Zeytinyağı endüstrisi atıksuyunu arıtan mikrofiltrasyon membran sisteminde organik madde gideriminin kinetik değerlendirilmesi

Yıl 2024, Cilt: 39 Sayı: 1, 287 - 298, 21.08.2023

Sevgi Tokgöz Güneş , Ezgi Oktav Akdemir

https://doi.org/10.17341/gazimmfd.1041320

Öz

Bu çalışmada, laboratuvar ölçekli bir mikrofiltrasyon membran sistemi, 100, 150 ve 200 L/sa debilerde, 1 bar basınçta ve 30, 60, 90 ve 120 dakikalık 4 farklı filtrasyon süresinde (MFS) çalıştırılmıştır. Sistem, 120 g/L kimyasal oksijen ihtiyacı (KOİ) konsantrasyonuna sahip zeytinyağı endüstrisi atıksuyu ile beslenmiştir. Mikrofiltrasyon sonrası elde edilen sonuçlar, Modifiye Stover-Kincannon modeli, İkinci Derece Kinetik model, Birinci Derece Kinetik model kullanılarak analiz edilmiş ve uygulanan modellerin deneysel verilere uygun olduğu bulunmuştur. Modifiye Stover-Kincannon model sabitleri olan Umaks ve KB sırasıyla 39,370- 46,948 g/L.dak ve 80,114-96,883 g/L.dak aralığındadır. İkinci Derece Kinetik model sabitleri olan b ve a değerleri sırasıyla 2,0349-2,0807 ve 2,5546-3,0527 1/dak ve ikinci derece KOİ giderme hız sabiti olan k2(C) değerleri ise, 39,3095-46,9741 1/dak aralığında bulunmuştur. Birinci Derece Kinetik modelinde, birinci derece KOİ giderme hız sabiti, k1, 0,8868-0,5286 1/dak aralığındadır. Yüksek korelasyon katsayıları (R2 = %100–97), uygulanan bu modellerin, mikrofiltrasyon sistem tasarımında organik madde giderme kinetiğinde kullanılabileceğini, dolayısıyla zeytinyağı endüstrisi atıksuyunun arıtımında membranın davranışını tahmin edebileceğini göstermektedir.

Anahtar Kelimeler

Kinetik model , organik madde , mikrofiltrasyon , zeytinyağı endüstrisi atıksuyu

Kaynakça

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