Direct Blue 2 Tekstil Boyar Maddesinin Agaricus campestris Biyokütlesi Tarafından Biyosorpsiyonu: Kinetik, İzotermal ve Termodinamik Çalışmalar

Yıl 2020, Cilt: 13 Sayı: 1, 258 - 273, 20.03.2020

Aslı Göçenoğlu Sarıkaya , Emre Erden

https://doi.org/10.18185/erzifbed.585623

Cited By: 4

Öz

Bu çalışmada, Direct Blue 2 (DB2) tekstil boyar maddesinin Agaricus
campestris’ten elde edilen biyosorbent ile sulu çözeltilerden giderimi
çalışılmıştır. Biyosorpsiyona pH, sıcaklık, başlangıç DB2 derişimi ve
biyosorbent miktarı gibi parametrelerin etkisi incelenmiştir. Optimum pH’ın 6.0
olarak tespit edildiği koşullarda 100 mg L^-1 başlangıç DB2 derişimi
ve 0.01 g biyosorbentin kullanıldığı koşullarda maksimum biyosorpsiyon
kapasitesi 38.56 mg g^-1, 0.2 g biyosorbentin kullanıldığı koşullarda
ise % tutunma miktarının % 93.39 olarakbulunmuştur. Elde edilen
sonuçlara göre biyosorpsiyonun Freundlich izoterm modeline ve yalancı-ikinci
derece kinetik modele uygun olduğu rapor edilmiştir. Son olarak, biyosorpsiyon
mekanizması için termodinamik parametreler (standart serbest enerji, standart
entalpi ve standart entropi) belirlenmiştir

Anahtar Kelimeler

Agaricus campestris, Direct Blue 2, biyosorpsiyon, biyosorbent

Teşekkür

Bu çalışmanın gerçekleşmesi esnasında yardımlarını esirgemeyen Prof. Dr. Nurdan Kaşıkara Pazarlıoğlu'na teşekkür ederiz.

Direct Blue 2 Textile Dye Biosorption by Agaricus campestris Biomass: Kinetic, Isotherm and Thermodynamic Studies

Öz

In
this work, the biosorption of Direct Blue 2 (DB2) textile dye from aqueus
solution were studied by biosorbent which were obtained from Agaricus campestris. The effect of pH,
temperature, initial DB2 concentration and amount of biosorbent were
investigated. When 100 mg L^-1 initial concentration of DB2 and 0.01
g of biosorbent were used, the maximum biosorption capacity was determined as
38.56 mg g^-1 under the optimum pH, which was determined as 6.0 and
0.2 g of biosorbent were used, the % removal was determined as 93.39 %. It was
reported as, biosorption process was fitted Freundlich isotherm model and
pseudo-second order kinetic model. In addition, the thermodynamic parameters
(such as standard free energy, standard enthalpy, and standard entropy) were
determined.

Anahtar Kelimeler

Agaricus campestris, Direct Blue 2, biosorption, biosorbent

Kaynakça

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