NOHUT SAMANI TARLA ATIĞININ SULU ÇÖZELTİLERDEN METİLEN MAVİSİ GİDERİMİNDE DÜŞÜK MALİYETLİ BİYOSORBENT OLARAK DEĞERLENDİRİLMESİ

Yıl 2014, , 0 - , 31.12.2014

Murat Kılıç , Özge Çepelioğullar , Gamzenur Özsin , Başak Uzun , Ayşe E. Pütün

https://doi.org/10.17341/gummfd.43899

Cited By: 3

Öz

Yapılan bu çalışmada tarımsal bir atık olan nohut samanı, sulu çözeltilerden boyar madde gideriminde biyosorbent olarak değerlendirilmiştir. Çözelti pH’ı, biyosorbent miktarı, başlangıç boyar madde derişimi, temas süresi ve çözelti sıcaklığının biyosorpsiyon işlemine olan etkileri incelenmiştir. Ayrıca, metilen mavisi biyosorpsiyonuna ait denge izoterm, termodinamik ve kinetik çalışmalar gerçekleştirilmiştir. Biyosorpsiyon denge verilerinin Freundlich izotermi ile uyumlu olduğu belirlenmiş, biyosorpsiyonu en iyi ifade edebilen kinetik modelin ise sözde(yalancı) ikinci dereceden model olduğu saptanmıştır. Hesaplanan termodinamik parametreler, biyosorpsiyonun 20-50 °C aralığında kendiliğinden gerçekleşen endotermik bir işlem olduğunu göstermiştir. Metilen mavisi biyosorpsiyonu için nohut samanının maksimum tek tabaka biyosorpsiyon kapasitesi 108,7 mg/g olarak belirlenmiştir. Sonuç olarak, nohut samanının sulu çözeltilerden metilen mavisi gideriminde çevreye dost, düşük maliyetli ve etkili bir biyosorbent olarak kullanılabileceği belirlenmiştir.

Anahtar Kelimeler

Biyosorpsiyon, boyar madde, nohut samanı, izoterm, kinetik, termodinamik

Kaynakça

• Doğan, M., Abak, H. ve Alkan, M., “Adsorption of Methylene Blue onto Hazelnut Shell: Kinetics, Mechanism and Activation Parameters”, Journal of Hazardous Materials, Cilt 164, 172-181, 2009.
• Gökkuş, Ö. ve Çiner, F., “Dispers Sarı 119 Ve Dispers Kırmızı 167 İçeren Atıksuların Fenton Oksidasyon Prosesi İle Renk ve KOI Giderimlerinin İncelenmesi”, Journal of the Faculty of Engineering and Architecture of Gazi University, Cilt 25, No 1, 49-55, 2010.
• Aroguz, A.Z., Gulen, J. ve Evers, R.H., “Adsorption of Methylene Blue form Aqueous Solution on Pyrolyzed Petrified Sediment”, Bioresource Technology, Cilt 99, 1503-1508, 2008.
• Aksu, A., Murathan, A. ve Koçyiğit, H., “Reaktif Mavi 221’in Pomza ile Adsorpsiyoın Kinetiği”, Journal of the Faculty of Engineering and Architecture of Gazi University, Cilt 26, No 4, 807-812, 2011.
• Murathan, A. ve Koçyiğit, H., “Sulu Çözeltilerden Kadmiyum İyonlarının Dolgulu Yataklarda At Kestanesi ve Meşe Palamudu Kullanılarak Giderilmesi”, Journal of the Faculty of Engineering and Architecture of Gazi University, Cilt 28, No 2, 303-306, 2013.
• Türkiye Cumhuriyeti Başbakanlık Yatırım Destek ve Tanıtım Ajansı, “Türkiye Tarım Sektörü Raporu”, Temmuz 2010, http://www.invest.gov.tr/trTR/infocenter/publications/Documents/TARIM.SEKTORU.PDF
• Food and Agriculture Organisation of United Nations(FAO), “Tarım Ürünlerin Dünya İstatistikleri”, Aralık 2012, www.fao.org
• Han, R., Zou, W., Yu, W., Cheng, S., Wang, Y. ve Shi, J., “Biosorption of Methylene Blue from Aqueous Solution by Fallen Phoenix Tree’s Leaves”, Journal of Hazardous Materials, Cilt 141, 156-162,2007.
• Ghaedi, M., Hajati, S., Barazesh, B., Karimi, F., Ghezelbash, G., “Saccharomyces cerevisiae for the biosorption of basic dyes from binary component systems and the high order derivative spectrophotometric method for simultaneous analysis of Brilliant green and Methylene blue”, Journal of Industrial and Engineering Chemistry, Cilt 19, 227–233, 2013.
• Aksu, Z., Ertuğrul, S., Dönmez, G., “Methylene Blue biosorption by Rhizopus arrhizus: Effect of SDS(sodium dodecylsulfate) surfactant on biosorption properties”, Chemical Engineering Journal, Cilt 158, No 3, 474–481, 2010.
• Han, R., Wang, Y., Han, P., Shi, J., Yang, J., Lu, Y., “Removal of methylene blue from aqueous solution by chaff in batch mode”, Journal of Hazardous Materials, Cilt 137, No 1, 550–557, 2006.
• Pavan, F.A., Lima, E.C., Dias, S.L.P., Mazzocato, A.C., “Methylene blue biosorption from aqueous solutions by yellow passion fruit waste”, Journal of Hazardous Materials, Cilt 150, No 3, 703–712, 2008.
• Xiao, X., Luo, S., Zeng, G., Wei, W., Wan, Y., Chen, L., Guo, H., Cao, Z., Yang, L., Chen, J. ve Xi, Q., “Biosorption of Cadmium by Endophytic Fungus(EF) Microsphaeropsis Sp. LSE10 İsolated from Cadmium Hyperaccumulator Solanum Nigrum L.”, Bioresource Technology, Cilt 101, 1668-1674, 2010.
• Al-Anber, Z.A., Al-Anber, M.A., Matouq, M., Al-Ayed, O., Omari, N.M., “Defatted Jojoba for the removal of methylene blue from aqueous solution: Thermodynamic and kinetic studies”, Desalination, Cilt 276, No 1–3, 169–174, 2011.
• Cherifi, H., Fatih, B., Salah, H., “Kinetic studies on the adsorption of methylene blue onto vegetal fiber activated carbons”, Applied Surface Science, Cilt 282, 52–59, 2013.
• Akkurt, F., Alıcılar, A., Şendil, O., “Sularda Bulunan Nitratın Adsorpsiyon Yoluyla Uzaklaştırılması”, Journal of the Faculty of Engineering and Architecture of Gazi University, Cilt 17, No 4, 83-91, 2002.
• Langmuir, I., “The Constitution and Fundamental Properties of Solids and Liquids”, Journal of American Chemical Society, Cilt 38, 2221-2295, 1916.
• Freundlich, H.M.F., “Über die Adsorption in Lösungen”, Zeitschrift für Physikalische Chemie, Cilt 57, 385-470, 1906.
• Dubinin, M.M. ve Radushkevich, L.V., “Equation of the Characteristic Curve of Activated Charcoal”, Proceedings of the USSR Academy of Sciences Physical Chemistry, Cilt 55, 331, 1947.
• Lagergren, S., “Zur theorie der sogenannten adsorption geloster stoffe”, Kungliga Svenska Vetenskapsakademiens, Handlingar, Cilt 24, 1-39, 1898.
• Ho, Y.S., McKay, G., “Pseudo-Second Order Model for Sorption Process”, Process Biochemistry, Cilt 34, 451-465, 1999.
• Weber, W.J., Morriss, J.C., “Kinetics of Adsorption on Carbon From Solution”, Journal of the Sanitary Engineering Division American Society of Civil Engineers, Cilt 89, 31-60, 1963.
• Amini, M., Younesi, H., Bahramifar, N., “Biosorption of nickel(II) from aqueous solution by Aspergillus niger: Response surface methodology and isotherm study”, Chemosphere, Cilt 75, No 11, 1483–1491, 2009.
• Ferrero, F., “Dye Removal by Low Cost Adsorbents: Hazelnut Shells in Comparison with Wood Sawdust”, Journal of Hazardous Materials, Cilt 142, 144-152, 2007.
• Vadivelan, V., Vasanth Kumar K., “Equilibrium, kinetics, mechanism, and process design for the sorption of methylene blue onto rice husk”, Journal of Colloid and Interface Science, Cilt 286, No 1, 90–100, 2005.
• Batzias, F., Sidiras, D., Schroeder, E., Weber, C., “Simulation of Dye Adsorption on Hydrolyzed Wheat Straw in Batch and Fixed-Bed Systems”, Chemical Engineering Journal, Cilt 148,459-472, 2009.
• Feng, Y., Yang, F., Wang, Y., Ma, L., Wu, Y., Kerr P.G., Yang, L., “Basic Dye Adsorption onto an Agro-Based Waste Material-Sesame Hull(Sesamum İndicum L.)”, Bioresource Technology, Cilt 102, 10280-10285, 2011.
• Belala. Z., Jeguirim, M., Belhachemi,M., Addoun, F., Trouvé, G., “Biosorption of Basic Dye from Aqueous Solutions by Date Stones and Palm-Trees Waste: Kinetic, Equilibrium and Thermodynamic Studies”, Desalination, Cilt 271, 80-87, 2011.
• Uddin, M.T., Islam, M.A., Mahmud, S., Rukanuzzaman, M., “Adsorptive Removal of Methylene Blue by Tea Waste”, Journal of Hazardous Materials, Cilt 164, 53-60, 2009.
• Annadurai, G., Juang, R.S., Lee, D.J., “Use of cellulose-based wastes for adsorption of dyes from aqueous solutions”, Journal of Hazardous Materials, Cilt 92, No 3, 263–274, 2002.
• Doğan, M., Özdemir, Y., Alkan, M., “Adsorption kinetics and mechanism of cationic methyl violet and methylene blue dyes onto sepiolite”, Dyes and Pigments, Cilt 75, Sayı 3, 701–713, 2007.
• Hamayun, M., Mahmood, T., Naeem, A., Muska, M., Din, S.U., Waseem, M., “Equilibrium and kinetics studies of arsenate adsorption by FePO4”, Chemosphere, Cilt 99, 207–215, 2014.
• Huang, W.Y., Li, D., Liu, Z.Q., Tao, Q., Zhu, Y., Yang, J., Zhang, Y.M., “Kinetics, isotherm, thermodynamic, and adsorption mechanism studies of La(OH)3-modified exfoliated vermiculites as highly efficient phosphate adsorbents”, Chemical Engineering Journal, Cilt 236, 191–201, 2014.
• Dursun, A.Y., “A comparative study on determination of the equilibrium, kinetic and thermodynamic parameters of biosorption of copper(II) and lead(II) ions onto pretreated Aspergillus niger”, Biochemical Engineering Journal, Cilt 28, No 2, 187–195, 2006.