Sabit Yataklı Kolonda Şeftali Çekirdeği Kabuğu Kullanılarak Sulu Çözeltilerden Basic Yellow 51’in Giderimi

Yıl 2019, Cilt: 31 Sayı: 2, 415 - 422, 27.09.2019

İbrahim Polat Ramazan Orhan

https://doi.org/10.35234/fumbd.601363

Öz

Sabit yataklı kolon sisteminde sulu çözeltiden Basic Yellow 51 (BY51) boyar maddesinin uzaklaştırılması için  tarımsal bir atık olan şeftali çekirdeği kabuğu adsorbent olarak kullanılmıştır. Adsorbentin adsorpsiyon özellikleri üzerine başlangıç BY51 boyar madde konsantrasyonu (20-60 mg/L), akış hızı (5-10 mL/dk) ve adsorbent miktarının (1.5-2.5 g) etkisi incelendi. Veriler, breakthrough (kırılma) eğrilerinin akış hızına, başlangıç boyar madde konsantrasyonuna ve adsorbent miktarına bağlı olduğunu gösterdi. En fazla adsorpsiyon kapasitesi 28.12 mg/g olarak 60 mg/L BY51 boyar madde konsantrasyonu, 5  mL/dk'lık çözelti akış hızı ve 2.0 g adsorbent miktarında elde edildi. Thomas ve Yoon-Nelson modelleri kırılma eğrilerini tahmin etmek için elde edilen deneysel verilere başarılı bir şekilde uygulandı. 

Anahtar Kelimeler

Şeftali çekirdeği kabuğu, Bazik sarı 51, Sabit yataklı kolon, Kırılma eğrisi

Kaynakça

• [1] Yang Y, Wang G, Wang B, Li Z, Jia X, Zhou Q, Zhao Y. Biosorption of Acid Black 172 and Congo Red from aqueous solution by nonviable Penicillium YW 01: kinetic study, equilibrium isotherm and artificial neural network modeling. Bioresour. Technol. 2011; 102: 828-834.
• [2] Gupta VK, Mohan D, Sharma S, Sharma M. Removal of basic dyes (rhodamine B and methylene blue) from aqueous solutions using bagasse fly ash. Sep. Sci. Technol. 2000; 35 (13): 2097–2113.
• [3] Vimonses V, Jin B, Chow CWK. Insight into removal kinetic and mechanisms of anionic dye by calcined clay materials and lime. J. Hazard. Mater. 2010;177:420–427.
• [4] Sohrabi MR, Ghavami M. Photocatalytic Degradation of Direct Red 23 Dye Using UV/TiO2: Effect of Operational Parameters. J. Hazard. Mater. 2008; 153 (3): 1235-1239.
• [5] Ciardelli G, Corsi L, Marcucci M. Membrane Seperation for Watewater Reuse in the Textile Industry. Resour. Conserv. Recycl. 2001; 31 (2): 189-197.
• [6] Tang H, Yin L, Lu H. Synthesis, Conformations and Cell-Penetrating Properties. Biomacromolecules 2012; 13 (9): 2609-2615.
• [7] Rafatullah M, Sulaiman O, Hashim R, Ahmad A. Adsorption of Methylene Blue on Low-cost Adsorbents: A Review. J. Hazard Mater. 2010; 177 (1): 70-80.
• [8] Aguedach A, Brosillon S, Morvan J, Lhadi EK. Photocatalytic degradation of azodyes reactive black 5 and reactive yellow 145 in water over a newly deposited titanium dioxide. Appl. Catal. B Environ. 2005; 57: 55–62.
• [9] Sharma P, Kaur H, Sharma M, Sahore V. A review on applicability of naturally available adsorbents for the removal of hazardous dyes from aqueous waste. Environ.Monit. Assess. 2011; 183: 151–195.
• [10] Altenor S, Ncibi MC, Emmanuel E, Gaspard S. Textural Characteristics, Physiochemical Properties and Adsorption Efficiencies of Caribbean Alga Turbinaria Turbinata and Its Derived Carbonaceous Materials for Water Treatment Application. Biochem. Eng. J. 2012; l (67): 35-44.
• [11] Malik PK. Use of activated carbons prepared from sawdust and rice-husk for adsorption of acid dyes: a case study of Acid Yellow 36. Dyes Pigments. 2003; 56: 239–249.
• [12] Kini SM, Saidutta MB, Murty VRC, Kadoli SV. Adsorption of basic dye fromaqueous solution using HCl treated saw dust (Lagerstroemia microcarpa): kinetic, modeling of equilibrium, thermodynamic. India, Int. Res. J. Env. Sci. 2013; 2: 6-16.
• [13] Al-Anber ZA, Al-Anber MA, Matouq M, Al-Ayed O, Omari NM. Defatted Jojoba for the Removal of Methylene Blue from Aqueous Solution: Thermodynamic and Kinetic Studies. Desalination. 2011; 276 (1): 169-174.
• [14] Malekbala M, Hosseini S, Yazdi SK, Masoudi SS. The Study of the Potential Capability of Sugar Beet Pulp on the Removal Efficiency of Two Cationic Dyes. Chem. Eng. Res. Des. 2013; 90 (5): 704-712.
• [15] Thomas HC. Heterogeneous ion exchange in a flowing system, J. Am. Chem. Soc. 1944; 66: 1466-1664.
• [16] Yoon YH, Nelson J.H. Application of gas adsorption kinetics. I. A theoretical model for respirator cartridge service life. Am. Ind. Hyg. Assoc. J. 1984; 45: 509-516.
• [17] Han R, Ding D, Xu Y, Zou W, Wang Y, Li Y, Zou L. Use of rice husk for the adsorption of Congo red from aqueous solution in column mode. Biores. Technol. 2008; 99: 2938-2946.
• [18] El-Kamash AM. Evaluation of zeolite A for the sorptive removal of Cs+ and Sr2+ ions from aqueous solutions using batch and fixed bed column operations. J Hazard Mater. 2008;151:432-445.
• [19] Goel J, Kadirvelu K, Rajagopal C, Garg VK. Removal of lead(II) by adsorption using treated granular activated carbon: batch and column studies, J. Hazard. Mater. B 2005; 125: 211-220.
• [20] Han R, Wang Y, Yu W, Zou W, Shi J, Liu H. Biosorption of methylene blue from aqueous solution by rice husk in a fixed-bed column. J. Hazard. Mater. 2007; 141: 713–718.
• [21] Sadaf S, Bhatti HN. Evaluation of peanut husk as a novel, low cost biosorbent for the removal of Indosol Orange RSN dye from aqueous solutions: batch and fixed bed studies. Clean Technol Environ Policy 2014;16: 527-544.
• [22] Sen TK, Mahajan SP, Khilar KC. Colloid-associated contaminant transport in porous media: 1. Experimental studies. AIChE J 2002; 48: 2366-2374.
• [23] Ozdemir O, Turan M, Turan AZ, Faki A, Engin AB. Feasibility analysis of color removal from textile dyeing wastewater in a fixed-bed column system by surfactant-modified zeolite (SMZ). J. Hazard. Mater. 2009; 166: 647–654.
• [24] Vijayaraghavan K, Jegan J, Palanivelu K, Velan M. Removal of nickel(II) ions from aqueous solution using crab shell particles in a packed bed up flow column, J. Hazard. Mater. 2004; 113B (1–3): 223–230.
• [25] Foroughi-dahr M, Esmaieli M, Abolghasemi H, Shojamoradi A, Pouya ES. Continuous adsorption study of Congo red using tea waste in a fixed-bed column. Desalin. Water Treat 2016; 57: 8437–8446.
• [26] Mobasherpour I, Salahi E, Asjodi A. Research on the batch and fixed-bed column performance of red mud adsorbents for lead removal. Canadian Chemical Transactions 2014; 2 (1): 83-96.
• [27] Padmesh TVN, Vijayaraghavan K, Sekaran G, Velan M. Batch and column studies on biosorption of acid dyes on fresh water macro alga Azolla filiculoides. J. Hazard. Mater. 2005; B 125: 121–129.
• [28] Han RP, Wang Y, Zhao X, Wang YF, Xie FL, Cheng JM, et al. Adsorption of methylene blue by phoenix tree leaf powder in a fixed-bed column: experiments