Adsorption Behavior of Methylene Blue Dye Using Carob Powder as Eco-Friendly New Adsorbent For Cleaning Wastewater: Optimization By Response Surface Methodology

Öz

The use of cheap, efficient and environmentally friendly adsorbents has served as an alternative source of carob in order to remove dye-stuffs from waste water. This study has researched the potential use of carob powder as alternative adsorbent for the removal of methylene blue from wastewater. Experiment parameters pH, ultrasonic frequency, particle size, contact time, temperature and initial concentration of dissolved methylene blue (MB) dye were investigated. Thereafter, Box-Behnken design experiment was applied the adsorption experiments. The equilibrium time was 267.63min for methelene blue dye. The results showed that physisorption seemed to play a major role in the adsorption process.  The adsorption process of methylene blue on carob powder was found to rate of adsorption decreases with increasing temperature and the process exothermic. Regression analysis results demonstrated that is good for the experimental data to the non-linear model with correlation coefficients of (R²) value of 0.8899 and 0.9830. The maximum adsorption value was determined as 256,4355 mg/g. This result appears to be important when compared with other studies reported in the literature. According to the results of the study was observed carob bean can be used as an alternative adsorbent. 

Anahtar Kelimeler

• Adsorption,Box-Behnken Design,Carob powder,Methylene Blue,Ultrasound –Assisted

Atık Suyunun Temizlenmesi İçin Çevre Dostu Yeni Adsorbent Olarak KeçiboynuzuTozunun Kullanılarak Metilen Mavi Boyasının Adsorpsiyon Davranışı: Tepki Yüzey Metodolojisiyle Optimizasyon

Öz

Ucuz, verimli ve çevre dostu adsorbanların kullanımı, atık sudan boya maddelerini çıkarmak için alternatif bir keçiboynuzu kaynağı olarak hizmet etmiştir. Bu çalışma, atık sudan metilen mavisi çıkarılması için alternatif bir adsorban olarak keçiboynuzu tozunun potansiyel kullanımını araştırmıştır. Deney parametreleri pH, ultrasonik frekans, partikül boyutu, temas süresi, sıcaklık ve çözünmüş metilen mavisi (MB) boyasının başlangıç konsantrasyonu incelenmiştir. Daha sonra, Box-Behnken tasarım deneyi adsorpsiyon deneylerine uygulandı. Denge zamanı, metali mavi boya için 267.63 dk. Sonuçlar, fiziksel adsorpsiyon sürecinde önemli bir rol oynadığını gösterdi. Metilen mavisinin keçiboynuzu tozu üzerindeki adsorpsiyon sürecinin, artan sıcaklık ve ekzotermik proses ile adsorpsiyon oranlarında azalma olduğu bulunmuştur. Regresyon analizi sonuçları, deneysel veriler için doğrusal olmayan modele (R2) 0.8899 ve 0.9830 arasındaki korelasyon katsayıları için iyi olduğunu göstermiştir. Maksimum adsorpsiyon değeri 256.4355 mg/g olarak belirlendi. Bu sonuç literatürde bildirilen diğer çalışmalarla karşılaştırıldığında önemli olduğu görülmüştür. Çalışmanın sonuçlarına göre, keçiboynuzu tozunun alternatif bir adsorban olarak kullanılabileceği gözlenmiştir.

Anahtar Kelimeler

• Adsorbsiyon,Box-Behnken tasarım,Keçiboynuzu tozu,Metilen mavisi,Ultrases banyo

Kaynakça

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