Atık sulardan metilen mavisi gideriminde polianilin/ceviz kabuğu atığı kompozitlerinin kullanımı

Yıl 2021, Cilt: 36 Sayı: 4, 1801 - 1816, 02.09.2021

Alaaddin Cerit

https://doi.org/10.17341/gazimmfd.845443

Cited By: 1

Öz

Sentetik boyaların atık sularda yarattığı kirlilik önemli bir sorun haline gelmiştir. Bilhassa selülozik malzemelerin boyanmasında kullanılan metilen mavisinin atık sulardan giderimi önemi artan bir konudur. Bu çalışmada, Polianilin/Ceviz kabuğu atığı kompozitleri düşük maliyetli ve kullanışlı adsorbanlar olarak sunulmuştur. Kompozitler farklı karışım oranlarında hazırlanmıştır. Adsorbanların kimyasal yapıları Fourier Dönüşümü Kızılötesi Spektroskopisi ile ve yüzey morfolojileri Taramalı Elektron Mikroskobu ile araştırılmıştır.
pH, adsorban miktarı, başlangıç boyarmadde konsantrasyonu, zaman ve sıcaklığın, Metilen Mavisi adsorpsiyonu üzerine etkisi incelenmiştir. Çeşitli sıcaklıklarda kinetik ve izoterm çalışmaları yapılmıştır. Adsorpsiyon davranışı, üç ana izoterm modeli yardımıyla incelenmiştir. Elde edilen izoterm verilerinin Freundlich izoterminden ziyade Langmuir izotermiyle daha çok eşleştiği görülmüştür. Kompozit adsorbanın adsorpsiyon kapasitesinin 105 mg/g olduğu bulunmuştur. En yüksek adsorpsiyon verimlilik değeri %98,93 olarak tesbit edilmiştir. Reaksiyon kinetiğinin sözde ikinci derece kinetik model ile eşleştiği görülmüştür.

Anahtar Kelimeler

polianilin, ceviz kabuğu atığı, metilen mavisi, adsorpsiyon, kompozit

Destekleyen Kurum

Necmettin Erbakan Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü

Proje Numarası

191225001

Teşekkür

Necmettin Erbakan Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğüne verdiği destekten dolayı Teşekkür Ederim.

Kaynakça

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