Rheological Analysis of The Aging Behavior of Short-Term Aged Pure And SBS-Modified Asphalt Binders
Yıl 2025,
Cilt: 4 Sayı: 2, 276 - 289, 26.06.2025
Ahmet Münir Özdemir
Öz
Flexible pavements consist of a bituminous binder and certain graded aggregate. The performance of the bitumen determines the overall pavement performance. Bitumen undergoes short-term aging from production to application, accounting for most of its total aging during service life. This study rheologically investigates the short-term aging behavior of 70/100 pure bitumen and SBS-modified bitumen. Frequency Sweep test was performed on bitumen samples with Dynamic Shear Rheometer (DSR) device at different frequency (0.01-10 Hz) and temperature (40, 50, 60, 70°C) ranges. The complex modulus and complex viscosity master curves of the binders were obtained by processing the experimental data and the curves were subjected to rheological model analysis. The study showed that SBS modification enhanced aging resistance by preserving elastic properties. Moreover, the master curves were applied to rheological models with high accuracy.
Etik Beyan
Ethics committee permission is not required for the prepared article”
“There is no conflict of interest with any person/institution in the prepared article.”
Kaynakça
-
R. Hunter, A. Self, and J. Read, The Shell Bitumen Handbook, 6th ed. London, U.K.: ICE Publishing, 2015.
-
R. Rahbar-Rastegar, R. Zhang, J. E. Sias, and E. V. Dave, "Evaluation of laboratory ageing procedures on cracking performance of asphalt mixtures," Road Mater. Pavement Des., vol. 20, no. sup2, pp. S647–S662, 2019.
-
B. V. Kok and M. Yilmaz, "The effects of using lime and styrene–butadiene–styrene on moisture sensitivity resistance of hot mix asphalt," Constr. Build. Mater., vol. 23, no. 5, pp. 1999–2006, 2009.
-
D. Zhang, B. Birgisson, X. Luo, and I. Onifade, "A new short-term aging model for asphalt binders based on rheological activation energy," Mater. Struct., vol. 52, no. 4, p. 68, 2019.
-
P. Radziszewski et al., "Ageing evaluation of foamed polymer modified bitumen with bio-flux additive," Materials, vol. 16, no. 6, p. 2167, 2023.
-
Y. R. Kim, Modeling of Asphalt Concrete, 1st ed. New York, NY, USA: McGraw-Hill Education, 2009.
-
T. Zhen et al., "Multiscale evaluation of asphalt aging behaviour: A review," Sustainability, vol. 15, no. 4, p. 2953, 2023.
-
D. N. Little, D. H. Allen, and A. Bhasin, Modeling and Design of Flexible Pavements and Materials, Springer, 2017.
-
N. Dehouche, M. Kaci, and K. A. Mokhtar, "Influence of thermo-oxidative aging on chemical composition and physical properties of polymer modified bitumens," Constr. Build. Mater., vol. 26, no. 1, pp. 350–356, 2012.
-
F. Wang et al., "Correlation of asphalt performance indicators and aging degrees: A review," Constr. Build. Mater., vol. 250, p. 118824, 2020.
-
O. Sirin, D. K. Paul, and E. Kassem, "State of the art study on aging of asphalt mixtures and use of antioxidant additives," Adv. Civ. Eng., vol. 2018, p. 1, 2018.
-
N. C. L. Madeira, V. Lacerda, and W. Romão, "Characterization of asphalt aging by analytical techniques: A review on progress and perspectives," Energy Fuels, vol. 36, no. 11, pp. 5531–5549, 2022.
-
S.-J. Lee, S. N. Amirkhanian, K. Shatanawi, and K. W. Kim, "Short-term aging characterization of asphalt binders using gel permeation chromatography and selected Superpave binder tests," Constr. Build. Mater., vol. 22, no. 11, pp. 2220–2227, 2008.
-
S.-J. Lee, S. N. Amirkhanian, and K. W. Kim, "Laboratory evaluation of the effects of short-term oven aging on asphalt binders in asphalt mixtures using HP-GPC," Constr. Build. Mater., vol. 23, no. 9, pp. 3087–3093, 2009.
-
H. Zhang et al., "Effect of long-term laboratory aging on rheological properties and cracking resistance of polymer-modified asphalt binders at intermediate and low temperature range," Constr. Build. Mater., vol. 226, pp. 767–777, 2019.
-
X. Liu, T. Li, and H. Zhang, "Short-term aging resistance investigations of polymers and polyphosphoric acid modified asphalt binders under RTFOT aging process," Constr. Build. Mater., vol. 191, pp. 787–794, 2018.
-
T. Jin et al., "Laboratory short-term aging of crumb rubber modified asphalt: RTFOT temperature optimization and performance investigation," J. Clean. Prod., vol. 434, p. 140327, 2024.
-
S. Wang and W. Huang, "Investigation of aging behavior of terminal blend rubberized asphalt with SBS polymer," Constr. Build. Mater., vol. 267, p. 120870, 2021.
-
EN 12607-1: Bitumen and Bituminous Binders – Determination of the Resistance to Hardening under Influence of Heat and Air – Part 1: RTFOT Method, CEN, 2014.
-
J. Xie and Z. Guo, "Researching on fatigue model of asphalt mixtures," J. Highway Transp. Res. Dev., vol. 2, no. 2, pp. 25–29, 2007.
-
D. W. Christensen, D. A. Anderson, and G. M. Rowe, "Relaxation spectra of asphalt binders and the Christensen–Anderson rheological model," Road Mater. Pavement Des., vol. 18, no. sup1, pp. 382–403, 2017.
-
F. Liu, Z. Zhou, and X. Zhang, "Linking chemical to rheological properties of asphalt binder with oxidative aging effect," Road Mater. Pavement Des., vol. 22, no. 9, pp. 2014–2028, 2021.
-
K. Zhao and Y. Wang, "Influences of aging conditions on the rheological properties of asphalt binders," Int. J. Pavement Eng., vol. 21, no. 5, pp. 653–665, 2020.
-
M. C. Cavalli et al., "Effect of ageing on the mechanical and chemical properties of binder from RAP treated with bio-based rejuvenators," Compos. B Eng., vol. 141, pp. 174–181, 2018.
-
P. L. D. et al., "Impact of asphalt aging temperature on chemo-mechanics," RSC Adv., vol. 9, no. 21, pp. 11602–11613, 2019.
-
M. Akpolat, B. V. Kök, and E. Aydoğmuş, "Research on the rheological properties of asphalt binder modified by fume silica and crumb rubber compound," Period. Polytech. Civ. Eng., 2022.
-
D. Lesueur et al., "Relationships between the structure and the mechanical properties of paving grade asphalt cement," Asphalt Paving Technol., vol. 66, 1997.
-
D. Lesueur et al., "Impact of the asphalt binder rheological behavior on the value of the ΔTc parameter," Constr. Build. Mater., vol. 293, p. 123464, 2021.
-
D. Kaya Özdemir, "Temperature susceptibility and rheological aging characteristics of the bitumen having different penetration grades," Black Sea J. Eng. Sci., vol. 4, no. 4, pp. 209–213, 2021.
Kısa Dönem Yaşlandırılmış Saf ve SBS Modifiyeli Asfalt Bağlayıcıların Yaşlanma Davranışlarının Reolojik Araştırması
Yıl 2025,
Cilt: 4 Sayı: 2, 276 - 289, 26.06.2025
Ahmet Münir Özdemir
Öz
Esnek üstyapılar bitümlü bağlayıcı ve uygun gradasyonda agreganın karışımından elde edilmekte ve bitümün performansı kaplamanın nihai performansı üzerinde belirleyici faktör olmaktadır. Bitüm, üretilmesinden uygulanmasına kadar geçen sürede kısa dönemli yaşlanmaya maruz kalır ve bu yaşlanma servis ömrü boyunca meydana gelecek yaşlanmanın büyük kısmını oluşturur. Bu sebeple kısa dönemli yaşlanma davranışı oldukça önemlidir. Bu çalışmada çeşitli analitik yaklaşımlar ile 70/100 saf bitüm ve Stiren-Butadien-Stiren (SBS) modifiyeli bitümün yaşlanma dayanımları reolojik olarak incelenmiştir. Bitüm numuneleri üzerinde Dinamik Kayma Reometresi (DSR) cihazı ile farklı frekans (0.01-10 Hz) ve sıcaklık (40, 50, 60, 70°C) aralıklarında Frekans Tarama testi uygulanmıştır. Deneysel veriler işlenerek bağlayıcıların kompleks modül ve kompleks viskozite ana eğrileri elde edilmiş, eğriler reolojik analizlere tabi tutulmuştur. Sonuçlar, SBS modifikasyonu ile yaşlanma esnasında elastik özelliklerin korunma kabiliyetinin artırılarak yaşlanma direncinin iyileştirildiğini göstermiştir. Ayrıca, ana eğriler reolojik modellere yüksek doğrulukta uygulanmıştır.
Etik Beyan
Hazırlanan makale için etik kurul izni gerekmemektedir”
“Hazırlanan makalede herhangi bir kişi/kurumla çıkar çatışması bulunmamaktadır.”
Kaynakça
-
R. Hunter, A. Self, and J. Read, The Shell Bitumen Handbook, 6th ed. London, U.K.: ICE Publishing, 2015.
-
R. Rahbar-Rastegar, R. Zhang, J. E. Sias, and E. V. Dave, "Evaluation of laboratory ageing procedures on cracking performance of asphalt mixtures," Road Mater. Pavement Des., vol. 20, no. sup2, pp. S647–S662, 2019.
-
B. V. Kok and M. Yilmaz, "The effects of using lime and styrene–butadiene–styrene on moisture sensitivity resistance of hot mix asphalt," Constr. Build. Mater., vol. 23, no. 5, pp. 1999–2006, 2009.
-
D. Zhang, B. Birgisson, X. Luo, and I. Onifade, "A new short-term aging model for asphalt binders based on rheological activation energy," Mater. Struct., vol. 52, no. 4, p. 68, 2019.
-
P. Radziszewski et al., "Ageing evaluation of foamed polymer modified bitumen with bio-flux additive," Materials, vol. 16, no. 6, p. 2167, 2023.
-
Y. R. Kim, Modeling of Asphalt Concrete, 1st ed. New York, NY, USA: McGraw-Hill Education, 2009.
-
T. Zhen et al., "Multiscale evaluation of asphalt aging behaviour: A review," Sustainability, vol. 15, no. 4, p. 2953, 2023.
-
D. N. Little, D. H. Allen, and A. Bhasin, Modeling and Design of Flexible Pavements and Materials, Springer, 2017.
-
N. Dehouche, M. Kaci, and K. A. Mokhtar, "Influence of thermo-oxidative aging on chemical composition and physical properties of polymer modified bitumens," Constr. Build. Mater., vol. 26, no. 1, pp. 350–356, 2012.
-
F. Wang et al., "Correlation of asphalt performance indicators and aging degrees: A review," Constr. Build. Mater., vol. 250, p. 118824, 2020.
-
O. Sirin, D. K. Paul, and E. Kassem, "State of the art study on aging of asphalt mixtures and use of antioxidant additives," Adv. Civ. Eng., vol. 2018, p. 1, 2018.
-
N. C. L. Madeira, V. Lacerda, and W. Romão, "Characterization of asphalt aging by analytical techniques: A review on progress and perspectives," Energy Fuels, vol. 36, no. 11, pp. 5531–5549, 2022.
-
S.-J. Lee, S. N. Amirkhanian, K. Shatanawi, and K. W. Kim, "Short-term aging characterization of asphalt binders using gel permeation chromatography and selected Superpave binder tests," Constr. Build. Mater., vol. 22, no. 11, pp. 2220–2227, 2008.
-
S.-J. Lee, S. N. Amirkhanian, and K. W. Kim, "Laboratory evaluation of the effects of short-term oven aging on asphalt binders in asphalt mixtures using HP-GPC," Constr. Build. Mater., vol. 23, no. 9, pp. 3087–3093, 2009.
-
H. Zhang et al., "Effect of long-term laboratory aging on rheological properties and cracking resistance of polymer-modified asphalt binders at intermediate and low temperature range," Constr. Build. Mater., vol. 226, pp. 767–777, 2019.
-
X. Liu, T. Li, and H. Zhang, "Short-term aging resistance investigations of polymers and polyphosphoric acid modified asphalt binders under RTFOT aging process," Constr. Build. Mater., vol. 191, pp. 787–794, 2018.
-
T. Jin et al., "Laboratory short-term aging of crumb rubber modified asphalt: RTFOT temperature optimization and performance investigation," J. Clean. Prod., vol. 434, p. 140327, 2024.
-
S. Wang and W. Huang, "Investigation of aging behavior of terminal blend rubberized asphalt with SBS polymer," Constr. Build. Mater., vol. 267, p. 120870, 2021.
-
EN 12607-1: Bitumen and Bituminous Binders – Determination of the Resistance to Hardening under Influence of Heat and Air – Part 1: RTFOT Method, CEN, 2014.
-
J. Xie and Z. Guo, "Researching on fatigue model of asphalt mixtures," J. Highway Transp. Res. Dev., vol. 2, no. 2, pp. 25–29, 2007.
-
D. W. Christensen, D. A. Anderson, and G. M. Rowe, "Relaxation spectra of asphalt binders and the Christensen–Anderson rheological model," Road Mater. Pavement Des., vol. 18, no. sup1, pp. 382–403, 2017.
-
F. Liu, Z. Zhou, and X. Zhang, "Linking chemical to rheological properties of asphalt binder with oxidative aging effect," Road Mater. Pavement Des., vol. 22, no. 9, pp. 2014–2028, 2021.
-
K. Zhao and Y. Wang, "Influences of aging conditions on the rheological properties of asphalt binders," Int. J. Pavement Eng., vol. 21, no. 5, pp. 653–665, 2020.
-
M. C. Cavalli et al., "Effect of ageing on the mechanical and chemical properties of binder from RAP treated with bio-based rejuvenators," Compos. B Eng., vol. 141, pp. 174–181, 2018.
-
P. L. D. et al., "Impact of asphalt aging temperature on chemo-mechanics," RSC Adv., vol. 9, no. 21, pp. 11602–11613, 2019.
-
M. Akpolat, B. V. Kök, and E. Aydoğmuş, "Research on the rheological properties of asphalt binder modified by fume silica and crumb rubber compound," Period. Polytech. Civ. Eng., 2022.
-
D. Lesueur et al., "Relationships between the structure and the mechanical properties of paving grade asphalt cement," Asphalt Paving Technol., vol. 66, 1997.
-
D. Lesueur et al., "Impact of the asphalt binder rheological behavior on the value of the ΔTc parameter," Constr. Build. Mater., vol. 293, p. 123464, 2021.
-
D. Kaya Özdemir, "Temperature susceptibility and rheological aging characteristics of the bitumen having different penetration grades," Black Sea J. Eng. Sci., vol. 4, no. 4, pp. 209–213, 2021.