Poli[2 – (p – Brom Fenil) 1,3 – Dioksalan – 4 – il] Metil Akrilat Kopolimerlerinin Sentezi, Karakterizasyonu,ve Fiziksel Özelliklerinin İncelenmesi

Yıl 2017, Cilt: 10 Sayı: 1, 23 - 37, 28.06.2017

Zülfiye İlter , Ferhat Alhanlı Serpil Yılmaz

Öz

Bu çalışmada öncelikle [2 – (p – brom
fenil)  1,3 – dioksalan  – 4 – il] metil akrilat monomeri (PBPhDMA)
sentezlendi. Sentezlenen monomer serbest radikalik yoldan polimerleştirildi.
Monomerin, Akrilonitril (AN) ve Stiren (St) ile kopolimerleri elde edildi.
Sentezlenen bütün yapılar FT-IR, ¹H-NMR teknikleri ile karakterize
edildi. Polimerlerin camsı geçiş sıcaklıkları DSC, termal kararlılıkları TGA
ile araştırıldı. Polimerlerin molekül ağırlıkları GPC ile belirlendi. Poli
(PBPhDMA – ko – AN)kopolimerine ait reaktivite oranları Kelen-Tudos ve Fineman
–Ross Yöntemleri kullanılarak bulundu.

Anahtar Kelimeler

Poli, 2 – (p – brom fenil) 1, 3 – dioksalan – 4 – il, metil akrilat, Reaktivite oranları

Synthesis, Characterization and Physical Properties of Poly [2- (p-Bromophenyl) 1,3-Dioxalane-4-yl] Methyl Acrylate Copolymers

Öz

In this work, Poly [2 – (p – bromophenyl) 
1,3 – dioxolane  – 4 – yl] methyl
acrylate(PBPhDMA) was first synthesized. The synthesized monomer was
polimerized by free radicalic polimerization. Copolymers of monomers,
acrylonitrile (AN) and styrene (St) were prepared. All the structures
synthesized were caharacterized by FT-IR, and ¹H-NMR
techniques.Thermal behaviors of polymers and glass transition temparatures were
measured by DSC and TGA. The polymers of average molecular weights were
measured by GPC. Poly (PBPhDMA – co – AN) reactivity ratios were calculated
according to the general copolymerization equation using Kelen-Tüdõs and
Finemann–Ross linearization methods. 

Anahtar Kelimeler

Poly, 2 – (p – bromophenyl) 1, 3 – dioxolane – 4 – il, methyl acrylate, Reactivity ratio, Thermal stability

Kaynakça

• Alhanlı, F. 2004. Yan zincirde Brom ve Klor 1,3 Dioksalan Grubu İçeren Akrilat Polimerlerinin Sentezi ve Karakterizasyonu. Fırat Üniversitesi Fen Bilimleri Enstitüsü, Elazığ, 1-64.
• Brar,A.S., Malhotra,M. 1996. Compositional assignments and sequence distribution of vinylidene chloride-methyl acrylate copolymers using one- and two- dimensional NMR spectroscopy.Macromolecules,29: p, 7470-7476.
• Erol, I., Kolu, S. 2011. Copolymers of a new methacrylate monomer bearing oxime ester and ether with methyl methacrylate: synthesis, characterization, monomer reactivity ratios, and biological activity. Journal of Applied Polymer Science, 120, 279–290.
• Fineman, M., Ross, S. D. 1950. Journal of Polymer Science,5,299.
• İlter, Z., Alhanlı, F., Doğan, F., Kaya, İ. 2012. Synthesis and characterization of an acrylate polymer containing chlorine-1,3-dioxalane groups in side chains. Chin J Polym Sci, 30, 642-651
• İlter, Z., Coşkun, M. 2002. Thermal Behaviour of Some Polymethacrylates with a 1,3-dioxolane Ring. Polymer Degradation and Stability, 75, 501 – 508.
• İlter, Z., Erol, G. 2016. Asetil Benzofuran Metakrilat Blendlerinin Termal, Elektriksel ve Biyolojik Özelliklerinin İncelenmesi. AKU J. Sci. Eng, 011201, 32‐40
• Ilter, Z., Öncü, İ. et al. 2016. Synthesis, Characterization and Thermodynamic Properties of Two New 1,3-Dioxolane Containing Copolymers. Journal of the Chemical Society of Pakistan, vol. 38, no. 3, p. 373-380
• Kelen, T., Tüdös, F. 1975. Analysis of the Lineer Methods for Determining Copolymerization Reactivity Ratios. I. A New Improved Lineer Graphic Method.Journal of Macromolecular Science-Chemistry, A9, 1, 1-27.
• Kelen, T., Tüdös, F.1977.Analysis of the Lineer Methods for Determining Copolymerization Reactivity Ratios. IV. A Comprehensive and Critical Reexamination of Carbocationic Copolymerization Data. Journal of Polymer Science, Polymer Chemistry Edition, 15, 3047-3074.
• Kocaokutan, H. 2012. Polimer Kimyası ve Endüstrisine Giriş, Samsun
• Kurt,A., Çağlayan, Z., Bektaş., H.S. 2014. Preparation Of Poly(MethylMethacrylate)/ClayNanocompozites And Investigation Of Some Physical Poperties.Sigma,32, 71-80
• Lengu, A., Neckers, D.C. 1995. Solution and solid 13C-NMR studies of multifunctional polyolacrylate Networks. Journal of Coating Technology, 67: p. 29-35.
• Omidin, H., Hashemi, S.A., Sammes, P.G., Meldrum, I. 1999. Modification acrylic-based superabsorbent polymers (dependence on particle size andsalinity). Polymer, 40: p. 1753-1761.
• Pan, C-Y., Wu, Z. 1987. Department of Applied Chemistry, Üniversity of Science and Technology of China, Anhui, People’sRepublic of Chinaand W.J.BAILEY, Departmen of Chemistry, Üniversity of Maryland College Park, Maryland, 20742 Vol.25, 243 – 248.
• Reddy, A., Reddy, R., Reddy, B., Reddy, S. 2011. Acrylic and methacrylic hompolymers based on pyramido [4, 5-d] pyrimidine derivatives: synthesis, characterization and in vitro antimicrobial activity.Advances in Polymer Science and Technology: An International Journal, 1 (1): 1-9.
• Soutif, J – C.,Ouchatar, L. 1986. D Courret, Jean – Claude Brosse Polymeres porteurs de derives du glycerol.Macromol. Chem, 187, 561 – 572
• Soykan, C., Delibas, A., Coskun,R. 2009. Novel copolymers of 4-chloronaphthyl methacrylate with acrylo nitrile: determination of monomer reactivity rations and antimicrobial activity. J. Macro. Sci. Part A: PureandAppl. Chem, 46, 250-267.
• Thamazharsi, S., Rami Reddy., A.V. 1992. Synthesis and characterization of polymeric Schiff base and their metal chelates. European Polymer Journal, 28(2): p. 119-123.
• Xue J. T., Micheal, A. 1997. Polymer. Deg. and Stab, 58: 193-202.