Fonksiyonel İnce Film Kaplı 3B Yüzeylerin Sis Toplama Performansının İncelenmesi
Yıl 2026,
Cilt: 19 Sayı: 1
,
253
-
267
,
30.03.2026
Meryem Coplan
,
Kurtuluş Yılmaz
,
Emine Sevgili Mercan
,
Mehmet Gürsoy
,
Mustafa Karaman
Öz
Temiz suya erişim, doğal tatlı su kaynaklarının tükenmesi, küresel ısınma ve artan dünya nüfusu gibi etkenler nedeniyle, günümüzde karşılaşılan en önemli küresel sorunlardan biridir. Temiz su üretimi için genellikle ters ozmoz ve tuzdan arındırma yöntemleri kullanılmaktadır; ancak bu yöntemler yüksek yatırım ve enerji maliyetlerine sahiptir ve bu durum yaygın kullanımını sınırlamaktadır. Son yıllarda, atmosferik su toplama yöntemi olarak sis kullanımı, enerji verimli, düşük maliyetli ve çevre dostu bir alternatif yöntem olarak öne çıkmaktadır. Ancak, geleneksel sis toplama ağlarının verimliliği düşüktür ve bu durum, daha yüksek verimle sis toplayabilen malzemelerin geliştirilmesine olan ilgiyi artırmıştır. Bu çalışmada, çeşitli topografik yapılara sahip yüzeyler 3D baskı ile üretilmiş ve çevre dostu bir yöntem olan plazma destekli kimyasal buhar biriktirme (PECVD) tekniği kullanılarak, tek adımda hidrofilik poliakrilik asit (PAA) ve hidrofobik poliheksaflorobütil akrilat (PHFBA) ince filmlerle kaplanmıştır. Ayrıca, hem hidrofilik hem de hidrofobik özellikler gösteren yüzeyler tasarlanıp üretilmiştir. Kaplanmış yüzeylerin kimyasal yapısı, topografik özellikleri ve ıslanabilirlik karakteristikleri kapsamlı bir şekilde karakterize edilmiştir. Farklı yüzey yapıları ve ıslanabilirlik özelliklerine sahip toplam 22 örnek üretilmiştir. Sis toplama deneyleri, kontrol yüzeyle karşılaştırıldığında, geliştirilen yüzey tasarımlarının sis toplama veriminde %270'e varan artış sağladığını ortaya koymuştur. Elde edilen sonuçlar, yüzey topografyası ve ıslanabilirliğin sis toplama performansını etkileyen temel faktörler olduğunu göstermektedir.
Kaynakça
-
[1] Lim, Y. J., Goh, K., Kurihara, M., & Wang, R. (2021). Seawater desalination by reverse osmosis: Current development and future challenges in membrane fabrication – A review, Journal of Membrane Science, 629, 119292.
-
[2] Voutchkov, N., (2018). Energy use for membrane seawater desalination – current status and trends. Desalination, 431, 2–14.
-
[3] Li, W., Liu, G., Kong, W., & Jia, H. (2025). Desert Beetle-Like Superhydrophobic/Superhydrophilic TiO2 –Nanoparticle Patterned Fabric Surface for Fog Harvesting. ACS Applied Nano Materials, 8(6), 2753–2762.
-
[4] Wang, Q., Tian, G., Zhang, H., He, Y., & Guo, Z. (2025). Hyperphilic/hydrophobic hybridized surfaces for efficient fog harvesting. Journal of Materials Chemistry A, 13(18), 13391–13401.
-
[5] Hou, L.-L., Qiu, M.-N., Wang, Y.-Q., Bai, T.-H., Cui, Z.-M., Liu, J.-C., … Zhao, Y. (2024). Bioinspired Double-stranded Yarn with Alternating Hydrophobic/Hydrophilic Patterns for High-efficiency Fog Collection. Chinese Journal of Polymer Science, 42(7), 968–975.
-
[6] Li, M., Xie, S., Tian, G., Chen, G., & Guo, Z. (2024). Biomimetic Leaf-Shaped Wedge Structure with Mixed Wettability for Fog Harvesting. ACS Applied Materials & Interfaces, 16(32), 42931–42941. https://doi.org/10.1021/acsami.4c08254
-
[7] Wang, J., Guo, Y., Pan, G., Li, Y., Zhang, Y., Yu, H., … Liu, Y. (2022). Hybrid wettability surfaces with hydrophobicity and hydrophilicity for fog harvesting. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 650, 129555. https://doi.org/10.1016/j.colsurfa.2022.129555
-
[8] Zhang, J., Zhang, Y., Yong, J., Hou, X., & Chen, F. (2022). Femtosecond laser direct weaving bioinspired superhydrophobic/hydrophilic micro-pattern for fog harvesting. Optics & Laser Technology, 146, 107593.
-
[9] Chakrapani Gunarasan, J. P., & Lee, J.-W. (2024). Active Surface Area-Dependent Water Harvesting of Desert Beetle-Inspired Hybrid Wetting Surfaces. Langmuir, 40(10), 5499–5507.
-
[10] Showket, J., Majumder, S., Kumar, N., Sett, S., & Mahapatra, P. S. (2024). Fog harvesting on micro-structured metal meshes: Effect of surface ageing. Micro and Nano Engineering, 22, 100236.
-
[11] Peng, Z., Fu, Y., & Guo, Z. (2023). Origami-like 3D Fog Water Harvestor with Hybrid Wettability for Efficient Fog Harvesting. ACS Applied Materials & Interfaces, 15(31), 38110–38123.
-
[12] Sun, H., Song, Y., Zhang, B., Huan, Y., Jiang, C., Liu, H., … Wang, H. (2021). Bioinspired micro- and nanostructures used for fog harvesting. Applied Physics A, 127(6), 461.
-
[13] Kennedy, B. S., & Boreyko, J. B. (2024). Bio‐Inspired Fog Harvesting Meshes: A Review. Advanced Functional Materials, 34(35).
-
[14] Gürsoy, M., Uçar, T., Tosun, Z., & Karaman, M. (2016). Initiation of 2‐Hydroxyethyl Methacrylate Polymerization by Tert‐Butyl Peroxide in a Planar PECVD System. Plasma Processes and Polymers, 13(4), 438–446.
-
[15] Lin-Vien, D., Colthup, N. B., Fateley, W. G., & Grasselli, J. G. (1991). The handbook of infrared and Raman characteristic frequencies of organic molecules. Elsevier.
-
[16] Yılmaz, K., Gürsoy, M., & Karaman, M. (2021). Vapor Deposition of Transparent Antifogging Polymeric Nanocoatings. Langmuir, 37(5), 1941–1947.
-
[17] Zhang, Y., Yan, Y., Wang, Y., Li, Y., Wang, X., Zhang, H., … Wang, F. (2013). The synthesis and solution properties of hyperbranched polyglycerols modified with hexafluorobutyl acrylate. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 436, 563–569.
-
[18] Gürsoy, M., & Karaman, M. (2016). Hydrophobic coating of expanded perlite particles by plasma polymerization. Chemical Engineering Journal, 284.
-
[19] Badyal, J. P. (2001). Beyond the surface-Cold plasmas are streamlining the surface coatings industry. Chemistry in Britain, 37(1), 45–46.
-
[20] Gürsoy, M. (2020). Fabrication of Poly(N-isopropylacrylamide) with Higher Deposition Rate and Easier Phase Transition by Initiated Plasma Enhanced Chemical Vapor Deposition. Plasma Chemistry and Plasma Processing, 40(4).
-
[21] Truica‐Marasescu, F., Jedrzejowski, P., & Wertheimer, M. R. (2004). Hydrophobic Recovery of Vacuum Ultraviolet Irradiated Polyolefin Surfaces. Plasma Processes and Polymers, 1(2), 153–163.
-
[22] Vasudev, M. C., Anderson, K. D., Bunning, T. J., Tsukruk, V. V., & Naik, R. R. (2013). Exploration of Plasma-Enhanced Chemical Vapor Deposition as a Method for Thin-Film Fabrication with Biological Applications. ACS Applied Materials & Interfaces, 5(10), 3983–3994.
-
[23] Rupper, P., Vandenbossche, M., Bernard, L., Hegemann, D., & Heuberger, M. (2017). Composition and Stability of Plasma Polymer Films Exhibiting Vertical Chemical Gradients. Langmuir, 33(9), 2340–2352.
-
[24] Abessolo Ondo, D., Loyer, F., Werner, F., Leturcq, R., Dale, P. J., & Boscher, N. D. (2019). Atmospheric-Pressure Synthesis of Atomically Smooth, Conformal, and Ultrathin Low- k Polymer Insulating Layers by Plasma-Initiated Chemical Vapor Deposition. ACS Applied Polymer Materials, 1(12), 3304–3312.
-
[25] Zhao, Y., Huo, N., Ye, S., & Tenhaeff, W. E. (2023). Elastic broadband antireflection coatings for flexible optics using multi-layered polymer thin films. Journal of Materials Chemistry C, 11(12), 4005–4016.
-
[26] Ozden, S., Ge, L., Narayanan, T. N., Hart, A. H. C., Yang, H., Sridhar, S., … Ajayan, P. M. (2014). Anisotropically Functionalized Carbon Nanotube Array Based Hygroscopic Scaffolds. ACS Applied Materials & Interfaces, 6(13), 10608–10613.
-
[27] Bai, H., Wang, L., Ju, J., Sun, R., Zheng, Y., & Jiang, L. (2014). Efficient Water Collection on Integrative Bioinspired Surfaces with Star‐Shaped Wettability Patterns. Advanced Materials, 26(29), 5025–5030.
-
[28] Gürsoy, M. (2020). All-dry patterning method to fabricate hydrophilic/hydrophobic surface for fog harvesting. Colloid and Polymer Science.
-
[29] Gürsoy, M., & Kocadayıoğulları, B. (2023). Environmentally Friendly Approach for the Plasma Surface Modification of Fabrics for Improved Fog Harvesting Performance. Fibers and Polymers, 24(10), 3557–3567.
-
[30] Reed, R., Godfrey, S., Kayaga, S., Reed, B., Rouse, J., Fisher, J., … Odhiambo, F. (2013). Technical notes on drinking-water, sanitation and hygiene in emergencies. Loughborough University.
Investigation of Fog Harvesting Performance of Functional Thin Film-Coated 3D Surfaces
Yıl 2026,
Cilt: 19 Sayı: 1
,
253
-
267
,
30.03.2026
Meryem Coplan
,
Kurtuluş Yılmaz
,
Emine Sevgili Mercan
,
Mehmet Gürsoy
,
Mustafa Karaman
Öz
Access to clean water is one of the major global challenges due to the depletion of natural freshwater reserves, exacerbated by global warming and increasing world population. Reverse osmosis and desalination methods are commonly used for clean water production; however, these methods have high investment and energy costs, limiting their widespread application. In recent years, atmospheric water collection, using fog, has emerged as an energy-efficient, low-cost, and environmentally friendly alternative method. However, traditional fog harvesting nets have low efficiency, prompting increasing interest in developing materials that can collect fog at higher yields. In this study, 3D printing was used to create surfaces with various topographies, which were then coated with hydrophilic polyacrylic acid (PAA) and hydrophobic polyhexafluorobutyl acrylate (PHFBA) thin films in a single step, utilizing the environmentally friendly plasma enhanced chemical vapor deposition (PECVD) technique. Additionally, surfaces exhibiting both hydrophilic and hydrophobic properties were designed and fabricated. The chemical structure, topographical features, and wettability characteristics of the coated surfaces were thoroughly characterized. A total of 22 samples with different surface structures and wettability properties were produced. Fog harvesting experiments revealed that, compared to the control surface, the surface designs achieved up to a 270% increase in fog harvesting efficiency. The results demonstrate that surface topography and wettability are key factors influencing fog harvesting performance.
Etik Beyan
There are no ethical issues regarding the publication of this study.
Teşekkür
This study was supported by the Konya Technical University Scientific Research Foundation with a project number of 232216033.
Kaynakça
-
[1] Lim, Y. J., Goh, K., Kurihara, M., & Wang, R. (2021). Seawater desalination by reverse osmosis: Current development and future challenges in membrane fabrication – A review, Journal of Membrane Science, 629, 119292.
-
[2] Voutchkov, N., (2018). Energy use for membrane seawater desalination – current status and trends. Desalination, 431, 2–14.
-
[3] Li, W., Liu, G., Kong, W., & Jia, H. (2025). Desert Beetle-Like Superhydrophobic/Superhydrophilic TiO2 –Nanoparticle Patterned Fabric Surface for Fog Harvesting. ACS Applied Nano Materials, 8(6), 2753–2762.
-
[4] Wang, Q., Tian, G., Zhang, H., He, Y., & Guo, Z. (2025). Hyperphilic/hydrophobic hybridized surfaces for efficient fog harvesting. Journal of Materials Chemistry A, 13(18), 13391–13401.
-
[5] Hou, L.-L., Qiu, M.-N., Wang, Y.-Q., Bai, T.-H., Cui, Z.-M., Liu, J.-C., … Zhao, Y. (2024). Bioinspired Double-stranded Yarn with Alternating Hydrophobic/Hydrophilic Patterns for High-efficiency Fog Collection. Chinese Journal of Polymer Science, 42(7), 968–975.
-
[6] Li, M., Xie, S., Tian, G., Chen, G., & Guo, Z. (2024). Biomimetic Leaf-Shaped Wedge Structure with Mixed Wettability for Fog Harvesting. ACS Applied Materials & Interfaces, 16(32), 42931–42941. https://doi.org/10.1021/acsami.4c08254
-
[7] Wang, J., Guo, Y., Pan, G., Li, Y., Zhang, Y., Yu, H., … Liu, Y. (2022). Hybrid wettability surfaces with hydrophobicity and hydrophilicity for fog harvesting. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 650, 129555. https://doi.org/10.1016/j.colsurfa.2022.129555
-
[8] Zhang, J., Zhang, Y., Yong, J., Hou, X., & Chen, F. (2022). Femtosecond laser direct weaving bioinspired superhydrophobic/hydrophilic micro-pattern for fog harvesting. Optics & Laser Technology, 146, 107593.
-
[9] Chakrapani Gunarasan, J. P., & Lee, J.-W. (2024). Active Surface Area-Dependent Water Harvesting of Desert Beetle-Inspired Hybrid Wetting Surfaces. Langmuir, 40(10), 5499–5507.
-
[10] Showket, J., Majumder, S., Kumar, N., Sett, S., & Mahapatra, P. S. (2024). Fog harvesting on micro-structured metal meshes: Effect of surface ageing. Micro and Nano Engineering, 22, 100236.
-
[11] Peng, Z., Fu, Y., & Guo, Z. (2023). Origami-like 3D Fog Water Harvestor with Hybrid Wettability for Efficient Fog Harvesting. ACS Applied Materials & Interfaces, 15(31), 38110–38123.
-
[12] Sun, H., Song, Y., Zhang, B., Huan, Y., Jiang, C., Liu, H., … Wang, H. (2021). Bioinspired micro- and nanostructures used for fog harvesting. Applied Physics A, 127(6), 461.
-
[13] Kennedy, B. S., & Boreyko, J. B. (2024). Bio‐Inspired Fog Harvesting Meshes: A Review. Advanced Functional Materials, 34(35).
-
[14] Gürsoy, M., Uçar, T., Tosun, Z., & Karaman, M. (2016). Initiation of 2‐Hydroxyethyl Methacrylate Polymerization by Tert‐Butyl Peroxide in a Planar PECVD System. Plasma Processes and Polymers, 13(4), 438–446.
-
[15] Lin-Vien, D., Colthup, N. B., Fateley, W. G., & Grasselli, J. G. (1991). The handbook of infrared and Raman characteristic frequencies of organic molecules. Elsevier.
-
[16] Yılmaz, K., Gürsoy, M., & Karaman, M. (2021). Vapor Deposition of Transparent Antifogging Polymeric Nanocoatings. Langmuir, 37(5), 1941–1947.
-
[17] Zhang, Y., Yan, Y., Wang, Y., Li, Y., Wang, X., Zhang, H., … Wang, F. (2013). The synthesis and solution properties of hyperbranched polyglycerols modified with hexafluorobutyl acrylate. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 436, 563–569.
-
[18] Gürsoy, M., & Karaman, M. (2016). Hydrophobic coating of expanded perlite particles by plasma polymerization. Chemical Engineering Journal, 284.
-
[19] Badyal, J. P. (2001). Beyond the surface-Cold plasmas are streamlining the surface coatings industry. Chemistry in Britain, 37(1), 45–46.
-
[20] Gürsoy, M. (2020). Fabrication of Poly(N-isopropylacrylamide) with Higher Deposition Rate and Easier Phase Transition by Initiated Plasma Enhanced Chemical Vapor Deposition. Plasma Chemistry and Plasma Processing, 40(4).
-
[21] Truica‐Marasescu, F., Jedrzejowski, P., & Wertheimer, M. R. (2004). Hydrophobic Recovery of Vacuum Ultraviolet Irradiated Polyolefin Surfaces. Plasma Processes and Polymers, 1(2), 153–163.
-
[22] Vasudev, M. C., Anderson, K. D., Bunning, T. J., Tsukruk, V. V., & Naik, R. R. (2013). Exploration of Plasma-Enhanced Chemical Vapor Deposition as a Method for Thin-Film Fabrication with Biological Applications. ACS Applied Materials & Interfaces, 5(10), 3983–3994.
-
[23] Rupper, P., Vandenbossche, M., Bernard, L., Hegemann, D., & Heuberger, M. (2017). Composition and Stability of Plasma Polymer Films Exhibiting Vertical Chemical Gradients. Langmuir, 33(9), 2340–2352.
-
[24] Abessolo Ondo, D., Loyer, F., Werner, F., Leturcq, R., Dale, P. J., & Boscher, N. D. (2019). Atmospheric-Pressure Synthesis of Atomically Smooth, Conformal, and Ultrathin Low- k Polymer Insulating Layers by Plasma-Initiated Chemical Vapor Deposition. ACS Applied Polymer Materials, 1(12), 3304–3312.
-
[25] Zhao, Y., Huo, N., Ye, S., & Tenhaeff, W. E. (2023). Elastic broadband antireflection coatings for flexible optics using multi-layered polymer thin films. Journal of Materials Chemistry C, 11(12), 4005–4016.
-
[26] Ozden, S., Ge, L., Narayanan, T. N., Hart, A. H. C., Yang, H., Sridhar, S., … Ajayan, P. M. (2014). Anisotropically Functionalized Carbon Nanotube Array Based Hygroscopic Scaffolds. ACS Applied Materials & Interfaces, 6(13), 10608–10613.
-
[27] Bai, H., Wang, L., Ju, J., Sun, R., Zheng, Y., & Jiang, L. (2014). Efficient Water Collection on Integrative Bioinspired Surfaces with Star‐Shaped Wettability Patterns. Advanced Materials, 26(29), 5025–5030.
-
[28] Gürsoy, M. (2020). All-dry patterning method to fabricate hydrophilic/hydrophobic surface for fog harvesting. Colloid and Polymer Science.
-
[29] Gürsoy, M., & Kocadayıoğulları, B. (2023). Environmentally Friendly Approach for the Plasma Surface Modification of Fabrics for Improved Fog Harvesting Performance. Fibers and Polymers, 24(10), 3557–3567.
-
[30] Reed, R., Godfrey, S., Kayaga, S., Reed, B., Rouse, J., Fisher, J., … Odhiambo, F. (2013). Technical notes on drinking-water, sanitation and hygiene in emergencies. Loughborough University.