229–235.
17. [17] Ortiz-Domínguez, M., Flores-Rentería, M. A., Keddam, M., Elias-Espinosa, M., Damián-Mejía, O., Aldana-González, J. I., Zuno-Silva, J., Medina-Moreno, S. A and González-Reyes, J. G., (2014) Simulatıon of growth kınetıcs of fe2b layers formed on gray cast ıron durıng the powder-pack borıdıng, Materiali in tehnologije/Materials and technology 48, 905–916.
18. [18] Dzyadykevich, Y. V and Zablotskaya, N. I., (1992) Influence of Copper on the Phase Formation Process in Borosilicide Layers on Niobium and Tantalum, Soviet Powder metallurgy andmetal Ceramics, 31,129-133.
19. [19] Fojtikova, Z. P. J., Koubsky, T., Musalek, R., Strasky, J., Capek, J., Kyncl, J., Beranek, L and Kolarik, K., (2015) Study of residual stresses, microstructure, and hardness in FeB and Fe2B ultra-hard layers, Powder Diffraction, 30, 83-89.
20. [20] Luo, H., Meng, F., Jiang, Q., Liu, H., Liu, E., Wu, G and Wang, Y., (2010) Effect of boron on the martensitic transformation and magnetic properties of Ni50Mn36.5Sb13.5_xBx alloys, Scripta Materialia, 63, 569–572.