Kitosan/modifiye montmorillonit küreler ile asit Violet 90 boyarmaddesinin adsorpsiyonu

Müjgan Okur; Berkay Taşkıntuna

doi:10.17341/gazimmfd.1334945

Kitosan/modifiye montmorillonit küreler ile asit Violet 90 boyarmaddesinin adsorpsiyonu

Öz

Sentetik boyar maddeler kağıt, plastik, deri, yün ve tekstil gibi bir çok endüstriyel alanda renklendirici olarak yaygın bir şekilde kullanılmaktadırlar. Bu boyar maddeleri içeren atıksular arıtılmadan alıcı su ortamlarına bırakıldığında, su ortamının ışık geçirgenliğini azaltarak sucul yaşamdaki fotosentetik aktiviteleri engellemekte, çevre, hayvan ve insan yaşam döngülerine zarar vermektedir. Bu nedenle boyar maddelerin sulardan arıtılmaları gerekmektedir. Adsorpsiyon uygun maliyetli, kolay uygulanabilir ve etkili giderim verimlerinin elde edildiği yöntemlerden birisidir. Bu çalışmada boyar madde adsorpsiyonunda kullanılmak üzere kitosan (CTS) ve modifiye montmorillonit (mMMT) içeren CTS/mMMT küreler hazırlanmıştır. Deneylerde metal-kompleks bir boyar madde olan Asit Violet 90 (AV90) kullanılmıştır. CTS ve CTS/mMMT küreler damlatma yöntemiyle hazırlanmıştır. Kürelerin morfolojik yapıları taramalı elektron mikroskobu (SEM) ile ve fonksiyonel grupları Fourier geçirimli infrared spektroskopisi (FT-TR) ile incelenmiştir. Küreler ile AV90 adsorpsiyonuna başlangıç pH ve boyar madde derişiminin etkisi incelenmiştir. Deneyler kesikli sistemde gerçekleştirilmiştir. En yüksek boyar madde giderimi pH 2’de elde edilmiştir. Elde edilen deneysel verilere adsorpsiyon izoterm modelleri (Langmuir, Freundlich ve Temkin) uygulanmış ve AV90 adsorpsiyonu için en uygun modelin Langmuir olduğu görülmüştür. Langmuir izoterm modelinden elde edilen adsorpsiyon kapasiteleri (qm, mg/g) CTS için 26,81 mg/g ve CTS/mMMT için 91,74 mg/g’dır. Yapılan çalışma ile modifiye montmorillonit içeren kürelerin boyar madde adsorpsiyonunda başarılı bir şekilde kullanılabileceği görülmüştür.

Anahtar Kelimeler

Kaynakça

1. Altıntıg E., Ates A., Angın D., Topal Z., Aydemir Z., Kinetic, equilibrium, adsorption mechanisms of RBBR and MG dyes on chitosan-coated montmorillonite with an ecofriendly approach, Chemical Engineering Research and Design, 188, 287–300, 2022.
2. El-Kousy S.M., El-Shorbagy H.G., El-Ghaffar M.A. Chitosan/montmorillonite composites for fast removal of methylene blue from aqueous solutions, Materials Chemistry and Physics, 254, 123236, 2020.
3. Benhouria A., Zaghouane-Boudiaf H., Bourzami R., Djerboua F., Hameed B.H., Boutahala M., Cross-linked chitosan-epichlorohydrin/bentonite composite for reactive orange 16 dye removal: Experimental study and molecular dynamic simulation, International Journal of Biological Macromolecules, 242, 124786, 2023.
4. Eltabey R.M., Abdelwahed F.T., Eldefrawy M.M., Elnagar M.M., Fabrication of poly(maleic acid)-grafted cross-linked chitosan/montmorillonite nanospheres for ultra-high adsorption of anionic acid yellow-17 and cationic brilliant green dyes in single and binary systems, Journal of Hazardous Materials, 439, 129589, 2022.
5. Okur M., Removal of metal-complex dye from textile wastewaters using eggshell, Journal of the Faculty of Engineering and Architecture of Gazi University, 28 (4), 777-785, 2013.
6. Jawad A.H., Abdulhameed A.S., Surip S.N., Alothman Z.A., Hybrid multifunctional biocomposite of chitosan grafted benzaldehyde/montmorillonite/algae for effective removal of brilliant green and reactive blue 19 dyes: Optimization and adsorption mechanism, Journal of Cleaner Production, 393, 136334, 2023.
7. Kumari J.H., Krishnamoorthy P., Arumugam T.K., Radhakrishnan S., Vasudevan D., An efficient removal of crystal violet dye from waste water by adsorption onto TLAC/Chitosan composite: A novel low cost adsorbent, International Journal of Biological Macromolecules, 96, 324-333, 2016.
8. Koyuncu D.D.E., Okur M., Investigation of dye removal ability and reusability of green and sustainable silica and carbon-silica hybrid aerogels prepared from paddy waste ash, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 628, 127370, 2021.

9. Karaca S., Çakmak Onal E., Açıslı Ö., Khataee A., Preparation of chitosan modified montmorillonite biocomposite for sonocatalysis of dyes: Parameters and degradation mechanism, Materials Chemistry and Physics, 260, 124125, 2021.
10. Tahari N., Hoyos-Martinez P.L., Izaguirre N., Houwaida N., Abderrabba M., Ayadi S., Labidi J., Preparation of chitosan/tannin and montmorillonite films as adsorbents for Methyl Orange dye removal, International Journal of Biological Macromolecules, 210, 94–106, 2022.
11. Pereira A.R., Sousa K.S., Cavalcanti G.R.S., França D.B., Queiroga L.N.F., Santos I.M.G., Fonseca M.G., Jaber M., Green biosorbents based on chitosan-montmorillonite beads for anionic dye removal, Journal of Environmental Chemical Engineering, 5, 3309–3318, 2017.
12. Kurczewska J., Chitosan-montmorillonite hydrogel beads for effective dye adsorption, Journal of Water Process Engineering, 48, 102928, 2022.
13. Altunkaynak F., Okur M., Saracoglu N., Controlled release of paroxetine from chitosan/montmorillonite composite films, Journal of Drug Delivery Science and Technology, 68, 103099, 2022.
14. Gao X., Yin H., Guo C., Yan B., Li M., Xin L., Wu Z., Comprehensive removal of various dyes by thiourea modified chitosan/nano ZnS composite via enhanced photocatalysis: Performance and mechanism, International Journal of Biological Macromolecules, 247, 125677, 2023.
15. Sirajudheen P., Meenakshi S., Lanthanum (III) incorporated chitosan-montmorillonite composite as flexible material for adsorptive removal of azo dyes from water, Materials Today: Proceedings, 27, 318–326, 2020.
16. Onnainty R., Onida B., Paez P., Longhi M., Barresi A., Granero G., Targeted chitosan-based bionanocomposites for controlled oral mucosal delivery of chlorhexidine, Int. J. Pharm., 509, 408–418, 2016.
17. Hürmüzlü R., Okur M., Saraçoglu N., Immobilization of Trametes versicolor laccase on chitosan/halloysite as a biocatalyst in the Remazol Red RR dye, International Journal of Biological Macromolecules, 192, 331–341, 2021.
18. Zhao Y., Zhang Y., Dong H., Wu W., Yang X., He Q., Functional biopolymers for food packaging: Formation mechanism and performance improvement of chitosan-based composites, Food Bioscience 54, 102927, 2023.
19. Seyrek, M.E., Okur, M., Saraçoğlu, N., Improvement of mechanical, thermal and antimicrobial properties of organically modified montmorillonite loaded polycaprolactone for food packaging, Journal of Vinyl and Additive Technology, 27, 894-908, 2021.
20. Wang G., Wang S., Sun Z., Zheng S., Xi Y., Structures of nonionic surfactant modified montmorillonites and their enhanced adsorption capacities towards a cationic organic dye, Applied Clay Science, 148, 1–10, 2017.
21. Mahmoodi N.M., Taghizadeh A., Taghizadeh M., Shahali Baglou M.A., Surface modified montmorillonite with cationic surfactants: Preparation, characterization, and dye adsorption from aqueous solution, Journal of Environmental Chemical Engineering, 7, 103243, 2019.
22. Hassani A., Khataee A., Karaca S., Karaca M., Kıranşan M., Adsorption of two cationic textile dyes from water with modified nanoclay: A comparative study by using central composite design, Journal of Environmental Chemical Engineering, 3, 2738–2749, 2015.
23. Nagarpita M.V., Roy P., Shruthi S.B., Sailaja R.R.N., Synthesis and swelling characteristics of chitosan and CMC grafted sodium acrylate-co-acrylamide using modified nanoclay and examining its efficacy for removal of dyes, International Journal of Biological Macromolecules, 102, 1226–1240, 2017.
24. Aktı, F., Okur, M., The Removal of Acid Violet 90 from Aqueous Solutions Using PANI and PANI/Clinoptilolite Composites: Isotherm and Kinetics, Journal of Polymers and the Environment, 26, 4233–4242, 2018.
25. Koyuncu, D.D.E., Okur, M., Removal of AV 90 dye using ordered mesoporous carbon materials prepared via nanocasting of KIT-6: adsorption isotherms, kinetics and thermodynamic analysis, Separation Purification Technology, 257, 117657, 2021.
26. Queiroz M.F., Melo K.R.T., Sabry D.A., Sassaki G.L., Rocha H.A.O., Does the Use of Chitosan Contribute to Oxalate Kidney Stone Formation?, Marine Drugs, 13, 141-158. 2015.
27. Kıranşan, M., Darvishi Cheshmeh Soltani R., Hassani A., Karaca S., Khataee A., Preparation of cetyltri methyl ammonium bromide modified montmorillonite nanomaterial for adsorption of a textile dye, Journal of the Taiwan Institute of Chemical Engineers, 45, 2565-2577, 2014.
28. Wang G., Jin L., Dong Y., Niu L., Liu Y., Ren F., Su X., Multifunctional Fe3O4-CdTe@SiO2@Carboxymethyl Chitosan Drug Nanocarriers: Synergistic Effect towards Magnetic Targeted Drug Delivery and Cell Imaging, New J. Chem., 38, 700-708, 2014.
29. Bayat A., Shakourian-Fard M., Ehyaei N., Mahmoodi Hashemi M., A magnetic supported iron complex for selective oxidation of sulfides to sulfoxides using 30% hydrogen peroxide at room temperature, RSC Adv., 4, 44274, 2014.
30. Munoz-Shuguli C., Rodríguez F.J., Bruna J.E., Galotto M.J., Sarantopoulos C., Favaro Perez M.A., Padula M., Cetylpyridinium bromide-modified montmorillonite as filler in low density polyethylene nanocomposite films, Applied Clay Science, 168, 203, 2019.
31. Mukheem A., Shahabuddin S., Akbar N., Miskon A., Sarih N.M., Sudesh K., Khan N.A., Saidur, R., Sridewi N., Boron Nitride Doped Polyhydroxyalkanoate/Chitosan Nanocomposite for Antibacterial and Biological Applications, Nanomaterials, 9, 645, 2019.
32. Albadarin A. B. , Collins M. N. , Naushad M. , Shirazian S. , Walker G. , Mangwandi C., Activated lignin–chitosan extruded blends for efficient adsorption of methylene blue, Chemical Engineering Journal, 307, 264-272, 2016.
33. Shajahan A., Shankar S., Sathiyaseelan A., Narayan, K.S., Narayanan V., Kaviyarasan V., Ignacimuthu S., Comparative Studies of Chitosan and Its Nanoparticles for the Adsorption Effıciency of Various Dyes, International Journal of Biological Macromolecules, 104, 1449-1458, 2017.
34. Zhai L., Bai Z., Zhu Y., Wang B., Luo W., Fabrication of chitosan microspheres for efficient adsorption of methyl orange, Chinese Journal of Chemical Engineering, 26, 657–666, 2018.
35. Rodrigues D.A.S., Moura J.M., Dotto G.L., Cadaval T.R.S., Pinto L.A.A., Preparation, Characterization and Dye Adsorption/Reuse of Chitosan-Vanadate Films, Journal of Polymers and the Environment, 26 (7), 2917-2924, 2018.
36. dos Santos J.M., Pereira C.R., Pinto L.A.A., Frantz T., Lima D.C., Foletto E.L., Dotto G.L., Synthesis of a novel CoFe2O4/chitosan magnetic composite for fast adsorption of indigotine blue dye, Carbohydrate Polymers, 217, 6-14, 2019.
37. Lou T., Yan X., Wang X., Chitosan coated polyacrylonitrile nanofibrous mat for dye adsorption, International Journal of Biological Macromolecules, 135, 919-925, 2019.
38. Liu, Q., Yang, B., Zhang, L., Huang, R., Adsorption of an anionic azo dye by cross-linked chitosan/bentonite composite, International Journal of Biological Macromolecules, 72, 1129–1135, 2015.

Ayrıntılar

Birincil Dil

Türkçe

Konular

Su Arıtma Süreçleri

Bölüm

Araştırma Makalesi

Yazarlar

Müjgan Okur ^*
0000-0002-1533-9408
Türkiye

Berkay Taşkıntuna
0009-0009-7889-9670
Türkiye

Erken Görünüm Tarihi

17 Mayıs 2024

Yayımlanma Tarihi

20 Mayıs 2024

Gönderilme Tarihi

31 Temmuz 2023

Kabul Tarihi

9 Aralık 2023

Yayımlandığı Sayı

Yıl 2024 Cilt: 39 Sayı: 4

DOI

https://doi.org/10.17341/gazimmfd.1334945

IZ

https://izlik.org/JA32ZT32HJ

Kaynak Göster

RIS / Bibtex

APA

Okur, M., & Taşkıntuna, B. (2024). Kitosan/modifiye montmorillonit küreler ile asit Violet 90 boyarmaddesinin adsorpsiyonu. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 39(4), 2463-2472. https://doi.org/10.17341/gazimmfd.1334945

AMA

1.Okur M, Taşkıntuna B. Kitosan/modifiye montmorillonit küreler ile asit Violet 90 boyarmaddesinin adsorpsiyonu. GUMMFD. 2024;39(4):2463-2472. doi:10.17341/gazimmfd.1334945

Chicago

Okur, Müjgan, ve Berkay Taşkıntuna. 2024. “Kitosan/modifiye montmorillonit küreler ile asit Violet 90 boyarmaddesinin adsorpsiyonu”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 39 (4): 2463-72. https://doi.org/10.17341/gazimmfd.1334945.

EndNote

Okur M, Taşkıntuna B (01 Mayıs 2024) Kitosan/modifiye montmorillonit küreler ile asit Violet 90 boyarmaddesinin adsorpsiyonu. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 39 4 2463–2472.

IEEE

[1]M. Okur ve B. Taşkıntuna, “Kitosan/modifiye montmorillonit küreler ile asit Violet 90 boyarmaddesinin adsorpsiyonu”, GUMMFD, c. 39, sy 4, ss. 2463–2472, May. 2024, doi: 10.17341/gazimmfd.1334945.

ISNAD

Okur, Müjgan - Taşkıntuna, Berkay. “Kitosan/modifiye montmorillonit küreler ile asit Violet 90 boyarmaddesinin adsorpsiyonu”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 39/4 (01 Mayıs 2024): 2463-2472. https://doi.org/10.17341/gazimmfd.1334945.

JAMA

1.Okur M, Taşkıntuna B. Kitosan/modifiye montmorillonit küreler ile asit Violet 90 boyarmaddesinin adsorpsiyonu. GUMMFD. 2024;39:2463–2472.

MLA

Okur, Müjgan, ve Berkay Taşkıntuna. “Kitosan/modifiye montmorillonit küreler ile asit Violet 90 boyarmaddesinin adsorpsiyonu”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, c. 39, sy 4, Mayıs 2024, ss. 2463-72, doi:10.17341/gazimmfd.1334945.

Vancouver

1.Müjgan Okur, Berkay Taşkıntuna. Kitosan/modifiye montmorillonit küreler ile asit Violet 90 boyarmaddesinin adsorpsiyonu. GUMMFD. 01 Mayıs 2024;39(4):2463-72. doi:10.17341/gazimmfd.1334945

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Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi

https://doi.org/10.17341/gazimmfd.1619448