Yıl 2011,
Cilt: 26 Sayı: 3, 0 - , 20.02.2013
Öz
Günümüzde yaygın bir şekilde ortaya çıkan atık plastiklerin geri dönüşüm dışı yollarla da değerlendirilmesiönemli konulardandır. Bu çalışmada evsel plastik atıklar arasından seçilen yüksek yoğunluklu polietilen (YYPE)ile biyokütle olarak seçilen çam odunu tozunun birlikte pirolizi araştırıldı. Bu materyallerin öğütülmüşörneklerinin belirli oranlarındaki karışımlarından hazırlanan pelletlerin sabit yataktaki pirolizi sonucu oluşanürünlerin verimlerine farklı piroliz parametrelerinin (ısıtma hızı, son sıcaklık, süpürme hızı, karışım oranı)etkileri ortaya konuldu.Eşit oranda YYPE ve çam odunu bulunduran pelletler ile en yüksek katı ürün verimi 1oC/min ısıtma hızında, 10mL/min azot akışı altında ve 500oC piroliz sıcaklığında elde edildi. En yüksek sıvı ürün verimi ise 5oC/min’ lıkısıtma hızında, azotsuz ortamda (azot sürükleyici gazının kullanılmadığı ve 0 mL/min ile ifade edilen ortam) ve700oC piroliz sıcaklığında elde edilmiştir.
Anahtar Kelimeler
Kaynakça
- Hartmann, D. and Kaltschmitt, M., “Electricity
- generation from solid biomass via cocombustion
- with coal: Energy and emission
- balances from a German case study”, Biomass
- and Bioenergy, Cilt 16, No 6, 397-406, 1999.
- Collot, A.G., Zhuo, Y., Dugwell, D.R.,
- Kandiyoti, R., “Co-pyrolysis and co-gasification
- of coal and biomass in bench-scale fixed bed
- and fluidized bed reactors”, Fuel, Cilt 78, No 6,
- -679, 1999.
- Cliffe, K.R. and Patumsawad, S., “Cocombustion
- of waste from olive oil production
- with coal in a fluidised bed”, Waste
- Management, Cilt 21, No 1, 49-53, 2001.
- Skodras, G., Grammelis, P., Samaras, P.,
- Vourliotis, P., Kakaras, P. and Sakellaropoulos,
- G.P., “Emissions monitoring during coal waste
- wood co-combustion in an industrial steam
- boiler”, Fuel, Cilt 81, No 5, 547-554, 2002.
- Armesto, L., Bahillo, A., Cabanillas, A.,
- Veijonen, K., Otero, J., Plumed, A. and
- Salvador, L., “Co-combustion of coal and olive
- oil industry residues in fluidized bed”, Fuel,
- Cilt 82, No 8, 993-1000, 2003.
- DPT, “Sekizinci beş yıllık kalkınma planı
- (2001-2005)”, Yıyın no: DPT: 2547-ÖİK: 563,
- Ankara, Türkiye, 2001.
- DPT, “Dokuzuncu Kalkınma Planı (2007-
- ”, Yayın no: DPT: 2779-ÖİK: 708,
- Ankara, Türkiye, 2008.
- Ballice, L., “A kinetic approach to the
- temperature-programmed pyrolysis of low –and
- high-density polyethylene in a fixed bed reactor:
- Determination of kinetic parameters for nparaffins
- and 1-olefins evolution”, Fuel, Cilt 80,
- -1935, 2001.
- Demirbaş, A., “Recovery of chemicals and
- gasoline-range fuels from plastic wastes via
- pyrolysis”, Energy Sources, Cilt 27, 1313-
- , 2005.
- Marin, N., Collura, S., Sharypov, V.I.,
- Beregovtsova, N.G., Baryshnikov, S.V.,
- Kuznetsov, B.N., Cebolla, V.L. and Weber,
- J.V., “Co-pyrolysis of wood biomass and
- synthetic polymer mixtures. Part II:
- Characterisation of the liquid phases”, Journal
- of Analytical and Applied Pyrolysis, 65, 41-
- , 2002.
- Sharypov, V.I., Marin, N., Beregovtsova, N.G.,
- Baryshnikov, S.V., Kuznetsov, B.N., Cebolla,
- V.L. and Weber, J.V., “Co-pyrolysis of wood
- biomass and synthetic polymer mixtures. Part I:
- Influence of experimental conditions on the
- evolution of solids, liquids and gases”, Journal
- of Analytical and Applied Pyrolysis, 64, 15-
- , 2002.
- Zhou, L., Wang, Y., Huang, Q. and Cai, J.,
- “Thermogravimetric characteristics and kinetic
- of plastic and biomass blends co-pyrolysis”,
- Fuel Processing Technology, 87, 963-969,
- -
- Encinara, J.M. and González, J.F., “Pyrolysis of
- synthetic polymers and plastic wastes Kinetic
- study”, Fuel Processıng Technology, Cilt 89,
- –686, 2008.
- Williams, P.T. and Slaney, E., “Analysis of
- products from the pyrolysis and liquefaction of
- single plastics and waste plastic mixtures”,
- Resources, Conservation and Recycling, Cilt
- , 754–769, 2007.
- Solomon, P.R., Serio, M.A. and Suuberg, E.M.,
- “Coal Pyrolysis: Experiments, Kinetics and
- Mechanisms”, Progres in Energy and
- Combustion Science, 18, 133-220, 1992.
Yıl 2011,
Cilt: 26 Sayı: 3, 0 - , 20.02.2013
Öz
Kaynakça
- Hartmann, D. and Kaltschmitt, M., “Electricity
- generation from solid biomass via cocombustion
- with coal: Energy and emission
- balances from a German case study”, Biomass
- and Bioenergy, Cilt 16, No 6, 397-406, 1999.
- Collot, A.G., Zhuo, Y., Dugwell, D.R.,
- Kandiyoti, R., “Co-pyrolysis and co-gasification
- of coal and biomass in bench-scale fixed bed
- and fluidized bed reactors”, Fuel, Cilt 78, No 6,
- -679, 1999.
- Cliffe, K.R. and Patumsawad, S., “Cocombustion
- of waste from olive oil production
- with coal in a fluidised bed”, Waste
- Management, Cilt 21, No 1, 49-53, 2001.
- Skodras, G., Grammelis, P., Samaras, P.,
- Vourliotis, P., Kakaras, P. and Sakellaropoulos,
- G.P., “Emissions monitoring during coal waste
- wood co-combustion in an industrial steam
- boiler”, Fuel, Cilt 81, No 5, 547-554, 2002.
- Armesto, L., Bahillo, A., Cabanillas, A.,
- Veijonen, K., Otero, J., Plumed, A. and
- Salvador, L., “Co-combustion of coal and olive
- oil industry residues in fluidized bed”, Fuel,
- Cilt 82, No 8, 993-1000, 2003.
- DPT, “Sekizinci beş yıllık kalkınma planı
- (2001-2005)”, Yıyın no: DPT: 2547-ÖİK: 563,
- Ankara, Türkiye, 2001.
- DPT, “Dokuzuncu Kalkınma Planı (2007-
- ”, Yayın no: DPT: 2779-ÖİK: 708,
- Ankara, Türkiye, 2008.
- Ballice, L., “A kinetic approach to the
- temperature-programmed pyrolysis of low –and
- high-density polyethylene in a fixed bed reactor:
- Determination of kinetic parameters for nparaffins
- and 1-olefins evolution”, Fuel, Cilt 80,
- -1935, 2001.
- Demirbaş, A., “Recovery of chemicals and
- gasoline-range fuels from plastic wastes via
- pyrolysis”, Energy Sources, Cilt 27, 1313-
- , 2005.
- Marin, N., Collura, S., Sharypov, V.I.,
- Beregovtsova, N.G., Baryshnikov, S.V.,
- Kuznetsov, B.N., Cebolla, V.L. and Weber,
- J.V., “Co-pyrolysis of wood biomass and
- synthetic polymer mixtures. Part II:
- Characterisation of the liquid phases”, Journal
- of Analytical and Applied Pyrolysis, 65, 41-
- , 2002.
- Sharypov, V.I., Marin, N., Beregovtsova, N.G.,
- Baryshnikov, S.V., Kuznetsov, B.N., Cebolla,
- V.L. and Weber, J.V., “Co-pyrolysis of wood
- biomass and synthetic polymer mixtures. Part I:
- Influence of experimental conditions on the
- evolution of solids, liquids and gases”, Journal
- of Analytical and Applied Pyrolysis, 64, 15-
- , 2002.
- Zhou, L., Wang, Y., Huang, Q. and Cai, J.,
- “Thermogravimetric characteristics and kinetic
- of plastic and biomass blends co-pyrolysis”,
- Fuel Processing Technology, 87, 963-969,
- -
- Encinara, J.M. and González, J.F., “Pyrolysis of
- synthetic polymers and plastic wastes Kinetic
- study”, Fuel Processıng Technology, Cilt 89,
- –686, 2008.
- Williams, P.T. and Slaney, E., “Analysis of
- products from the pyrolysis and liquefaction of
- single plastics and waste plastic mixtures”,
- Resources, Conservation and Recycling, Cilt
- , 754–769, 2007.
- Solomon, P.R., Serio, M.A. and Suuberg, E.M.,
- “Coal Pyrolysis: Experiments, Kinetics and
- Mechanisms”, Progres in Energy and
- Combustion Science, 18, 133-220, 1992.
Toplam 74 adet kaynakça vardır.
Ayrıntılar
| Birincil Dil | Türkçe |
|---|---|
| Bölüm | Makaleler |
| Yazarlar | |
| Yayımlanma Tarihi | 20 Şubat 2013 |
| Gönderilme Tarihi | 20 Şubat 2013 |
| Yayımlandığı Sayı | Yıl 2011 Cilt: 26 Sayı: 3 |