UVA uygulamalarıyla topraktaki PCB’lerin gideriminde H2O2 kullanımı

Yıl 2021, Cilt: 36 Sayı: 2, 779 - 792, 05.03.2021

Büşra Tandoğan Gizem Eker Şanlı

https://doi.org/10.17341/gazimmfd.596319

Cited By: 1

Öz

Bu çalışmada,
topraktaki PCB kirliliğinin uzaklaştırılması için UV uygulamalarında belli
dozlarda (%1, %10 ve %20) H₂O₂ kullanımının S₈₂  PCB giderim verimine  etkilerini belirlemek amaçlanmıştır. Çalışma
kapsamında alınan toprak örnekleri tasarlanan düzenekte 24 saat boyunca 18 ^oC
ve 30 ^oC sıcaklıklarda, UV A ışınlarına maruz bırakılarak PCB
giderim uygulamaları gerçekleştirilmiştir. UV A uygulamalarında sonrasında
katkı maddesi kullanımıyla beraber 18 ^oC’de giderim verimi %82 iken,
30 ^oC’de %95’e ulaşmıştır. En verimli (%95 PCB giderimi) doz 30 ^oC’de
%10 H₂O₂ olarak belirlenmiştir. Türler bazında
bakıldığında ağır klorlu türlerin gideriminin yüksek olduğu görülmüştür. Dutch S₇
PCB türleri için tüm uygulamalar incelendiğinde, %90’ın üzerinde giderim
verimleri elde edilmiştir. PCB izomerlerinin üç (yutma, dermal, soluma) ana
yolla maruziyetlerinin kanser riski olasılık tespiti yapılmış ve PCB türlerinin
kanserojenik potansiyel risk değerleri ile toksisite değerleri belirlenmiştir.
Bursa’da sanayi bölgesi yakınından alınan toprak örneklerinin kanser riski
analizi sonucunda “çok düşük risk” grubunda yer aldığı ve toksisite açısından
sağlık riski oluşturmadığı belirlenmiştir.  

Anahtar Kelimeler

H2O2, PCB, sıcaklık, toksisite, UV

Kaynakça

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