Yıl 2020, Cilt 13 , Sayı 1, Sayfalar 25 - 32 2020-03-20

Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties
1-Vinilimidazol Ligantı İçeren Kadmiyum(II) Klorür Kompleksi: Yapısal, Spektroskopik ve Termal Özellikler

Zuhal YOLCU [1]


In this work dichlorotetrakis(1-vinylimidazole)cadmium(II), [CdCl2(vim)4] complex was synthesized using 1-vinylimidazole (vim) ligand and CdCl2. The structure of the complex was characterized by FT-IR spectroscopy, thermal analysis (TG, DTG, DTA) and X-ray single crystal studies. In the FT-IR spectrum of the complex, the characteristic peaks (C−H stretch, C=C and C=N vibration bands) of vim were observed. X-ray crystallographic data of the titled complex revealed that vim ligand coordinated to the metal atom via the heterocyclic ring nitrogen atom. The coordination geometry of the Cd(II) central atom is elongated octahedral. Compound crystallized in P21/n space group, and the mononuclear units were weakly linked to each other by C-HCl hydrogen bonds. It was determined by thermal analysis data that the complex degraded in four steps and total mass loss was 99%.

Bu çalışmada 1-vinilimidazol (vim) ve CdCl2 kullanılarak; diklorotetrakis(1-vinilimidazol)kadmiyum(II), [CdCl2(vim)4] kompleksi sentezlendi. Kompleksin yapısı FT-IR spektroskopisi, termal analiz (TG, DTG, DTA) ve X-ışınları tek kristal çalışmaları ile karakterize edildi. Kompleksin IR spektrumunda vim ligandna ait karakteristik pikler (C−H gerilme, C=C ve C=N titreşim bandları) gözlendi. Kompleksin X-ışınları kristallografik verileri komplekste vim ligantlarının heterosiklik halka azotu üzerinden metal atomuna koordine olduğunu ortaya koymuştur. Cd(II) merkez atomunun koordinasyon geometrisi uzamış oktahedraldir. Kompleks P21/n uzay grubunda kristallenmiş ve mononükleer birimler, C-HCl hidrojen bağları ile birbirlerine zayıf şekilde bağlanmıştır. Termal analiz verilerinden kompleksin dört basamakta bozunduğu ve toplam kütle kaybının % 99 olduğu belirlenmiştir

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Orcid: 0000-0001-7761-122X
Yazar: Zuhal YOLCU (Sorumlu Yazar)
Kurum: Giresun University
Ülke: Turkey


Tarihler

Yayımlanma Tarihi : 20 Mart 2020

Bibtex @araştırma makalesi { erzifbed566231, journal = {Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi}, issn = {1307-9085}, eissn = {2149-4584}, address = {}, publisher = {Erzincan Üniversitesi}, year = {2020}, volume = {13}, pages = {25 - 32}, doi = {10.18185/erzifbed.566231}, title = {Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties}, key = {cite}, author = {YOLCU, Zuhal} }
APA YOLCU, Z . (2020). Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi , 13 (1) , 25-32 . DOI: 10.18185/erzifbed.566231
MLA YOLCU, Z . "Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties". Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi 13 (2020 ): 25-32 <https://dergipark.org.tr/tr/pub/erzifbed/issue/53239/566231>
Chicago YOLCU, Z . "Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties". Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi 13 (2020 ): 25-32
RIS TY - JOUR T1 - Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties AU - Zuhal YOLCU Y1 - 2020 PY - 2020 N1 - doi: 10.18185/erzifbed.566231 DO - 10.18185/erzifbed.566231 T2 - Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi JF - Journal JO - JOR SP - 25 EP - 32 VL - 13 IS - 1 SN - 1307-9085-2149-4584 M3 - doi: 10.18185/erzifbed.566231 UR - https://doi.org/10.18185/erzifbed.566231 Y2 - 2020 ER -
EndNote %0 Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties %A Zuhal YOLCU %T Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties %D 2020 %J Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi %P 1307-9085-2149-4584 %V 13 %N 1 %R doi: 10.18185/erzifbed.566231 %U 10.18185/erzifbed.566231
ISNAD YOLCU, Zuhal . "Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties". Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi 13 / 1 (Mart 2020): 25-32 . https://doi.org/10.18185/erzifbed.566231
AMA YOLCU Z . Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2020; 13(1): 25-32.
Vancouver YOLCU Z . Cadmium(II) Chloride Complex Containing 1-Vinylimidazole Ligand: Structural, Spectroscopic and Thermal Properties. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2020; 13(1): 32-25.