Kalsiyum oksit varlığında teknik hegzaklorosiklohegzan’nın mekanokimyasal parçalanması

Volkan Pelitli; Uğur Kurt; Oltan Canlı

doi:10.17341/gazimmfd.460493

Kalsiyum oksit varlığında teknik hegzaklorosiklohegzan’nın mekanokimyasal parçalanması

Öz

Bu çalışmada, kalsiyum oksit (CaO) varlığında gezegen hareketli bilyalı değirmen kullanılarak teknik hegzaklorosiklohegzan’nın (t-HCH) mekanokimyasal parçalanma verimi araştırılmıştır. Kalıntı içeriğindeki t-HCH miktarı elektron dedektörlü gaz kromatografi (GC-µECD) ile analiz edilmiş ve 6 saat sonunda parçalanma verimi %99.7 olarak bulunmuştur. Pantaklorosiklohegzen, tetraklorobenzen, triklorobenzen, diklorobenzen ve monoklorobenzen gibi parçalanma ürünleri Headspace Gaz kromatografisi-kütle spektrometresi (GC-MS) ile tespit edilmiş ve temel parçalanma yolu önerilmiştir. Sonuçlar son ürünlerin amorf karbon ve suda çözünür klorür olduğunu göstermiştir. Çalışma CaO’nun t-HCH’nin parçalanmasında etkin olarak kullanılabileceğini göstermiştir.

Anahtar Kelimeler

Hekzaklorosiklohegzan,mekanokimyasal proses,parçalama,kalsiyum oksit

Kaynakça

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Ayrıntılar

Birincil Dil

Türkçe

Konular

-

Bölüm

-

Yazarlar

Volkan Pelitli

Uğur Kurt

Oltan Canlı

Yayımlanma Tarihi

23 Mayıs 2019

Gönderilme Tarihi

21 Temmuz 2017

Kabul Tarihi

-

Yayımlandığı Sayı

Yıl 2019 Cilt: 34 Sayı: 2

DOI

https://doi.org/10.17341/gazimmfd.460493

IZ

https://izlik.org/JA24GY43KT

Kaynak Göster

RIS / Bibtex

APA

Pelitli, V., Kurt, U., & Canlı, O. (2019). Kalsiyum oksit varlığında teknik hegzaklorosiklohegzan’nın mekanokimyasal parçalanması. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 34(2), 961-974. https://doi.org/10.17341/gazimmfd.460493

AMA

1.Pelitli V, Kurt U, Canlı O. Kalsiyum oksit varlığında teknik hegzaklorosiklohegzan’nın mekanokimyasal parçalanması. GUMMFD. 2019;34(2):961-974. doi:10.17341/gazimmfd.460493

Chicago

Pelitli, Volkan, Uğur Kurt, ve Oltan Canlı. 2019. “Kalsiyum oksit varlığında teknik hegzaklorosiklohegzan’nın mekanokimyasal parçalanması”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 34 (2): 961-74. https://doi.org/10.17341/gazimmfd.460493.

EndNote

Pelitli V, Kurt U, Canlı O (01 Mayıs 2019) Kalsiyum oksit varlığında teknik hegzaklorosiklohegzan’nın mekanokimyasal parçalanması. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 34 2 961–974.

IEEE

[1]V. Pelitli, U. Kurt, ve O. Canlı, “Kalsiyum oksit varlığında teknik hegzaklorosiklohegzan’nın mekanokimyasal parçalanması”, GUMMFD, c. 34, sy 2, ss. 961–974, May. 2019, doi: 10.17341/gazimmfd.460493.

ISNAD

Pelitli, Volkan - Kurt, Uğur - Canlı, Oltan. “Kalsiyum oksit varlığında teknik hegzaklorosiklohegzan’nın mekanokimyasal parçalanması”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 34/2 (01 Mayıs 2019): 961-974. https://doi.org/10.17341/gazimmfd.460493.

JAMA

1.Pelitli V, Kurt U, Canlı O. Kalsiyum oksit varlığında teknik hegzaklorosiklohegzan’nın mekanokimyasal parçalanması. GUMMFD. 2019;34:961–974.

MLA

Pelitli, Volkan, vd. “Kalsiyum oksit varlığında teknik hegzaklorosiklohegzan’nın mekanokimyasal parçalanması”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, c. 34, sy 2, Mayıs 2019, ss. 961-74, doi:10.17341/gazimmfd.460493.

Vancouver

1.Volkan Pelitli, Uğur Kurt, Oltan Canlı. Kalsiyum oksit varlığında teknik hegzaklorosiklohegzan’nın mekanokimyasal parçalanması. GUMMFD. 01 Mayıs 2019;34(2):961-74. doi:10.17341/gazimmfd.460493