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Süperkapasitör Elektrot Malzemesi Olarak 3D-Ni Köpük Üzerinde Büyüyen Çiçek-Benzeri ZnCo2O4 Nanotel Dizilerinin Araştırılması

Yıl 2020, Cilt: 13 Sayı: 3, 1235 - 1241, 31.12.2020
https://doi.org/10.18185/erzifbed.776081

Öz

Bir süperkapasitör elektrot malzemesi olarak, çiçek benzeri ZnCo2O4 nanotel (NW) dizileri hidrotermal yöntem kullanılarak doğrudan 3D-Ni köpük üzerinde büyütülmüştür. Elektrot malzemesinin yapısal ve morfolojik analizi XRD, FE-SEM ve EDS ile karakterize edilirken elektrokimyasal analizi ise CV, GCD ve EIS ile karakterize edilmiştir. Elektrot malzemesi, 0,5 mA cm-2 akım yoğunluğunda maksimum 1,01 F cm-2 'lik alansal kapasitans ile mükemmel bir elektrokimyasal performans göstermiştir. 2,000 şarj-deşarj döngüsünden sonra elektrot, başlangıçtaki alansal kapasitansın % 72'sine sahip olarak mükemmel bir döngü kararlılığı sergilemiştir.

Kaynakça

  • Chen, H., Zhang, Q., Wang, J., Wang, Q., Zhou, X., Li, X., Yang, Y., Zhang, K. 2014. “Mesoporous ZnCo2O4 microspheres composed of ultrathin nanosheets cross-linked with metallic NiSix nanowires on Ni foam as anodes for lithium ion batteries”. Nano Energy, 10, 245-258.
  • Huang, Y., Miao, Y. E., Lu, H., Liu, T. 2015. “Hierarchical ZnCo2O4@NiCo2O4 Core–Sheath Nanowires: Bifunctionality towards High‐Performance Supercapacitors and the Oxygen‐Reduction Reaction”. Chemistry–A European Journal, 21(28), 10100-10108.
  • Lin, L., Li, Q., Nie, S., Peng, X., Hu, N. 2016. “3D ZnCo2O4 nanowires@MnO2 nanosheets core-shell structures grown on carbon cloth for excellent supercapacitor electrodes”. Ceramics International, 42(16), 19343-19348.
  • Liu, B., Zhang, J., Wang, X., Chen, G., Chen, D., Zhou, C., Shen, G. 2012. “Hierarchical three-dimensional ZnCo2O4 nanowire arrays/carbon cloth anodes for a novel class of high-performance flexible lithium-ion batteries”. Nano letters, 12(6), 3005-3011.
  • Lv, J., Liang, T., Yang, M., Ken, S., Hideo, M. 2017. “Investigation of microstructures of ZnCo2O4 on bare Ni foam and Ni foam coated with graphene and their supercapacitors performance”. Journal of energy chemistry, 26(3), 330-335.
  • Mohamed, S. G., Hung, T. F., Chen, C. J., Chen, C. K., Hu, S. F., Liu, R. S., Wang, K.C., Xing, X.K., Liu, H.M., Liu, A.S., Hsieh, M. H., Lee, B.J. 2013. “Flower-like ZnCo2O4 nanowires: toward a high-performance anode material for Li-ion batteries”. RSC Advances, 3(43), 20143-20149.
  • Moon, I. K., Yoon, S., Oh, J. 2017. “Three‐dimensional hierarchically mesoporous ZnCo2O4 nanowires grown on graphene/sponge foam for high‐performance, flexible, all‐solid‐state supercapacitors”. Chemistry–A European Journal, 23(3), 597-604.
  • Rajesh, J. A., Min, B. K., Kim, J. H., Kang, S. H., Kim, H., Ahn, K. S. 2017. “Facile hydrothermal synthesis and electrochemical supercapacitor performance of hierarchical coral-like ZnCo2O4 nanowires”. Journal of Electroanalytical Chemistry, 785, 48-57.
  • Ratha, S., Khare, R. T., More, M. A., Thapa, R., Late, D. J., Rout, C. S. 2015. “Field emission properties of spinel ZnCo2O4 microflowers”. RSC Advances, 5(7), 5372-5378.
  • Wang, S., Pu, J., Tong, Y., Cheng, Y., Gao, Y., Wang, Z. 2014. “ZnCo2O4 nanowire arrays grown on nickel foam for high-performance pseudocapacitors”. Journal of Materials Chemistry A, 2(15), 5434-5440.
  • Wang, S., Teng, Y., Liu, X., Yu, D., Meng, Y., Wu, Y., Sun, S., Zhao, X., Liu, X. 2019. “Facile synthesis of mesoporous ZnCo2O4 nanowire arrays and nanosheet arrays directly grown on nickel foam for high-performance supercapacitors”. Inorganic Chemistry Communications, 101, 16-22.
  • Wu, C., Cai, J., Zhang, Q., Zhou, X., Zhu, Y., Li, L., Shen, P., Zhang, K. 2015. “Direct growth of urchin-like ZnCo2O4 microspheres assembled from nanowires on nickel foam as high-performance electrodes for supercapacitors”. Electrochimica Acta, 169, 202-209.
  • Xie, L., Liu, Y., Bai, H., Li, C., Mao, B., Sun, L., Shi, W. 2018. “Core-shell structured ZnCo2O4@ZnWO4 nanowire arrays on nickel foam for advanced asymmetric supercapacitors”. Journal of colloid and interface science, 531, 64-73.
  • Zhang, D., Zhang, Y., Li, X., Luo, Y., Huang, H., Wang, J., Chu, P. K. 2016. “Self-assembly of mesoporous ZnCo2O4 nanomaterials: density functional theory calculation and flexible all-solid-state energy storage”. Journal of Materials Chemistry A, 4(2), 568-577.
  • Zhao, J., Li, C., Zhang, Q., Zhang, J., Wang, X., Lin, Z., Wang, J., Lv, W., Lu, C., Wong, C.P., Yao, Y. 2017. “An all-solid-state, lightweight, and flexible asymmetric supercapacitor based on cabbage-like ZnCo2O4 and porous VN nanowires electrode materials”. Journal of Materials Chemistry A, 5(15), 6928-6936.
  • Zhao, W., Qi, Y., Dong, J., Xu, J., Wu, P., Zhang, C. 2020. “New insights into the structure-property relation in ZnCo2O4 nanowire and nanosheet arrays”. Journal of Alloys and Compounds, 817, 152692.

Investigation of Flower-like ZnCo2O4 Nanowire Arrays Growth on 3D-Ni Foam as Supercapacitor Electrode Material

Yıl 2020, Cilt: 13 Sayı: 3, 1235 - 1241, 31.12.2020
https://doi.org/10.18185/erzifbed.776081

Öz

As a supercapacitor electrode material, flower-like ZnCo2O4 nanowire (NW) arrays were directly grown on 3D-Ni foam using the hydrothermal method. Structural and morphological analysis of the electrode material was characterized by XRD, FE-SEM, and EDS, while its electrochemical analysis was characterized by CV, GCD, and EIS. The electrode material demonstrated excellent electrochemical performance with a maximum areal capacitance of 1.01 F cm-2 at a current density of 0.5 mA cm-2. After 2.000 charge-discharge cycles, the electrode showed excellent cycle stability, having 72% of the initial areal capacitance.

Kaynakça

  • Chen, H., Zhang, Q., Wang, J., Wang, Q., Zhou, X., Li, X., Yang, Y., Zhang, K. 2014. “Mesoporous ZnCo2O4 microspheres composed of ultrathin nanosheets cross-linked with metallic NiSix nanowires on Ni foam as anodes for lithium ion batteries”. Nano Energy, 10, 245-258.
  • Huang, Y., Miao, Y. E., Lu, H., Liu, T. 2015. “Hierarchical ZnCo2O4@NiCo2O4 Core–Sheath Nanowires: Bifunctionality towards High‐Performance Supercapacitors and the Oxygen‐Reduction Reaction”. Chemistry–A European Journal, 21(28), 10100-10108.
  • Lin, L., Li, Q., Nie, S., Peng, X., Hu, N. 2016. “3D ZnCo2O4 nanowires@MnO2 nanosheets core-shell structures grown on carbon cloth for excellent supercapacitor electrodes”. Ceramics International, 42(16), 19343-19348.
  • Liu, B., Zhang, J., Wang, X., Chen, G., Chen, D., Zhou, C., Shen, G. 2012. “Hierarchical three-dimensional ZnCo2O4 nanowire arrays/carbon cloth anodes for a novel class of high-performance flexible lithium-ion batteries”. Nano letters, 12(6), 3005-3011.
  • Lv, J., Liang, T., Yang, M., Ken, S., Hideo, M. 2017. “Investigation of microstructures of ZnCo2O4 on bare Ni foam and Ni foam coated with graphene and their supercapacitors performance”. Journal of energy chemistry, 26(3), 330-335.
  • Mohamed, S. G., Hung, T. F., Chen, C. J., Chen, C. K., Hu, S. F., Liu, R. S., Wang, K.C., Xing, X.K., Liu, H.M., Liu, A.S., Hsieh, M. H., Lee, B.J. 2013. “Flower-like ZnCo2O4 nanowires: toward a high-performance anode material for Li-ion batteries”. RSC Advances, 3(43), 20143-20149.
  • Moon, I. K., Yoon, S., Oh, J. 2017. “Three‐dimensional hierarchically mesoporous ZnCo2O4 nanowires grown on graphene/sponge foam for high‐performance, flexible, all‐solid‐state supercapacitors”. Chemistry–A European Journal, 23(3), 597-604.
  • Rajesh, J. A., Min, B. K., Kim, J. H., Kang, S. H., Kim, H., Ahn, K. S. 2017. “Facile hydrothermal synthesis and electrochemical supercapacitor performance of hierarchical coral-like ZnCo2O4 nanowires”. Journal of Electroanalytical Chemistry, 785, 48-57.
  • Ratha, S., Khare, R. T., More, M. A., Thapa, R., Late, D. J., Rout, C. S. 2015. “Field emission properties of spinel ZnCo2O4 microflowers”. RSC Advances, 5(7), 5372-5378.
  • Wang, S., Pu, J., Tong, Y., Cheng, Y., Gao, Y., Wang, Z. 2014. “ZnCo2O4 nanowire arrays grown on nickel foam for high-performance pseudocapacitors”. Journal of Materials Chemistry A, 2(15), 5434-5440.
  • Wang, S., Teng, Y., Liu, X., Yu, D., Meng, Y., Wu, Y., Sun, S., Zhao, X., Liu, X. 2019. “Facile synthesis of mesoporous ZnCo2O4 nanowire arrays and nanosheet arrays directly grown on nickel foam for high-performance supercapacitors”. Inorganic Chemistry Communications, 101, 16-22.
  • Wu, C., Cai, J., Zhang, Q., Zhou, X., Zhu, Y., Li, L., Shen, P., Zhang, K. 2015. “Direct growth of urchin-like ZnCo2O4 microspheres assembled from nanowires on nickel foam as high-performance electrodes for supercapacitors”. Electrochimica Acta, 169, 202-209.
  • Xie, L., Liu, Y., Bai, H., Li, C., Mao, B., Sun, L., Shi, W. 2018. “Core-shell structured ZnCo2O4@ZnWO4 nanowire arrays on nickel foam for advanced asymmetric supercapacitors”. Journal of colloid and interface science, 531, 64-73.
  • Zhang, D., Zhang, Y., Li, X., Luo, Y., Huang, H., Wang, J., Chu, P. K. 2016. “Self-assembly of mesoporous ZnCo2O4 nanomaterials: density functional theory calculation and flexible all-solid-state energy storage”. Journal of Materials Chemistry A, 4(2), 568-577.
  • Zhao, J., Li, C., Zhang, Q., Zhang, J., Wang, X., Lin, Z., Wang, J., Lv, W., Lu, C., Wong, C.P., Yao, Y. 2017. “An all-solid-state, lightweight, and flexible asymmetric supercapacitor based on cabbage-like ZnCo2O4 and porous VN nanowires electrode materials”. Journal of Materials Chemistry A, 5(15), 6928-6936.
  • Zhao, W., Qi, Y., Dong, J., Xu, J., Wu, P., Zhang, C. 2020. “New insights into the structure-property relation in ZnCo2O4 nanowire and nanosheet arrays”. Journal of Alloys and Compounds, 817, 152692.
Toplam 16 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Fatma Nur Tuzluca 0000-0003-4383-2432

Yayımlanma Tarihi 31 Aralık 2020
Yayımlandığı Sayı Yıl 2020 Cilt: 13 Sayı: 3

Kaynak Göster

APA Tuzluca, F. N. (2020). Investigation of Flower-like ZnCo2O4 Nanowire Arrays Growth on 3D-Ni Foam as Supercapacitor Electrode Material. Erzincan University Journal of Science and Technology, 13(3), 1235-1241. https://doi.org/10.18185/erzifbed.776081