Biosorption of reactive dye Remazol Ultra Red RGB by metabolically active kefir biomass

Yıl 2021, Cilt: 36 Sayı: 2, 1055 - 1074, 05.03.2021

Ali Osman Erdoğdular Dilek Kılıç Apar

https://doi.org/10.17341/gazimmfd.615654

Öz

In the
present study biosorptive removal of Remazol Ultra Red RGB textile dye from
aqueous solutions with living kefir biomass was investigated.  The experiments were carried out at batch
operation mode under different process conditions such as initial pH (2 - 2.5 -
3 - 3.5 - 4 -5- 6 - 7 - 8), temperature (18 - 25 - 32 - 39°C), shaking rate (0
- 140 - 300 rpm) and initial dye concentration (50 - 75 - 100 - 200 - 400 mg/L)
to optimize and model the biosorption process. 
93% dye removal was attained in 180 min processing time by using 2.4 g/
kefir biomass for 100 mg/L initial dye concentration at pH 2 and 25°C. The
maximum adsorption capacity for kefir biomass was obtained as 112 mg/g at 400
mg/L dye concentration.  Successively
performed biosorption experiments showed that the kefir biomass is reusable. As
a result of the modelling studies performed the biosorption kinetics and
equilibrium by kefir biomass were best described respectively with
pseudo-first-order and Temkin models.

Anahtar Kelimeler

Remazol Red RGB, biosorption, kefir biomass, kinetic, isotherm

Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu

Öz

Bu çalışmada, canlı formda kefir
biyokütleleri ile sulu çözeltilerden Remazol ultra Kırmızı RGB boyar maddesinin
biyosorpsiyon yöntemi ile giderimi incelenmiştir. Biyosorpsiyon prosesini
optimize etmek ve modellemek amacı ile deneyler kesikli olarak, farklı ​​pH (2
- 2,5 - 3 - 3,5 -  4 - 5 - 6 - 7 - 8),
sıcaklık (18- 25 - 32 - 39°C), çalkalama hızı (0 - 140 - 300 rpm) ve başlangıç
boyar madde konsantrasyonlarında (50 - 75 - 100 -  200 - 400 mg/L) gerçekleştirilmiştir. pH 2’de,
25°C sıcaklıkta, 100 mg/L başlangıç boyar madde konsantrasyonunda, 2,4 g/L
kefir biyokütlesi kullanılarak gerçekleştirilen 180 dakikalık biyosorpsiyon
işlemi sonunda % 93 oranında boyar madde giderimi elde edilmiştir. Kefir biyokütlesi
için maksimum adsorpsiyon kapasitesi değeri 112 mg/g olarak 400 mg/L başlangıç
boyar madde konsantrasyonunda elde edilmiştir. Ardışık olarak gerçekleştirilen
biyosorpsiyon deneyleri kefir biyokütlelerinin tekrar kullanılabilir olduğunu
göstermiştir. Gerçekleştirilen modelleme çalışmaları sonucunda, kefir biyokütleleri
ile boyar madde biyosorpsiyon kinetiğinin yalancı birinci derece kinetik modeli
ile, biyosorpsiyon dengesinin ise Temkin izoterm modeli ile ifade edilebileceği
belirlenmiştir.

Anahtar Kelimeler

Remazol Kırmızı RGB, biyosorpsiyon, kefir biyokütlesi, kinetik, izoterm

Kaynakça

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